Hybrid Organic-Inorganic Perovskites Open a New Era for Low-Cost, High Efficiency Solar Cells

Peng, Guiming; Xu, Xueqing; Xu, Gang

doi:https://doi.org/10.1155/2015/241853

Journal of Nanomaterials

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Nanomaterials for Solar Energy Harvesting and Storage

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Review Article | Open Access

Volume 2015 | Article ID 241853 | https://doi.org/10.1155/2015/241853

Hybrid Organic-Inorganic Perovskites Open a New Era for Low-Cost, High Efficiency Solar Cells

Guiming Peng,^1,2,3Xueqing Xu,²and Gang Xu²

Academic Editor: Cao Yuebin

Received12 Oct 2014

Revised14 Dec 2014

Accepted14 Dec 2014

Published26 Oct 2015

Abstract

The ramping solar energy to electricity conversion efficiencies of hybrid organic-inorganic perovskite solar cells during the last five years have opened new doors to low-cost solar energy. The record power conversion efficiency has climbed to 19.3% in August 2014 and then jumped to 20.1% in November. In this review, the main achievements for perovskite solar cells categorized from a viewpoint of device structure are overviewed. The challenges and prospects for future development of this field are also briefly presented.

1. Introduction

The energy crisis and environment pollution are two main worldwide challenges that would restrain the society development. Solar energy, as a clean and vast energy source, is widely believed to be a promising way to address these global issues. Converting solar energy into electricity is thought to be an effective way to harness this abundant energy source. To date, single-crystalline silicon solar cells have shown optimistic power conversion efficiency (PCE) above 24%. However, the cost of manufacturing process is still very high. Searching for low-cost materials with high PCE always attracts extensive efforts from the scientists.

Fortunately, the past five years have seen hybrid organic-inorganic perovskite solar cells (PSCs) performing promisingly on a low-cost avenue to the clean and vast solar energy. The ease of fabrication, abundant material source, and high PCE rapidly caught the attention of scientists.

PSCs first emerged as a liquid electrolyte based solar cell in 2009 with the PCE of only 3.8% [1]. However, perovskite was found to be unstable in liquid electrolyte [1, 2]. In 2012, solid-state dye-sensitized solar cell with a PCE of 10.2% [3], which was obtained by using tin containing perovskite CsSnI₃ as a cosensitizer and hole conductor, N719 as a sensitizer, and the CH₃NH₃PbI₃ perovskite sensitized solar cell on Al₂O₃ scaffold with a PCE of 10.9% are the considerable millstone and herald the coming era of perovskite solar cells [4]. Since then, PSCs have been developed at an unprecedented rate. The PCEs of PSCs have evolved rapidly during the past five years. As shown in Figure 1(a), the PCE of perovskite had been boosted up to 15% in 2013 [5, 6]. Then a confirmed efficiency of 17.9% was achieved in early 2014 [7]. Subsequently, the PCE climbed to 19.3% by engineering the interface on a planar device [8, 9]. By November 2014, a new record certified nonstabilized efficiency of 20.1% was achieved by KRICT [10].

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A schematic illustration of the crystal structure of perovskite is shown in Figure 1(b). The general formula for hybrid perovskites is ABX₃, where A is methyl ammonium, B is Pb(II) or Sn(II), and X is Cl, Br, or I, or a coexistence of several halogens. As an exciting material for solar cells, hybrid perovskites combine many in-built advantageous properties. As shown in Figure 2(d) [11], optical properties of perovskites can be tuned by varying the ratio between different halogen elements [11–13]. The most widely studied CH₃NH₃PbI₃ is a direct bandgap semiconductor with a bandgap of 1.55 eV, which determines its absorption offset up to 800 nm [14]. The weak photogenerated exciton binding energy of merely 0.03 eV facilitates the charge separation at ambient temperature [15]. In addition, the small effective masses of electrons and holes generated in CH₃NH₃PbI₃ promote rapid transport of these carriers [16]. The lifetime of the carriers is in the hundreds of nanoseconds’ range, leading to much slower recombination and much longer diffusion length from 100 nm to 1000 nm [15, 17, 18]. Apart from acting by light absorbing, hole-transporting material- (HTM-) free perovskite solar cell showing a PCE of 5.5% highlights the efficient hole-transporting ability of CH₃NH₃PbI₃ [19]. Furthermore, long range ambipolar charge transport was found in CH₃NH₃PbI₃ [20]. All these material properties make perovskites attractive for photovoltaic applications.

