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Journal of Nanomaterials
Volume 2013 (2013), Article ID 745746, 8 pages
The Study of Magnetorheology of Iron Oxide Nanowires
1Institute of Organic and Polymeric Materials, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao E. Road, Taipei 10648, Taiwan
2Center of Condensed Matter Science, National Taiwan University, Taipei, Taiwan
Received 9 March 2013; Accepted 20 May 2013
Academic Editor: Subhankar Bedanta
Copyright © 2013 S. P. Rwei et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
In this work, circular Fe3O4 particles with a diameter of 24 nm and quasicircular Fe3O4 particles with a diameter of 10 nm were synthesized using peptization and coprecipitation methods, respectively. The coprecipitated particles were further formed into Fe3O4 nanowires at high temperature and high pressure in a strongly alkaline environment. The optimal environment for forming nanowire was 15 m (molality) NaOH at 120°C for three days; the resulting proportional relationship between its width and its height, the aspect ratio, was 50.5/1. In the second part of this study, the nanoparticles and nanowire were dispersed in silicon oil and formed into magnetorheological (MR) fluids of different concentrations, before undergoing various MR tests—a shear test, a compression test, and a creep recovery test. The results revealed that the MR performance of nanowire fluid was better than that of circular particle fluid, in terms of yield stress (35 Pa versus 60 Pa), compression displacement (Δd) (0.19 mm versus 0.44 mm), and creep recovery ratio (82% versus 48%). The experimental results conclude that the nanowire network is more robust than the nanoparticle network. The test of the storage shelf time revealed that 12 wt% nanowire fluid retained more than 80% of its original yield stress after three months, indicating slight precipitation in the nanowire fluid. In summary, the nanowire MR fluid had a stronger MR effect than traditional MR fluid that was prepared with spherical MR particles.
A magnetorheological (MR) suspension can be promptly transformed from a fluid-like structure to a solid-like structure with a viscoelastic to plastic yielding by subjecting it into a magnetic field [1–7]. Rabinow  discovered this phenomenon in 1948. Since then, various metal or ceramic powders with magnetic characteristics have been dispersed in nonmagnetic carrier liquids (such as oil or aqueous liquids) in the preparation of MR suspensions. Smart damper  is an important application of magnetorheological (MR) fluid. The releasing of its internal energy depends mainly on the viscosity of the dashpot. Therefore, a method for preparing MR fluid with a wide range of viscosities, ensuring a strong response of the yield stress or creep recovery from low to high magnetic strength, is crucial. Notably, Fe3O4, having a net ferromagnetic moment arising from the incomplete cancellation of spin materials of Fe2+ ions, can respond very sensitively to the magnetic fields. More importantly, the permanent magnetization of Fe3O4 nanoparticles is still weak enough that it cannot cause any interparticle agglomeration under zero magnetic field strength; Fe3O4 nanoparticle thus becomes a good candidate for the preparation of MR fluids. This work employs various chemical methods to synthesize Fe3O4 magnetic particles of various sizes and Fe3O4 magnetic nanowire and to form them into MR fluids, whose MR properties, including shear yield stress, compression resistance, creep recovery, and yield strength decay, are then observed. The goal is to find the formulation of MR fluids with optimal performance.
Add iron chloride hexahydrate (10.8 g, 80 mmol), sodium oleate (36.5 g, 240 mmol) to a mixed solution of ethanol (80 mL), deionized water (60 mL), and hexane (140 mL). Stir the mixture well in a 500 mL three-neck flask that is mounted on a condensation system. Heat to 70°C and maintain this temperature for 4.5 h; then purify three times using deionized water (30 mL) and finally store the iron-oleate complex product in hexane. Add iron-oleate complex 9 g, oleic acid 1.7 g to 30 g tri-n-octylamine and stir well in a 500 mL three-neck flask. Heat at 3.3°C/min to 366°C or 300°C and maintain this temperature for 30 min. Wash the excessive oleic acid from the surface of Fe3O4 nanoparticles using ethanol or hexane, respectively.
