Abstract

This paper deals with findings on dynamic mechanical analysis (DMA) and ion-conduction behavior of MWNTs (multiwall carbon nanotubes) doped PVA:NH4SCN:DMSO dried gel electrolyte system prepared for four filler concentrations (2, 4, 6 & 8 wt%) by solution cast technique. XRD measurements reveal enhancement in amorphous behavior of composite gel electrolyte upon incorporation of filler particles. Better mechanical stability is noticed in the composite system upon dispersal of MWNT along with presence of dynamic during DMA measurements. Enhancement in ionic conductivity has been noticed with an optimum value of 4.5 × 10−3 Scm−1 for 6 wt% MWNTs filled composite electrolyte. Composite system exhibits combination of Arrhenius and Vogel-Tammam-Fulcher (VTF) behavior in temperature dependent conductivity study. The a.c. conductivity response seems to follow universal power law.

1. Introduction

During the past two decades, there has been a progressively increasing interest in ionically conducting membranes possessing properties that enables them to replace the conventional liquid electrolyte used as separators in electrochemical devices [1]. In designing a novel polymer electrolyte, emphasis is placed on increasing the amorphous content in the polymer which assists fast ion motion while maintaining its mechanical stability [2]. Various polymer matrix systems that have been studied for this purpose include PEO (polyethylene oxide) [1, 3, 4], PVA (polyvinyl alcohol) [2, 5], PVdF (polyvinylidene fluoride) [6], and PVP (Poly vinyl pyrrolidone) [7]. Among these polymer hosts, PVA has been prominently studied due to its excellent biocompatibility, electrochemical stability, and solvent-swollen ability [2, 5]. Further, this polymer contains hydroxyl groups attached to methane carbons which are active sites for complexation with various salts and acids [8]. Owing to the possibility of achieving maximal ionic conduction with protons/ ions as transporting specie in polymer electrolyte systems, impetus has also been given to development of proton conducting polymer electrolytes in recent times. Awadhia and Agrawal [5] have reported ionic conductivity of the order of 10−3 Scm−1 in Polyvinyl alcohol-ammonium thiocyanate-dimethyl sulphoxide (PVA-NH4SCN-DMSO) dried gel electrolyte. However, it is difficult to use such a system in devices due to insufficient ionic conductivity and poor mechanical stability at ambient temperature when samples are kept over prolonged time periods. These drawbacks have been reduced considerably by using a third component in pristine polymer electrolytes matrix leading to emergence of composite polymer electrolytes in recent past [9, 10].

After the advent of nanotechnology, researchers have also used dispersion of a third component of nanodimensions in pristine polymer electrolytes in a bid to circumvent problems cited above. Thus, efforts have been directed in recent past to develop high performance nanocomposite polymer electrolytes [11, 12]. Generally, nanostructural particles like ceramics [12, 13] and carbon nanotubes [14] have not only been shown to improve the mechanical properties of gel and solid polymer electrolyte membranes and their nanofibers but they have also provided improved conductivities to allow their usage in sensors, super capacitors, batteries, electronic components, and so forth [15]. Carbon nanotubes (CNTs) are considered as an ideal reinforcement material for polymer nanocomposites [14, 15], as the mechanical properties of the polymer composites are strongly influenced by their morphology and crystallization behaviour [1618]. Though CNT is electronic in nature, the surface groups present are likely to promote charge dissociation leading to improved ionic conductivity. Hence, it is very instructive to characterize CNT-reinforced proton conducting polymer nanocomposite electrolytes. Based on these considerations, efforts have been made in the present work to develop a sufficiently dry free standing proton conducting composite gel membranes of PVA:NH4SCN dispersed with multiwall carbon nanotubes (MWNTs) and characterise them structurally and electrically.