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Figure 2

Perovskite synthesis methods and light absorption tuning. (a) Vapour deposition of CH₃NH₃PbI_3−xCl_x. Reprinted from [5]. Copyright: Nature Publishing Group. (b) Mixed cation perovskite ((5-AVA)_x(MA)_1−xPbI₃) prepared by drop-casting a solution of PbI₂, methylammonium (MA) iodide, and 5-ammoniumvaleric acid (5-AVA) iodide onto a double layer of TiO₂ and ZrO₂ through a carbon film. Reproduced with permission from [21]. Copyright: Science. (c) Solution processed CH₃NH₃PbI_3−xCl_x with interface engineering. Reproduced with permission from [9]. Copyright: Science. (d) Colorful CH₃NH₃Pb(I_1−xBr_x)₃ obtained by tuning the chemical composition. Reprinted from [11]. Copyright: the American Chemical Society.

To date, each individual layer of organic-inorganic perovskite solar cells has been investigated and optimized intensively. As the rapid development of PSCs goes on, there is a strong demand for a summary of what achievements the scientists have realized. A summary is also necessary for looking forward to address the existing issues. In this review, we would like to overview the PSCs from the following aspects: perovskite synthesis methods, hole transport materials (HTMs), and photoanode morphologies. Some outlook and challenges for PSCs also will be briefly discussed.

2. Perovskite Synthesis and Optimization

Two synthesis methods of hybrid perovskite are widely used in solar cell applications. The precursor CH₃NH₃I is synthesized by reacting equimolar methylamine with hydroiodic acid under stirring at 0°C for 2 h. Rotary evaporation is often used to recover the CH₃NH₃I from the reaction mixture. The recovered CH₃NH₃I is washed with diethyl ether.

For the one-step method, CH₃NH₃PbI₃ is synthesized by mixing equimolar CH₃NH₃I and PbI₂ in γ-butyrolactone, N,N-dimethylformamide (DMF), or dimethylsulfoxide (DMSO) at 60°C for 12 hours [2]. To synthesize the mixed halides containing perovskite, the ratios between CH₃NH₃I and PbX₂ are varied according to the target perovskite formula [4, 12]. So far, the most successful one-step method case is CH₃NH₃PbI_3−xCl_x which is well illustrated by Yang group with the cell PCE of 19.3% and is summarized in Figure 2(c) [9].

The two-step method, named sequential deposition as well, is a method similar to successive ionic layer adsorption and reaction method (SILAR) for quantum dot synthesis and was developed by Burschka et al. [6]. Typically in this method, PbI₂ is first dissolved in a solvent, such as N,N-dimethylformamide, under stirring at 70°C. Then the photoanodes or substrates are spin-coated with the PbI₂ solution maintained at 70°C, followed by drying at 70°C for 30 min. After cooling to room temperature, the films are dipped into a CH₃NH₃I solution (usually 10 mg/mL in 2-propanol) for 20 s and then rinsed with 2-propanol and dried at 70°C for 30 min [6].

Other novel synthesis methods have been attempted as well. For example, vacuum condition is employed to increase the perovskite purity and uniformity [13, 24]. Vacuum deposition, which involves evaporating and depositing organic and inorganic sources to form perovskite, was introduced by Snaith et al. (Figure 2(a)). Such vapour-deposited planar device showed a PCE of 15.4%, which was higher than that of the solution deposited device, 8.6% [5]. In addition, planar device fabricated via a vapor-assisted solution processing generated a PCE of 12.1% by Yang group [25]. More recently, hybrid chemical vapour deposition was employed to synthesize perovskite. Such device yielded 19% PCE according to the report [26].

