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Journal of Nanomaterials
Volume 2013 (2013), Article ID 736375, 7 pages
http://dx.doi.org/10.1155/2013/736375
Review Article

A Review on the Synthesis of Manganese Oxide Nanomaterials and Their Applications on Lithium-Ion Batteries

College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

Received 21 January 2013; Accepted 22 February 2013

Academic Editor: Bo Yu

Copyright © 2013 Xiaodi Liu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. C. Burda, X. B. Chen, R. Narayanan, and M. A. El-Sayed, “Chemistry and properties of nanocrystals of different shapes,” Chemical Reviews, vol. 105, no. 4, pp. 1025–1102, 2005. View at Publisher · View at Google Scholar
  2. J. Cao, Q. H. Mao, L. Shi, and Y. T. Qian, “Fabrication of γ-MnO2/α-MnO2/ hollow core/shell structures and their application to water treatment,” Journal of Materials Chemistry, vol. 21, pp. 16210–16215, 2011. View at Publisher · View at Google Scholar
  3. D. Yan, S. Cheng, R. F. Zhuo et al., “Nanoparticles and 3D sponge-like porous networks of manganese oxides and their microwave absorption properties,” Nanotechnology, vol. 20, no. 10, Article ID 105706, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. Y. W. Tan, L. R. Meng, Q. Peng, and Y. D. Li, “One-dimensional single-crystalline Mn3O4 nanostructures with tunable length and magnetic properties of Mn3O4 nanowires,” Chemical Communications, vol. 47, no. 4, pp. 1172–1174, 2011. View at Publisher · View at Google Scholar
  5. X. Zhang, Z. Xing, Y. Yu et al., “Synthesis of Mn3O4 nanowires and their transformation to LiMn2O4 polyhedrons, application of LiMn2O4 as a cathode in a lithium-ion battery,” CrystEngComm, vol. 14, no. 4, pp. 1485–1489, 2012. View at Publisher · View at Google Scholar
  6. R. Ma, Y. Bando, L. Zhang, and T. Sasaki, “Layered MnO2 nanobelts: hydrothermal synthesis and electrochemical measurement,” Advanced Materials, vol. 16, no. 11, pp. 918–922, 2004. View at Publisher · View at Google Scholar
  7. F. Y. Cheng, J. Z. Zhao, W. Song et al., “Facile controlled synthesis of MnO2 nanostructures of novel shapes and their application in batteries,” Inorganic Chemistry, vol. 45, no. 5, pp. 2038–2044, 2006. View at Publisher · View at Google Scholar
  8. F. Y. Cheng, J. A. Shen, B. Peng, Y. D. Pan, Z. L. Tao, and J. Chen, “Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts,” Nature Chemistry, vol. 3, pp. 79–84, 2011. View at Publisher · View at Google Scholar
  9. B. Sun, Z. X. Chen, H. S. Kim, H. Ahn, and G. X. Wang, “MnO/C core-shell nanorods as high capacity anode materials for lithium-ion batteries,” Journal of Power Sources, vol. 196, no. 6, pp. 3346–3349, 2011. View at Publisher · View at Google Scholar · View at Scopus
  10. N. Sui, Y. Duan, X. Jiao, and D. Chen, “Large-scale preparation and catalytic properties of one-dimensional α/β-mno2 nanostructures,” Journal of Physical Chemistry C, vol. 113, no. 20, pp. 8560–8565, 2009. View at Publisher · View at Google Scholar · View at Scopus
  11. J. Luo, H. T. Zhu, H. M. Fan et al., “Synthesis of single-crystal tetragonal α-MnO2 nanotubes,” Journal of Physical Chemistry C, vol. 112, no. 33, pp. 12594–12598, 2008. View at Publisher · View at Google Scholar · View at Scopus
  12. S. Jana, S. Pande, A. K. Sinha et al., “A green chemistry approach for the synthesis of flower-like Ag-doped MnO2 nanostructures probed by surface-enhanced raman spectroscopy,” Journal of Physical Chemistry C, vol. 113, no. 4, pp. 1386–1392, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. Y. S. Ding, X. F. Shen, S. Gomez, H. Luo, M. Aindow, and S. L. Sui, “Hydrothermal growth of manganese dioxide into three-dimensional hierarchical nanoarchitectures,” Advanced Functional Materials, vol. 16, no. 4, pp. 549–555, 2006. View at Publisher · View at Google Scholar
  14. C. N. R. Rao, S. R. C. Vivekchand, K. Biswas, and A. Govindaraja, “Synthesis of inorganic nanomaterials,” Dalton Transactions, no. 34, pp. 3728–3749, 2007.