2. Materials and Methods

In this study, PVA (average molecular weight 124,000–186,000 Aldrich make), ammonium thiocyanate (NH4SCN), AR grade sd. fine chem. make, and aprotic solvent dimethyl sulphoxide (DMSO) Merk limited, Mumbai, make were chosen for synthesis of nanocomposite polymer electrolyte (NCPE). MWNT used in the study was obtained from Aldrich, CAS Number: 308068-56-6, possessing average diameter 110–170 nm and length 6–9 μm. PVA was dispersed in 1 M salt solution of NH4SCN in DMSO in different stoichiometric ratios to form pristine electrolyte (PE). Composite polymer electrolytes (CPE) were prepared by adding MWNTs in PE solution in different weight fractions (2 to 8 wt%) followed by thorough mixing for nearly 8 hours at 45°C on a magnetic stirrer. The so obtained viscous solution was poured in polycarbonate pettridishes to gellify. Containers were covered with Al-foil to avoid contamination and kept for 7–10 days. After syneresis gel in the form of thick film was obtained. The films were taken out and dried at 60°C in air for 15 days for exudation of unwanted liquid to obtain dried composite polymer gel electrolyte films.

Dynamic mechanical analysis (DMA) was carried out on a dynamic mechanical spectrometer (model DMS 6100 SSI Nanotechnology Inc., USA). DMA runs were recorded at 3°C heating rate. Measurement of storage modulus (E′), loss modulus (E′′), and tan of dried gel electrolyte samples was performed in compression mode at 10 Hz frequency in the temperature range 25°C to 200°C.

X-ray diffraction (XRD) patterns of films were recorded on X-ray diffractometer (RIGAKU, JAPAN make, model MINIFLEX-II). The diffraction patterns were recorded at room temperature (~30°C) for the Bragg angle (2θ) varying from 2° to 90° with  Å.

The complex-impedance measurements were carried out with help of a computer controlled Hioki (Japan) make LCR meter (Model 3520). The solid composite electrolyte was sandwiched between two platinum electrodes to measure electrical conductivity in the frequency range 40 Hz–100 kHz at different temperatures ranging in between 30°C and 100°C. a.c. conductivity has been calculated from impedance data using the relation where (relative permittivity) = ,   is the permittivity of the free space, , is the frequency of the applied field.

3. Results and Discussion

3.1. Dynamic Mechanical Analysis

Occurrence of molecular mobility transitions, such as dynamic glass transition temperature () and other mechanical relaxations can be studied with the help of ε′, ε′′ and Tan δ versus plot. Variation in E′ (storage modulus), E′′ (loss modulus) and Tan δ (loss tangent or damping factor) with temperature for composite and pristine electrolyte films are shown in Figures 1 and 2. It is apparent from Figure 1 that storage modulus E′ enhances in general upon introduction of filler particles in matrix electrolyte below 100°C indicating improvement in mechanical stability of the system. However, the peak flexural storage modulus diminishes with increasing CNT content. Careful examination of modulus data shows that CNT soaked films give rise to dynamic of composite system coupled with transition related to melting of composite electrolyte system in the temperature range 120–160°C. Existence of dynamic in composite system dispersed with particles of nanodimensions has been earlier reported by Tsagaropoulos and Eisenberg [14]. Increasing CNT content shifts melting related peaks to lower temperature and ultimately convolutes the separate transitions into a broader transition at 6 wt% CNT. When CNT content is added in excess of 6 wt% it causes reappearance of CNT and composite related transitions. These observations show maximum intercalation of 6 wt% CNT content in matrix electrolyte and suggest that the mechanical stability of nanocomposites increases with filler loading till 6 wt%. Simultaneously, the decreasing nature of storage modulus beyond 6 wt% MWNTs, suggest loss in molecular mobility of the polymer matrix. This can be attributed to agglomeration of filler particles (caused by Van-der Waal force among nanotubes) rendering large surface area, which diminishes filler-polymer interaction [19]. It is probably due to the presence of salt (NH4SCN) ions intercalated with nanotubes within polymer matrix affecting the crystallisation process and thus they play a role of plasticization effect [20].