Due to the nature of perovskites, finding the optimal conditions and methods necessary to obtain a dense, uniform, and high quality perovskite film still remains a challenge. There are considerable efforts by different groups to optimize the deposition conditions for high quality perovskite films. For example, Carnie et al. codeposited an Al₂O₃/perovskite layer at T < 110°C by adding 5% Al₂O₃ suspension to the CH₃NH₃PbI₃ precursor and a solar cell was fabricated with a PCE of 7.2% [27]. In order to improve the film quality and enhance light harvesting, three ways are attempted: firstly, doping other halide atoms into CH₃NH₃PbI₃ to improve its surface coverage and light absorption. By doping chlorine element into CH₃NH₃PbI₃ while fabricating a planar device, perovskite annealed at 95°C exhibited a PCE over 10% [28]. Colorful light absorbers based on CH₃NH₃Pb(I_1−xBr_x)₃ were synthesized by changing the I to Br ratio (Figure 2(d)). The cells using CH₃NH₃Pb(I_1−xBr_x)₃ with x value from 0 to 0.2 exhibited an average PCE of more than 10% and a maximum PCE of 12.3% [11]. Extremely uniform and dense CH₃NH₃Pb(I_1−xBr_x)₃ (x = 0.1–0.15) film was obtained by using a mixed solvent of γ-butyrolactone and dimethylsulphoxide (DMSO) followed by a toluene drop-casting process when spin-coating the precursor solution [7]. Secondly, methylammonium group could be substituted by other moieties to change its bandgap and film evolution behavior [21, 29]. NH₂CH=NH₂PbI₃ with its bandgap of 1.4 eV showed 7.5% in PSC [29]. More recently, mixed organic cation perovskite was produced by drop-casting a solution of PbI₂, methylammonium (MA) iodide, and 5-ammoniumvaleric acid (5-AVA) iodide onto a double layer of TiO₂ and ZrO₂ through a carbon film. This structured PSC led to a more stable device (>1000 h) with a PCE of 12.8% (Figure 2(b)) [21]. The deep relationship between bandgap and substituents of MA was also investigated. The bandgap of CsPbI₃ is 1.67 eV [30]. The bandgap seems to gradually increase as the size of the substituents of methylammonium group increases [31]. Thirdly, light absorption onset of perovskites could also be tuned by substituting part of the toxic lead with other nontoxic metal elements. CH₃NH₃Sn_1−xPb_xI₃ with series of different metal ratios were synthesized. Their bandgaps were located between 1.17 and 1.55 eV. Consequently, the light absorption could be extended from the visible region to the near-infrared region (~1060 nm), and finally the PSC using CH₃NH₃Sn_0.5Pb_0.5I₃ had a 4.18% PCE [32]. Moreover, lead-free solid-state perovskite solar cells based on CH₃NH₃SnI₃ as the light harvester were first reported by Hao et al. with a PCE of 5.73% [33].

3. HTMs for PSCs

HTMs, just as the name implies, transport the holes to the back electrode when the excitons are dissociated into electrons and holes. Apart from the fast hole transport rate, direct contact to the sensitizer allows HTMs to coexist with the sensitizer and not cause any sensitizer degradation.

3.1. Organic HTMs

The first PSCs adopted CH₃NH₃PbI₃ and CH₃NH₃PbBr₃ as the light absorber and LiI and I₂ containing methoxyacetonitrile as electrolyte. Such PSCs yielded PCEs of 3.8% and 3.1%, respectively [1]. However, perovskite was found to rapidly dissolve into the organic solvent. Much progress was achieved by changing the electrolyte composition and improving the perovskite deposition method. The resultant PSC achieved a PCE of 6.5%, but the devices still lasted for only several minutes [2]. To resolve this dissolution issue, scientists tried to replace liquid electrolyte with solid HTMs. Perovskite CsSnI_2.95F_0.05 was the first perovskite employed to act as both solid HTM and light absorber. Impressively, such PSC construct significantly lifted its PCE to 10.2% [3]. 2,2′,7,7′-Tetrakis-(N,N-dimethoxyphenyl-amine)-9,9′-spirobifluorene (spiro-OMeTAD) was incorporated with mesoporous TiO₂ and Al₂O₃, which showed PCE of 10.9% and generated open-circuit photovoltage up to 1.1 V [4, 34]. By electron coupling with fullerene monolayer on the surface of TiO₂, the device using poly(3-hexylthiophene-2,5-diyl) (P3HT) as HTM realized a PCE of 6.7%, while the device using spiro-OMeTAD as HTM output a PCE of 11.7% [35]. In addition, behaviors of three HTMs, spiro-OMeTAD, P3HT, and 4-(diethylamino)-benzaldehyde diphenylhydrazone (DEH), were compared in CH₃NH₃PbI₃ sensitized solar cells [36]. Hole transfer from CH₃NH₃PbI₃ to HTMs was observed after excitation of CH₃NH₃PbI₃. The electron lifetime in these devices was in the order spiro-OMeTAD > P3HT > DEH, while the charge transport time was similar. Besides, PSC incorporated with spiro-OMeTAD showed the best performances [36]. Tris[2-(1H-pyrazol-1-yl)-4-tert-butylpyridine) cobalt(III) tris(bis (trifluoromethylsulfonyl) imide)] as an additive in spiro-OMeTAD is believed to improve PSC PCE from 8.1% to 10.4% [37]. Moreover, several other organic HTMs were also employed with perovskite to fabricate PSCs. Poly(triarylamine) is another efficient organic HTM. PSCs of CH₃NH₃PbI₃ and CH₃NH₃Pb(I_1−xBr_x)₃ incorporated with poly(triarylamine) realized PCE over 12% [11, 20]. When using conjugated quinolizino acridine as HTM, CH₃NH₃PbI₃ sensitized TiO₂ mesoporous PSC output a better PCE of 12.8% than using spiro-OMeTAD as HTM [38]. With o-methoxy substituents in spiro-OMeTAD as HTM, planar PSC achieved PCE of 16.7% [39]. Carbazole derivatives were adopted as HTMs and fabricated with CH₃NH₃PbI₃ into PSC yielding a remarkable PCE of 14.79% [40].