  15. W. Xiao, D. Wang, and X. W. Lou, “Shape-controlled synthesis of MnO2 nanostructures with enhanced electrocatalytic activity for oxygen reduction,” The Journal of Physical Chemistry C, vol. 114, pp. 1694–1700, 2010. View at Publisher · View at Google Scholar
  16. G. L. Xu, Y. F. Xu, H. Sun et al., “Facile synthesis of porous MnO/C nanotubes as a high capacity anode material for lithium ion batteries,” Chemical Communications, vol. 48, pp. 8502–8504, 2012. View at Publisher · View at Google Scholar
  17. D. Yan, P. X. Yan, G. H. Yue et al., “Self-assembled flower-like hierarchical spheres and nanobelts of manganese oxide by hydrothermal method and morphology control of them,” Chemical Physics Letters, vol. 440, no. 1–3, pp. 134–138, 2007. View at Publisher · View at Google Scholar · View at Scopus
  18. X. Wang and Y. Li, “Synthesis and formation mechanism of manganese dioxide nanowires/nanorods,” Chemistry, vol. 9, pp. 300–306, 2003. View at Publisher · View at Google Scholar
  19. S. Ching, E. J. Welch, S. M. Hughes, A. B. F. Bahadoor, and S. L. Suib, “Nonaqueous sol-gel syntheses of microporous manganese oxides,” Chemistry of Materials, vol. 14, no. 3, pp. 1292–1299, 2002. View at Publisher · View at Google Scholar · View at Scopus
  20. N. Wang, X. Cao, L. He et al., “One-Pot synthesis of highly crystallined λ-MnO2 nanodisks assembled from nanoparticles: morphology evolutions and phase transitions,” The Journal of Physical Chemistry C, vol. 112, no. 2, pp. 365–369, 2008. View at Publisher · View at Google Scholar
  21. Y. Oaki and H. Imai, “One-pot synthesis of manganese oxide nanosheets in aqueous solution: chelation-mediated parallel control of reaction and morphology,” Angewandte Chemie, vol. 119, no. 26, pp. 5039–5043, 2007. View at Publisher · View at Google Scholar
  22. X. Yu, Y. He, J. Sun et al., “Nanocrystalline MnO thin film anode for lithium ion batteries with low overpotential,” Electrochemical Communications, vol. 11, no. 4, pp. 791–794, 2009. View at Publisher · View at Google Scholar
  23. T. Ahmad, K. V. Ramanujachary, S. E. Lofland, and A. K. Ganguli, “Nanorods of manganese oxalate: a single source precursor to different manganese oxide nanoparticles (MnO, Mn2O3, Mn3O4),” Journal of Materials Chemistry, vol. 14, no. 23, pp. 3406–3410, 2004. View at Publisher · View at Google Scholar · View at Scopus
  24. P. Yu, X. Zhang, D. Wang, L. Wang, and Y. Ma, “Shape-controlled synthesis of 3D hierarchical MnO2 nanostructures for electrochemical supercapacitors,” Crystal Growth & Design, vol. 9, no. 1, pp. 528–533, 2009. View at Publisher · View at Google Scholar
  25. C. Wu, W. Xie, M. Zhang, L. Bai, J. Yang, and Y. Xie, “Environmentally friendly γ-MnO2 hexagon-based nanoarchitectures: structural understanding and their energy-saving applications,” Chemistry, vol. 15, no. 2, pp. 492–500, 2009. View at Publisher · View at Google Scholar
  26. R. Liu, J. Duay, and S. B. Lee, “Redox exchange induced MnO2 nanoparticle enrichment in poly(3,4-ethylenedioxythiophene) nanowires for electrochemical energy storage,” ACS Nano, vol. 4, no. 7, pp. 4299–4307, 2010. View at Publisher · View at Google Scholar · View at Scopus
  27. Y. Chen, Y. Hong, Y. Ma, and J. Li, “Synthesis and formation mechanism of urchin-like nano/micro-hybrid α-MnO2,” Journal of Alloys and Compounds, vol. 490, pp. 331–335, 2010. View at Publisher · View at Google Scholar
  28. X. Wang and Y. Li, “Selected-control hydrothermal synthesis of α- and β-MnO2 single crystal nanowires,” Journal of the American Chemical Society, vol. 124, no. 12, pp. 2880–2881, 2002. View at Publisher · View at Google Scholar
  29. N. Kijima, H. Yasuda, T. Sato, and Y. Yoshimura, “Preparation and characterization of open tunnel oxide α-MnO2 precipitated by ozone oxidation,” Journal of Solid State Chemistry, vol. 159, no. 1, pp. 94–102, 2001. View at Publisher · View at Google Scholar · View at Scopus
  30. M. H. Huang, S. Mao, H. Feick et al., “Room-temperature ultraviolet nanowire nanolasers,” Science, vol. 292, no. 5523, pp. 1897–1899, 2001. View at Publisher · View at Google Scholar · View at Scopus
  31. S. Chen, J. Zhu, Q. Han, Z. Zheng, Y. Yang, and X. Wang, “Shape-controlled synthesis of one-dimensional MnO2 via a facile quick-precipitation procedure and its electrochemical properties,” Crystal Growth & Design, vol. 9, no. 10, pp. 4356–4361, 2009. View at Publisher · View at Google Scholar · View at Scopus
  32. X. Wang and Y. Li, “Rational synthesis of α-MnO2 single-crystal nanorods,” Chemical Communications, no. 7, pp. 764–765, 2002.