Figure 2(a) shows the variation of loss modulus with temperature for different MWNTs filler concentration in pristine electrolyte. A small broad transition around 50°C is noticed in E′′ view graph (present in all samples) which is essentially due to interaction of DMSO with PVA [5]. Pure PVA powder used in the present investigation possesses a glass transition of nearly ~85°C and has been reported in one of our earlier papers [8]. This transition shifts towards higher temperature in nanocomposite polymer electrolyte with MWNT level upto 4 wt% and transforms into well-defined broad peak in E′′ & tan δ reflecting dynamic of PVA in NCPE and also referred as a α relaxation [11]. Further, a small shoulder around 98°C has been traced in E′′. This can be correlated to presence of water formed in the process of interaction of DMSO with PVA and has been reported earlier [11]. This transition shifts on temperature scale towards lower temperature with increase of MWNT contents (Table 1). The loss spectra of pristine complex show a well-defined peak around 120°C. This can be assigned to presence of bound water in pristine system. Existence of this water has also been shown earlier [11]. A shoulder relaxation around 150°C gives reflection of the presence of uncomplexed salt in electrolyte on account of melting of salt [12]. The loss spectra show a well-defined peak around 160°C (Table 1). This can be assigned to complexation caused by interaction among components and therefore referred to as composite of NCPE system. Kerr et al. [21] have reported that when the fillers are of nanodimension and the concentration of filler particles is optimum, a composite or second may be observed in dynamic mechanical behaviour at higher temperatures. The composite is attributed to σ relaxation. The σ relaxation peak is possibly due to breakage of hydrogen bonding between polymer chains which induces long segmental chain movement in the amorphous area [1, 5].

Figure 2(b) which shows the tangent loss plot of dried films of composite electrolyte is a manifestation of the results obtained in Figure 2(b). In this graph, a major and few other shoulder peaks appear for all stoichiometric ratios. These peaks also show the presence of α and σ relaxations as discussed earlier.

3.2. XRD Studies

The XRD patterns of MWNTs filled polymer composite electrolyte films along with pristine electrolyte and pristine components are shown in Figure 3. These patterns show in general an increase in amorphousness of polymer electrolytes on addition of MWNT filler. This is reflected from the decrease in intensity for all the major peaks along with increase in broadening. Intercalation of CNT contents with electrolyte matrix results in such a behavior. Two peaks appear in the diffractogram of pristine electrolyte (Inset Figure 3(d)), which do not correspond to either NH4SCN salt or PVA and thus has been earlier correlated to formation of PVA:NH4SCN complex. Further, these observations also corroborate the results of Awadhia and Agrawal [5] who have reported interaction of NH4SCN with PVA leading to formation of PVA-NH4SCN complex. When 2 wt% MWNT filler is loaded in pristine electrolyte (Figure 3(e)), the peaks seem to broaden up in XRD profile besides emergence of a broad peak around 26.1°. It is apparent from comparison of XRD profile “a” (inset Figure 3(a)) with profile “e” that 26.1° peak in diffractogram “e” essentially corresponds to MWNT [14]. Further, the broadening seems to result from intercalation of MWNT in electrolyte matrix. Though complex related main peak shifts towards lower 2θ values as a result of polymer salt filler interaction, existence of MWNT related XRD peak shows that MWNT essentially acts as passive filler and is responsible only for change in film morphology [22]. On addition of 4 wt% MWNTs content (Figure 3(f)), the main peak (PVA:NH4SCN complex related peak) is seen to shift to higher 2θ value along with increase in broadness and further loss of intensity. This can once again be attributed to polymer-salt-filler interaction [2224]. On further extending MWNT loading to 6 and 8 wt% (Figure 3  (g) and (h)), complex related peak again shifts towards lower 2θ value with increasing intensity. At higher concentration of MWNT (Figure 3(h)), the characteristic reflections of filler start reappearing because of its segregation. From X-ray diffraction study, it is thus concluded that MWNTs upon dispersal significantly improves the amorphous behavior of polymer electrolyte.