3.2. Inorganic HTMs

However, the cost of organic HTMs is still high. Low-priced HTMs for reducing the cost of PSCs appear appealing. Compared to organic HTMs, inorganic HTMs are less expensive and attract less attention. PSCs using copper iodide realized a PCE over 6.0% but with an inferior of 0.55 V [41]. The small for the copper iodide based PSCs originated from the unfavorable bandgap. Copper thiocyanate is a more efficient HTM for PSCs. Qin et al. adopted copper thiocyanate to incorporate with CH₃NH₃PbI₃, and the device showed PCE of 12.4% [42]. Nickel oxide is another inorganic HTM due to its large bandgap and deep valance band (5.4 eV). NiO was employed as HTM and the corresponding PSC yielded a PCE of 7.3% [43]. PCE of 11.6% was obtained on a NiO/CH₃NH₃PbI₃ device via introducing NiO_x as electron blocking layer [44]. By employing NO as hole-collecting and hole-conducting layer, CH₃NH₃PbI₃ on planar NiO film output a PCE of 7.6% with the of 1.05 V [45]. By doping NiO_x thin film with copper, the hole transport ability of the resultant film increased remarkably. For the copper-doped NiO_x based PSCs, the environmental stability was much improved, and the PCE was impressively elevated to 15.40% [46].

3.3. HTM-Free PSCs

The device using Al₂O₃ as scaffold stimulated the deep thought of the property of CH₃NH₃PbI₃ [4]. Due to the larger band gap of Al₂O₃, it could not conduct electron from perovskite to the TiO₂ underlayer. The high device performance implies the high electron transport ability of the material [47, 48]. On the other hand, the HTM-free device that generated PCE of 5.5% confirmed the hole transport ability of the perovskite [19]. Theoretically, the high hole transport ability of CH₃NH₃PbI₃ voids the need for using an HTM, which prompts the development of new nanocomposite solar cells: mesoporous scaffold based solar cells (Figure 3(b)). In these structured solar cells, CH₃NH₃PbI₃ is fully infiltrated between the TiO₂, and no additional space is mandatorily needed for HTMs. Such structure could save the thickness of the film to 200–300 nm. Poly(triarylamine) was used as HTM for this new PSC and attained PCE of 12%, suggesting the carrier collection by hole transport through the perovskite was quite effective [20]. By using hybrid composite of single-wall carbon nanotube-PMMA and P3HT as HTM, planar PSC achieved a PCE up to 15.3% and resistance to degradation by water was remarkably improved [49]. Ambipolar structure of CH₃NH₃PbI₃ was verified by transistor measurement [4, 19]. Both electron and hole transport ability pave the way for the planar device.

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4. Photoanode Morphologies for PSCs

Photoanodes, as the support for sensitizer loading, play a vital role in the performance of PSCs. So far, several kinds of PSCs have been developed, such as nanoparticle based PSCs, one-dimensional nanomaterial-based PSCs, planar devices, and flexible devices.