2.2. Coprecipitation Synthesis of Nanoparticle II
To 6 g iron chloride tetrahydrate and 12 g iron chloride hexahydrate add 25 mL deionized water and mix to form an ionic solution. Add 50 mL ammonium hydroxide rapidly while agitating mechanically; keep stirring for 6 min and coprecipitate [13–16] to obtain Fe3O4 nanoparticles. Use deionized water to wash off excessive ammonium hydroxide. Remove remaining deionized water in Fe3O4 nanoparticles by freeze-drying.
2.3. Hydrothermal Synthesis of Nanowire III
Put 0.5 g Fe3O4 nanoparticles in a pressurized reaction flask and add sodium hydroxide solution to a concentration of 15 M. Place the flask in an oven and allow the hydrothermal reaction [17–19] to proceed at 120°C (2 atm) for three days to yield Fe3O4 nanowires. Use deionized water to remove the excess sodium hydroxide solution. Remove the remaining deionized water from the Fe3O4 nanowires by freeze-drying.
2.4. Preparation of Magnetic Fluid
Add materials I, or II, or III to silicon oil with viscosities of 10 cp and 100 cp (polydimethylsiloxane PDMS). Stir well to obtain MR fluid. Pour the MR fluid into the groove on the lower plate of the rheometer (Anton Paar Physica MCR301 MRD). Then, lower the upper plate until the clearance is 0.1 cm. The temperature of the rheometer is held constant, 25°C. Apply various currents and measure the yield stress, the compression displacement, and the creep recovery rate of the specimen. The electronic micrographs were taken using transmission electron microscope at 300 kV (TEM Hitachi: H-7100). The X-ray powder diffractometer (XRD PANalytical X’Pert PRO MPD), operated at 45 kV and 20 mA under CuKα radiation, was applied to analyze the crystal phase. The detector was scanned over a range of 4θ angles from 0° to 70° at a speed of 4° per minute.
3. Results and Discussion
Figure 1 presents a TEM image of Fe3O4 nanoparticles that were synthesized by oleic acid peptization. The diameters of the particles are uniformly distributed with an average of 24 nm. X-ray diffraction proves that the nanoparticles are pure Fe3O4 (Figure 2 lower curve). The peaks are consistent with the previous study . Figure 3 presents a TEM image of Fe3O4 nanoparticles that were formed by coprecipitation. As is seen, the distribution of particle sizes is very broad—much broader than achieved by peptization. The particles are not spherical but appear quasicircular or even polygonal. However, X-ray diffraction pattern (Figure 2-upper curve) proves that they are still pure Fe3O4 particles.
Figures 4(a)–4(c) present the influence of NaOH concentration on the lengths of Fe3O4 nanowires formed at high temperature (110°C) and high pressure in a hydrothermal environment. As is seen, the nanowires were longest when the NaOH concentration was 15 m. As the NaOH concentration was further increased, less deionized water can be vaporized, resulting in the pressure in the flask at high temperature being reduced. Consequently, the Fe3O4 nanoparticles are not driven to combine to form nanowire. The length of the rod shapes is therefore reduced. In short, the optimal environment in which to form nanowire is 15 m NaOH, which was utilized hereafter.
Figures 5(a)–5(d) present a TEM photograph of Fe3O4 nanowires that were synthesized at various temperatures or reaction durations. The conditions of Figure 5(a), including a temperature of 120°C, in which the fewest particles were unreacted, were obviously optimal. Analysis of the image reveals that the aspect ratio of 50.5 : 1 obtained at 120°C is also the maximum value. The optimal conditions for forming Fe3O4 nanowire formation are thus determined to be 15 m NaOH, 120°C, high pressure, and a strongly alkaline ambient.