  33. D. Zheng, S. Sun, W. Fan et al., “One-step preparation of single-crystalline β-MnO2 nanotubes,” Journal of Physical Chemistry B, vol. 109, no. 34, pp. 16439–16443, 2005. View at Publisher · View at Google Scholar · View at Scopus
  34. H. T. Zhu, J. Luo, H. X. Yang et al., “Birnessite-type MnO2 nanowalls and their magnetic properties,” Journal of Physical Chemistry C, vol. 112, no. 44, pp. 17089–17094, 2008. View at Publisher · View at Google Scholar · View at Scopus
  35. N. Wang, X. Cao, L. Guo, and S. Yang, “λ-MnO2 nanodisks and their magnetic properties,” Nanotechnology, vol. 18, no. 47, Article ID 475605, 2007. View at Publisher · View at Google Scholar
  36. D. Zheng, Z. Yin, W. Zhang, X. Tan, and S. Sun, “Novel branched γ-MnOOH and β-MnO2 multipod nanostructures,” Crystal Growth & Design, vol. 6, no. 8, pp. 1733–1735, 2006. View at Publisher · View at Google Scholar
  37. X. Yang, Y. Makita, Z. H. Liu, K. Sakane, and K. Ooi, “Structural characterization of self-assembled MnO2 nanosheets from birnessite manganese oxide single crystals,” Chemistry of Materials, vol. 16, no. 26, pp. 5581–5588, 2004. View at Publisher · View at Google Scholar · View at Scopus
  38. Z. Li, Y. Ding, Y. Xiong, Q. Yang, and Y. Xie, “One-step solution-based catalytic route to fabricate novel α-MnO2 hierarchical structures on a large scale,” Chemical Communications, no. 7, pp. 918–920, 2005.
  39. J. Fei, Y. Cui, X. Yan et al., “Controlled preparation of MnO2 hierarchical hollow nanostructures and their application in water treatment,” Advanced Materials, vol. 20, no. 3, pp. 452–456, 2008. View at Publisher · View at Google Scholar
  40. B. Li, G. Rong, Y. Xie, L. Huang, and C. Feng, “Low-temperature synthesis of α-MnO2 hollow urchins and their application in rechargeable Li+ batteries,” Inorganic Chemistry, vol. 45, no. 16, pp. 6404–6410, 2006. View at Publisher · View at Google Scholar
  41. C. Xia, W. Ning, and G. Lin, “Facile synthesis of novel MnO2 hierarchical nanostructures and their application to nitrite sensing,” Sensors and Actuators B, vol. 137, no. 2, pp. 710–714, 2009. View at Publisher · View at Google Scholar · View at Scopus
  42. X. Fu, J. Feng, H. Wang, and K. M. Ng, “Room temperature synthesis of a novel γ-MnO2 hollow structure for aerobic oxidation of benzyl alcohol,” Nanotechnology, vol. 20, no. 37, Article ID 375601, 2009. View at Publisher · View at Google Scholar
  43. X. C. Song, Y. Zhao, and Y. F. Zheng, “Synthesis of MnO2 nanostructures with sea urchin shapes by a sodium dodecyl sulfate-assisted hydrothermal process,” Crystal Growth & Design, vol. 7, no. 1, pp. 159–162, 2007. View at Publisher · View at Google Scholar
  44. H. Chen and J. He, “Self-assembly of birnessite manganese dioxide into monodisperse honeycomb and hollow nanospheres,” Chemistry Letters, vol. 36, pp. 174–175, 2007. View at Publisher · View at Google Scholar
  45. Q. C. Sun, X. Xu, S. N. Baker, A. D. Christianson, and J. L. Musfeldt, “Experimental determination of ionicity in MnO nanoparticles,” Chemistry of Materials, vol. 23, no. 11, pp. 2956–2960, 2011. View at Publisher · View at Google Scholar · View at Scopus
  46. M. Baldi, E. Finocchio, F. Milella, and G. Busca, “Catalytic combustion of C3 hydrocarbons and oxygenates over Mn3O4,” Applied Catalysis B, vol. 16, no. 1, pp. 43–51, 1998. View at Publisher · View at Google Scholar · View at Scopus