4.1. Nanoparticle Based PSCs

TiO₂ nanoparticles (NPs) are the most common scaffolds that are used for PSCs. Due to the ambipolar charge transport nature of perovskite, as shown in Figures 3(a) and 3(b), the NPs-based PSCs can be categorized into two structural PSCs. The one similar to traditional solid-state semiconductor sensitized solar cells is shown in Figure 3(a). In this structure, the mesoporous TiO₂ film usually acts as an electron extraction layer, transporting photogenerated electrons to the electron collector electrode (as the red arrow shown in Figure 3(a)), while the perovskite mainly acts as a sensitizer. The holes are primarily transported by the penetrated HTM (black arrow shown in Figure 3(a)). A representative PSC of this structure is the mesoporous Al₂O₃ based PSC, which has a PCE of 10.9%, while the mesoporous TiO₂ based PSC has a PCE of 7.6% [4]. The PCE of the mesoporous TiO₂ based PSC was improved to 9% [34] and to 12.8% [38] subsequently. By using commercial carbon as the counter electrode, CH₃NH₃PbI₃ sensitized mesoporous TiO₂ solar cell achieved a PCE of 8.31% with a good stability [50]. Theoretically, the liquid electrolyte based PSCs also belong to this kind of PSCs. The first reported liquid electrolyte based CH₃NH₃PbI₃ and CH₃NH₃PbBr₃ sensitized solar cells employed ~15 nm sized, 8–12 μm TiO₂ NP films which provided a large surface area for perovskite loading [1].

According to the literatures summarized in the Hole Transport Materials section, the unique ambipolar charge transport property of perovskites renders the photoanode no longer needed to spare much space for HTMs in the PSC architecture. Therefore, a new kind of PSC, which had the interstitial spaces between the photoanode NPs being completely filled with perovskite (Figure 3(b)), is developed. In this kind of PSCs, photogenerated electrons in the perovskite diffuse through the perovskite to the nearest TiO₂ NPs and then are transported along the TiO₂ skeleton to the electron collector electrode (the red arrow in Figure 3(b)). Holes are transported by the perovskite (the black arrow in Figure 3(b)). The first HTM-free PSC was fabricated using TiO₂ nanosheets as a support, and CH₃NH₃PbI₃ was deposited on TiO₂ nanosheets. Such device generated a PCE of 5.5%. In this architecture, CH₃NH₃PbI₃ was believed to act as both light harvester and HTM [19]. The Au@SiO₂ nanoparticle (NP) based PSC delivering a device efficiency of up to 11.4% was reported, in which the enhanced photocurrent was attributed to the reduced exciton binding energy due to the incorporation of metal NPs rather than the enhanced light absorption [51]. of ~1.3 V was obtained by a CH₃NH₃PbBr₃ PSC on the TiO₂ NP scaffold [52]. In addition, mesoporous TiO₂ film was used to anchor CH₃NH₃Pb(I_1−xBr_x)₃ to tune its light absorbing property and such device achieved the highest PCE of 12.3% [11]. To date, a certified PCE of 17.9% was realized by the CH₃NH₃PbI_3−xBr_x (x = 0.1–0.15) PSC on a TiO₂ NP scaffold [7]. Up to now, this is the highest reported PCE for mesoporous NP-based PSC.

Unlike the dye-sensitized solar cells and other semiconductor-sensitized solar cells, different shaped TiO₂ NPs are not the focus for PSCs. However, as is introduced above, NPs-based PSCs show a great prospect to exhibit high PCE.

4.2. NR Based PSCs

One-dimensional nanomaterials are believed to promote electron transport, elongate electron lifetime, increase diffusion length, and slow down the electron and hole recombination [53–56]. A PCE of 9.4% was achieved on a 600 nm thick TiO₂ nanorod array photoanode. Results showed that longer NRs deteriorated the and the charge generation efficiency (Figure 4(a)) [22]. Qiu et al. reported a PSC with a PCE of 4.87% using CH₃NH₃PbI₂Br as light absorber with TiO₂ nanowire arrays. The PCE of this PSC was higher than that of CH₃NH₃PbI₃ solar cell [57]. The device using 1D ZnO incorporated with CH₃NH₃PbI₃ also showed a PCE of 11.13% with the short-circuit current density of 20.08 mA/cm², the open-circuit voltage of 991 mV, and fill factor of 0.56 (Figure 4(b)) [23].

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Although the literatures on 1D nanomaterial-based PSCs are not as many as those of the NP-based or planar PSCs, the superior ambipolar charge transport of perovskite does not require the large specific surface area from the scaffolds, which would compensate for the drawbacks of 1D nanomaterials. Owing to the superior charge transport of 1D nanomaterials, they might function synergistically with perovskites in PSCs application.