As shown in Figure 6, the yield stress of Fe3O4 nanowire fluid, 60 Pa, is nearly double that of Fe3O4 nanoparticle fluid, 35 Pa, at the same concentration (6 wt%). This result indicates that the asymmetry of nanowire can enhance the MR effect. Figure 7 plots the dependence of shear stress on shear rate for various concentrations of Fe3O4 nanowires that were suspended in silicon oil with various viscosities (10 cp, 100 cp). The MR fluid exhibits typical Bingham character , with a yield stress threshold at which fluidity in a magnetic field is first exhibited. Figure 7 demonstrates that the yield stress increases with the nanowire concentration. Moreover, when the solid loading is 12 wt%, the yield stress of the 100 cp suspension is 1.5 times that of the 10 cp suspension (1100 Pa versus 720 Pa). This result demonstrates that an increase of PDMS viscosity results in a higher yield stress at a given Fe3O4 loading. Figure 8 plots the yield stress against Fe3O4 solid concentrations when 0–36 wt% of Fe3O4 nanowires are suspended in 100 cp silicon oil. In the plot, as the solid loading increases, the yield stress increases as approximately a second-order polynomial () function. Even though the increase of Fe3O4 loading positively affects the MR effect, the nanowire agglomeration that arises from high loading may occur seriously. This work demonstrates that the solid loading of Fe3O4 nanowires can be increased to 36 wt% without causing serious agglomeration. The authors’ ultimate goal is to formulate a highly effective MR fluid at a sufficiently high concentration so that it can flow freely in a nonmagnetic field without solid-liquid separation but has a yield stress that can increase to 104 Pa in a magnetic field.
Along with the shear test, the compression test can also be employed to characterize MR fluids. When a magnetic fluid is placed in a magnetic field, MR particles are temporarily in a network state, as shown in Figure 9(a). The purpose of shear test, as stated previously, is to determine the critical shear stress, also known as the yield stress that disrupts the network state. Similarly, the action of compression stress on the network can alter the network structure. Figure 9(b) demonstrates that under a given compression stress, a smaller change in volume, or a smaller Δd, corresponds to a greater magnetic attractive force among the magnetic particles within the network. When subjected to an external force, a more robust network is associated with a greater displacement resistance, and the displacement in the direction of the force is smaller. Figure 10 reveals that the compression displacements of the Fe3O4 nanoparticle are 0.39 mm and 0.44 mm in 10 cp and 100 cp silicon oil, respectively. In contrast, the compression displacements (Δd) of the nanowires dispersed in 10 cp and 100 cp silicon oil are 0.19 mm and 0.07 mm, respectively. The experimental result demonstrates that nanowire can exhibit favorable MR behavior. Additionally, the nanowire network has a higher compact density and toughness than the nanoparticle network. In fact, the particles are orientated and line up along the magnetic line of force with fewer joints. However, the line derived from the circular nanoparticles has more junctions than that derived from a nanowire. These junctions are the weakest points of the line. They usually collapse under a shear force or compression stress (Figures 11(a) and 11(b)). The resistance of the nanowire network to an external force is better because it has fewer junctions. The results also reveal that 10 cp silicon oil is associated with a shorter compression displacement than 100 cp silicon oil, perhaps because the former lubricates the joints less well than the latter. Better lubrication is generally associated with longer compression displacement.
The creep and recovery test [22, 23] focuses on investigating the recovery behavior of a magnetic network following deformation by shearing, which has rarely been studied as part of MR investigations. In this work, the elasticity of the magnetic network structure is determined by applying a constant shear stress less than the yield stress to the MR fluid. The transient displacement of the MR structure reaches a constant, and then the stress is removed to observe the recovery of the MR fluid. A high recovery ratio demonstrates excellent elasticity of the magnetic network. It also indicates that the arrangement of magnetic particles inside the network is in a very stable state. Notably, the stress applied herein is less than the yield stress, and none of the magnetic fluids flows; rather, it exhibits various degrees of displacement. If obvious damage or permanent displacement occurs in the creep test, then the stress has permanently and detrimentally affected the relative positions of the network particles, such that the magnetic network structure fails to recover after shearing. This situation reveals that the solid character of the magnetic network is not strong. Figure 12 plots the result of the creep and recovery test for nanoparticles and nanowire. When the shear stress (10 Pa or 20 Pa) is much less than the yield stresses of the MR fluids (35 Pa for nanoparticles and 60 Pa for nanowire), the recovery ratio of elasticity is nearly 100%. However, at a shear stress of 30 Pa, which is close to the yield stress of nanoparticles, the recovery ratio is only 48%. In contrast, 30 Pa is far below the yield stress of the nanowire, for which the recovery ratio is 82%. This result confirms that a nanowire network is more robust than a nanoparticle network. Additionally, Figure 12 shows that a network formed by the magnetic field suffers serious damage when the applied stress is only slightly less than the yield stress. Figure 13 plots the creep and recovery of MR fluids when the applied stress exceeds the yield stress. In the creep stage in Figure 13, the creep strain is not constant but increases with time. When the creep recovery stage is triggered 100 seconds later, the recovery is unobservable because the previous magnetic network structure had completely disintegrated. Even if the applied stress were terminated, a new network that is oriented with the magnetic field would gradually form, but it would have no relation to the previously damaged network in terms of structure or relative position of particles. Accordingly, recovery cannot occur when the applied stress exceeds the yield stress.