  47. L. Ji and X. Zhang, “Manganese oxide nanoparticle-loaded porous carbon nanofibers as anode materials for high-performance lithium-ion batteries,” Electrochemistry Communications, vol. 11, no. 4, pp. 795–798, 2009. View at Publisher · View at Google Scholar
  48. S. L. Brock, M. Sanabria, S. L. Suib, V. Urban, P. Thiyagarajan, and D. I. Potter, “Particle size control and self-assembly processes in novel colloids of nanocrystalline manganese oxide,” Journal of Physical Chemistry B, vol. 103, no. 35, pp. 7416–7428, 1999. View at Scopus
  49. Z. Tian, Q. Feng, N. Sumida, Y. Makita, and K. Ooi, “Synthesis of manganese oxide nanofibers by selfassembling hydrothermal process,” Chemistry Letters, vol. 33, no. 8, pp. 952–953, 2004. View at Publisher · View at Google Scholar · View at Scopus
  50. Y. Oaki and H. Imai, “One-pot synthesis of manganese oxide nanosheets in aqueous solution: chelation-mediated parallel control of reaction and morphology,” Angewandte Chemie, vol. 46, pp. 4951–4955, 2007. View at Publisher · View at Google Scholar
  51. Q. Li, J. Wang, Y. He, W. Liu, and X. Qiu, “Growth of nearly monodisperse MnO nanocrystals in a two-size distribution system,” Crystal Growth & Design, vol. 9, no. 7, pp. 3100–3103, 2009. View at Publisher · View at Google Scholar
  52. M. Yin and S. O'Brien, “Synthesis of monodisperse nanocrystals of manganese oxides,” Journal of the American Chemical Society, vol. 125, no. 34, pp. 10180–10181, 2005. View at Publisher · View at Google Scholar
  53. J. Park, E. Kang, C. J. Bae et al., “Synthesis, characterization, and magnetic properties of uniform-sized MnO nanospheres and nanorods,” Journal of Physical Chemistry B, vol. 108, no. 36, pp. 13594–13598, 2004. View at Publisher · View at Google Scholar · View at Scopus
  54. A. Puglisi, S. Mondini, S. Cenedese, A. M. Ferretti, N. Santo, and A. Ponti, “Monodisperse octahedral α-MnS and MnO nanoparticles by the decomposition of manganese oleate in the presence of sulfur,” Chemistry of Materials, vol. 22, no. 9, pp. 2804–2813, 2010. View at Publisher · View at Google Scholar · View at Scopus
  55. S. Xie, X. Zhou, X. Han et al., “Supercrystals from crystallization of octahedral MnO nanocrystals,” Journal of Physical Chemistry C, vol. 113, no. 44, pp. 19107–19111, 2009. View at Publisher · View at Google Scholar · View at Scopus
  56. R. Xing, G. Liu, Q. Quan et al., “Functional MnO nanoclusters for efficient siRNA delivery,” Chemical Communications, vol. 47, pp. 12152–12154, 2011. View at Publisher · View at Google Scholar
  57. T. Ould-Ely, D. Prieto-Centurion, A. Kumar et al., “Manganese(II) oxide nanohexapods: insight into controlling the form of nanocrystals,” Chemistry of Materials, vol. 18, no. 7, pp. 1821–1829, 2006. View at Publisher · View at Google Scholar · View at Scopus
  58. I. Rusakova, T. Ould-Ely, C. Hofmann et al., “Nanoparticle shape conservation in the conversion of MnO nanocrosses into Mn3O4,” Chemistry of Materials, vol. 19, no. 6, pp. 1369–1375, 2007. View at Publisher · View at Google Scholar
  59. X. Li, D. Li, L. Qiao et al., “Interconnected porous MnO nanoflakes for high-performance lithium ion battery anodes,” Journal of Materials Chemistry, vol. 22, pp. 9189–9194, 2012. View at Publisher · View at Google Scholar