4.3. Planar Devices

The ambipolar charge transport property of CH₃NH₃PbI₃ simplifies the architectures of PSCs. Because of the self-charge transport property towards electrons and holes together with the light absorbing property, the PSCs can work without the scaffold and HTMs. A simple planar heterojunction solar cell was fabricated without the metal oxide scaffold, incorporating vapour-deposited perovskite as the absorbing layer and spiro-OMeTAD as the HTM. Such PSC had a PCE up to 15.4% (Figure 2(a)) [5]. Planar CH₃NH₃PbI₃ perovskite/fullerene planar heterojunction hybrid solar cell was developed with a PCE of 3.9%, and its interfaces were tuned by conducting polymers, where CH₃NH₃PbI₃/fullerene interface was verified as the donor-acceptor interface [58]. By evaporating CH₃NH₃I at 150°C to react with the PbI₂ film, Chen et al. developed a vapor-assisted solution process to fabricate a full coverage and small roughness planar heterojunction CH₃NH₃PbI₃ device, which yielded a PCE of 12.1% [25]. Another newly structured planar PSC, which had CH₃NH₃PbI₃ sandwiched between two thin organic charge-transporting layers, reached a high PCE over 12% [24]. By tuning the interface states and matching the band diagram, a record PCE of 19.3% on a planar device was obtained by Zhou et al. recently [9].

The PSC PCE race joined by scientists all over the world is still ongoing. It is too early to draw any conclusion to what record PCE of PSCs can be achieved. However, the surging PCEs of planar PSCs and ease of fabrication of planar devices imply that future PSCs may adopt such simple configuration.

4.4. Flexible PSCs

PSCs on flexible substrates are advantageous for a few reasons. Such PSCs are much more portable and practical for mobile electronics, such as cell phones and laptops. They can also save more space and are not easy to break. The low processing temperature of perovskites will promote the realization of flexible PSCs.

As a part of PSCs research, lots of efforts are put into designing flexible PSCs. The PSC with substrate/PEDOT: PSS/CH₃NH₃PbI_3−xCl_x/PCBM/TiO_x/Al configuration was fabricated on ITO-coated plastic foil with a PCE over 6% [59]. The PCE of flexible PSC was subsequently improved to 9.2% by Yang group [60]. Carbon nanotubes were used as the hole collector and the support for CH₃NH₃PbI₃ loading. Such HTM-free device realized PCE of 6.87%. By using spiro-OMeTAD as the HTM, the PCE was improved to 9.90% [61]. By replacing the TiO₂ dense electron transport layer with ZnO on conducting flexible substrate and adopting spiro-OMeTAD as the HTM, CH₃NH₃PbI₃ PSC fabricated at 100°C yielded a PCE of 15.7%, which is close to the record PCE [62]. However, these achievements still seem far away for practical applications.

5. Challenges and Perspective

Even now, rapid progress takes place every day, faster than ever in photovoltaic field. The PCE of 19.3% realized by Yang group [9] is a huge step towards real life applications. Scientists anticipate that PCEs of 28 to 30% are feasible in the near future by fabricating perovskite and crystalline silicon cells in a tandem configuration [47].

Nevertheless, stability is still a big challenge for PSCs. CH₃NH₃PbI₃ is very sensitive to polar solvents such as water. It readily dissolves and decomposes into PbI₂ rapidly. Up to now, only a few studies on stability have been reported [6]. These reports concluded that the HTM with long alkyl chains and without deliquescent additives would reduce the water filtration and prevent sensitizer corrosion and improve the humidity stability [63]. Carbon material used as the back contact is believed to act as a water-retaining layer as well. The PCE of the device did not show a decrease after exposure to air for over 1000 hours [21]. However, there is still a long way to go to meet the rigid requirement for long-term outdoor practical applications. On the other hand, the longtime UV exposure stability is another problem for PSCs. Snaith et al. investigated the effect of longtime exposure towards UV light on the performance of PSCs. The performance of PSCs would decay due to the light-induced desorption of surface-adsorbed oxygen on mesoporous TiO₂. However, TiO₂-free PSCs are protected from this instability [64].

Toxicity of heavy metal lead to people and the environment is another big concern for scaling up production of PSCs. Scientists are attempting to synthesize lead-free perovskites [5, 64]. The PSC incorporating CH₃NH₃SnI_3−xBr_x, a lead-free perovskite, and spiro-OMeTAD produced a PCE of 5.73% [33]. Another alternative is CH₃NH₃SnI₃ on a TiO₂ scaffold, which achieved a PCE of 6.4% [65]. To prevent environmental pollution from lead, perovskites made from lead-free composition are likely to be the next widely researched area for PSCs. In general, before making full use of the PSC technology, all the above issues need to be addressed.

Conflict of Interests

The authors declare no competing financial interests.

Acknowledgments

Sean Hwang is much thanked for his language processing. This work was supported by the State Scholarship Fund of China Scholarship Council.

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Copyright © 2015 Guiming Peng et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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