To determine whether the nanowire fluid meets the operating requirements, 12 wt% nanowire suspensions were stored for one, two, and three months, restirred, and then individually subjected to the MR shear test. Figure 14 shows that the yield stress decays from an initial value of 400 Pa at a rate from 20 Pa–30 Pa per month to 325 Pa after three months. This result shows that, because the size of the suspended nanowires is of the order of microns, their Brownian motion cannot overcome gravity, and precipitation eventually occurs. However, after restirring, this suspended matter is again dispersed, reducing the agglomeration. Figures 15(a) to 15(c) are TEM images of nanowire fluid with various storage periods. A comparison with Figure 5(b) reveals slight wire agglomeration, which, while not severe, should be reduced.
This systematic study of the preparation of magnetic particles preparation and their MR characterization supports the following conclusions. (1)Circular Fe3O4 particles with a diameter of 24 nm and quasicircular Fe3O4 particles with a diameter of 10 nm were synthesized by peptization and coprecipitation. The peptized particles were formed into Fe3O4 nanowire at high temperature and high pressure in strongly alkaline environment. The optimal reaction conditions for forming nanowires are 15 m NaOH at 120°C for three days. An aspect ratio as high as 50.5 : 1 can thus be achieved. (2)The MR shear test revealed that the yield stress of Fe3O4 nanowire fluid is double that of the same concentration of Fe3O4 nanoparticle fluid. Furthermore, as the Fe3O4 particle concentration increases, the yield stress increases following a second-order polynomial () curve. (3)The compression displacement (Δd) of the Fe3O4 nanowire MR fluid is far less than that of the Fe3O4 nanoparticle MR fluid (0.19 mm versus 0.44 mm). The creep recovery capacity of Fe3O4 nanowire also exceeds that of Fe3O4 nanoparticle. (4)The creep and recovery test showed that a network formed by the magnetic field had serious damage once the applied stress was close to the yield stress.(5)In the storage test, 12 wt% nanowire fluid retained more than 80% of its original yield stress after three months.
In summary, nanowire magnetic particles can exhibit a better MR effect than traditional magnetic particles that were prepared with spherical MR particles.
Conflict of Interests
The MR fluid prepared according to the method mentioned herein is a novel method. Even though it still has long way to go for commercial application, its patents have been claimed and filed by the authors and the financial founder: NSC of Taiwan. There is no conflict of interests for any commercial application at present time or in the future.
The authors would like to thank the National Science Council of Taiwan, for financially supporting this research under Contract no. NSC 98-2221-E-027-003-MY3.
- W. M. Winslow, “Induced fibration of suspensions,” Journal of Applied Physics, vol. 20, no. 12, pp. 1137–1140, 1949.
- P. P. Phulé, “Magnetorheological (MR) fluids: principles and applications,” Smart Materials Bulletin, vol. 2001, no. 2, pp. 7–10, 2001.
- G. Bossis, O. Volkova, S. Lacis, and A. Meunier, “Magnetorheology: fluids, structures and rheology,” Stefan Odenbach, vol. 594, pp. 202–230, 2002.
- I. Bica and H. J. Choi, “Preparation and electro-thermoconductive characteristics of magnetorheological suspensions,” International Journal of Modern Physics B, vol. 22, no. 29, pp. 5041–5064, 2008.
- J. L. Viota, J. de Vicente, J. D. G. Durán, and A. V. Delgado, “Stabilization of magnetorheological suspensions by polyacrylic acid polymers,” Journal of Colloid and Interface Science, vol. 284, no. 2, pp. 527–541, 2005.