  60. H. Ohno, “Making nonmagnetic semiconductors ferromagnetic,” Science, vol. 281, no. 5379, pp. 951–956, 1998. View at Scopus
  61. K. M. Nam, Y. Kim, Y. Jo et al., “New crystal structure: synthesis and characterization of hexagonal wurtzite MnO,” Journal of the American Chemical Society, vol. 134, pp. 8392–8395, 2012. View at Publisher · View at Google Scholar
  62. X. Zhang, Z. Xing, L. Wang et al., “Synthesis of MnO@C core-shell nanoplates with controllable shell thickness and their electrochemical performance for lithium-ion batteries,” Journal of Materials Chemistry, vol. 22, no. 34, pp. 17864–17869, 2012. View at Publisher · View at Google Scholar
  63. T. D. Schladt, K. Koll, S. Prüfer et al., “Multifunctional superparamagnetic MnO@SiO2 core/shell nanoparticles and their application for optical and magnetic resonance imaging,” Journal of Materials Chemistry, vol. 22, pp. 9253–9262, 2012. View at Publisher · View at Google Scholar
  64. Y. Sun, X. Hu, W. Luo, and Y. Huang, “Porous carbon-modified MnO disks prepared by a microwave-polyol process and their superior lithium-ion storage properties,” Journal of Materials Chemistry, vol. 22, pp. 19190–19195, 2012. View at Publisher · View at Google Scholar
  65. M. Armand and J. M. Tarascon, “Building better batteries,” Nature, vol. 451, no. 7179, pp. 652–657, 2008. View at Publisher · View at Google Scholar · View at Scopus
  66. X. Sun, X. Wang, L. Qiao et al., “Electrochemical behaviors of porous SnO2-Sn/C composites derived from pyrolysis of SnO2/poly(vinylidene fluoride),” Electrochimica Acta, vol. 66, pp. 204–209, 2012. View at Publisher · View at Google Scholar
  67. J. Zhao, Z. Tao, J. Liang, and J. Chen, “Facile synthesis of nanoporous γ-MnO2 structures and their application in rechargeable li-Ion batteries,” Crystal Growth & Design, vol. 8, pp. 2799–2805, 2008.
  68. K. Zhong, X. Xia, B. Zhang, H. Li, Z. Wang, and L. Chen, “MnO powder as anode active materials for lithium ion batteries,” Journal of Power Sources, vol. 195, no. 10, pp. 3300–3308, 2010. View at Publisher · View at Google Scholar · View at Scopus
  69. Y. U. Jeong and A. Manthiram, “Nanocrystalline manganese oxides for electrochemical capacitors with neutral electrolytes,” Journal of the Electrochemical Society, vol. 149, no. 11, pp. A1419–A1422, 2002. View at Publisher · View at Google Scholar · View at Scopus
  70. H. Y. Lee and J. B. Goodenough, “Supercapacitor behavior with KCl electrolyte,” Journal of Solid State Chemistry, vol. 144, no. 1, pp. 220–223, 1999. View at Publisher · View at Google Scholar · View at Scopus
  71. E. Raymundo-Piñero, V. Khomenko, E. Frackowiak, and F. Béguin, “Performance of manganese oxide/CNTs composites as electrode materials for electrochemical capacitors,” Journal of the Electrochemical Society, vol. 152, no. 1, pp. A229–A235, 2005. View at Publisher · View at Google Scholar
  72. J. Liu and Q. M. Pan, “MnO/C nanocomposites as high capacity anode materials for li-Ion batteries,” Electrochemical and Solid-State Letters, vol. 13, no. 10, pp. A139–A142, 2010. View at Publisher · View at Google Scholar
  73. W. Xiao, J. S. Chen, Q. Lu, and X. W. Lou, “Porous spheres assembled from polythiophene (PTh)-coated ultrathin MnO2 nanosheets with enhanced lithium storage capabilities,” The Journal of Physical Chemistry C, vol. 114, no. 27, pp. 12048–12051, 2010. View at Publisher · View at Google Scholar