- A. J. F. Bombard, M. Knobel, and M. R. Alcântara, “Phosphate coating on the surface of carbonyl iron powder and its effect in magnetorheological suspensions,” International Journal of Modern Physics B, vol. 21, no. 28-29, pp. 4858–4867, 2007.
- F. F. Fang and H. J. Choi, “Fabrication of multiwalled carbon nanotube-wrapped magnetic carbonyl iron microspheres and their magnetorheology,” Colloid and Polymer Science, vol. 288, no. 1, pp. 79–84, 2010.
- J. Rabinow, “The magnetic fluid clutch,” Transactions of the American Institute of Electrical Engineers, vol. 67, pp. 1308–1315, 1948.
- A. G. Olabi and A. Grunwald, “Design and application of magneto-rheological fluid,” Materials and Design, vol. 28, no. 10, pp. 2658–2664, 2007.
- X. Ren, “Large electric-field-induced strain in ferroelectric crystals by point-defect-mediated reversible domain switching,” Nature Materials, vol. 3, no. 2, pp. 91–94, 2004.
- S. Sun, H. Zeng, D. B. Robinson et al., “Monodisperse MFe2O4 (M = Fe, Co, Mn) nanoparticles,” Journal of the American Chemical Society, vol. 126, no. 1, pp. 273–279, 2004.
- T. Hyeon, “Chemical synthesis of magnetic nanoparticles,” Chemical Communications, no. 8, pp. 927–934, 2003.
- R. Massart, “Preparation of aqueous magnetic liquids in alkaline and acidic media,” IEEE Transactions on Magnetics, vol. 17, no. 2, pp. 1247–1248, 1981.
- J. Zhang, Q. Kong, J. Du, D. Ma, G. Xi, and Y. Qian, “Formation, characterization, and magnetic properties of Fe3O4 microoctahedrons,” Journal of Crystal Growth, vol. 308, no. 1, pp. 159–165, 2007.
- J. Wang, K. Zhang, Z. Peng, and Q. Chen, “Magnetic properties improvement in Fe3O4 nanoparticles grown under magnetic fields,” Journal of Crystal Growth, vol. 266, no. 4, pp. 500–504, 2004.
- S. Lian, E. Wang, L. Gao et al., “Growth of single-crystal magnetite nanowires from Fe3O4 nanoparticles in a surfactant-free hydrothermal process,” Solid State Communications, vol. 132, no. 6, pp. 375–378, 2004.
- S. Lian, E. Wang, Z. Kang et al., “Synthesis of magnetite nanorods and porous hematite nanorods,” Solid State Communications, vol. 129, no. 8, pp. 485–490, 2004.
- K. He, C.-Y. Xu, L. Zhen, and W.-Z. Shao, “Hydrothermal synthesis and characterization of single-crystalline Fe3O4 nanowires with high aspect ratio and uniformity,” Materials Letters, vol. 61, no. 14-15, pp. 3159–3162, 2007.
- X. Lan, X. Cao, W. Qian, W. Gao, C. Zhao, and Y. Guo, “Long Fe3O4 nanowires decorated by CdTe quantum dots: synthesis and magnetic-optical properties,” Journal of Solid State Chemistry, vol. 180, no. 8, pp. 2340–2345, 2007.
- G. Vaidyanathan, S. Sendhilnathan, and R. Arulmurugan, “Structural and magnetic properties of nanoparticles by co-precipitation method,” Journal of Magnetism and Magnetic Materials, vol. 313, no. 2, pp. 293–299, 2007.
- J. M. G. Cowie and V. Arrighi, Polymers: Chemistry and Physics of Modern Materials, CRC Press, New York, NY, USA, 2007.
- I. G. Plashchina, N. V. Grinberg, E. E. Braudo, and V. B. Tolstoguzov, “Conformational transition and aggregation of 𝓍-carrageenan macromolecules in solutions,” Colloid and Polymer Science, vol. 258, no. 9, pp. 1038–1043, 1980.
- S.-P. Rwei and L. Wang, “Synthesis and electrical, rheological and thermal characterization of conductive polyurethane,” Colloid and Polymer Science, vol. 285, no. 12, pp. 1313–1319, 2007.