Degree of crystallinity Xc of electrolytes with respect to MWNT was estimated to ascertain improvement in amorphous nature [12] presuming filler to be fully crystalline (Table 2). The structural parameter calculated for pristine electrolyte and MWNT doped electrolytes from Scherrer’s equation are given in Table 2. It is observed that the crystallite size and degree of crystallinity decreases upon addition of MWNT in pristine electrolyte. Though the average crystallite size increases marginally with MWNT loadings, degree of crystallinity dips continuously. These observations ascertain enhancement in the degree of disorder and amorphousness in the polymeric membranes on loading electrolytes with MWNTs [20, 25]. Further average crystallite size of nanomatric size is restricted for all the samples indicating formation of nanocomposite electrolytes subsequent to MWNT dispersal.

3.3. Frequency Independent (d.c.) Conductivity

Figure 4 shows the effect of dispersal of MWNTs on the ion conduction properties of polymer composite dried gel electrolytes. It is apparent from this figure that the conductivity of composite electrolyte improves slightly in magnitude till 2 wt% and thereafter decreases till 4 wt% before rising again and ultimately falling off beyond 6 wt% MWNT concentration in composite electrolyte. This feature is typical of nanocomposite polymer electrolytes [2528]. XRD studies have shown intercalation of MWNTs in pristine electrolyte. This intercalation is likely to promote dissociation of salt leading to enhancement in the value of carrier concentration thereby causing increase in conductivity values [12, 14]. Such a conclusion is envisaged on the fact that Lewis acid-base interactions between the heterogeneously dispersed filler surface and anions compete with interactions between cations and anions promoting salt dissociation via a sort of ion-filler complex formations [29]. Polymer-filler-salt interaction has also been noticed in XRD profiles (Figure 3) through shifting of diffraction peaks in the presence of filler particles (Section 3.2). At higher concentration of nanofillers, the nano filler particles serve as cross linking centres for polymer segments causing immobility of polymer chains in accordance with Tsagarapolous model [14]. Thus conductivity drops significantly. At intermediate concentrations the decrease in conductivity may be due to pairing effect/re-association of free ions [1, 5, 21]. The second conductivity maxima is related to formation of highly conducting interfacial layer between MWNT and gel electrolyte caused by filler salt interaction which dominates over ion pairing effect [6, 11, 14, 24].

Ionic conductivity of polymer electrolytes is known to augment with rise of temperature and the behaviour has been rationalised by recognizing free volume model [30]. This in turn positively affects the mobility of ion and polymer segments resulting in rise of bulk conductivity. The amount of increase in conductivity thus depends upon the free volume around the polymer chain. Present investigations too show an enhancement in bulk conductivity of composite system with increasing temperature (Figure 5). Arrhenius and Vogel-Tammam-Fulcher (VTF) relation [31] have been successfully used to describe temperature dependence of ionic conductivity of polymeric systems. In the low temperature regime (below 50°C) segmental motion of chain segments obstructs the easy motion of charge carriers as polymer enters into viscoelastic phase [5, 32]. Hence, conductivity rise is limited. Further as the filler concentration increases in composite electrolytes, conductivity values significantly drop down owing to increasing tortuous pathways created by agglomeration of filler particles [13]. Thus, it seems that the nanocomposite solid electrolytes membranes behave as an ionic solid in which the mechanism of ion diffusion involves ion–polymer segment coupling such as conventional polymer electrolytes [33].

3.4. Frequency Dependent (a.c.) Conductivity

Analysis of frequency dependent electrical response of solid electrolytes with disordered structure is a versatile approach for understanding the nature of ionic transport. The variation of a.c. conductivity for pristine electrolyte and nanocomposite polymer electrolyte doped with two MWNT loadings as a function of frequency is shown in Figure 6. It is apparent that a.c. conductivity increases with frequency in the low frequency regime followed by a nearly frequency independent behavior in the high frequency regime for all electrolyte systems. The increasing conductivity behavior is connected to the electrode-electrolyte phenomena that is, it results from electrode polarization effects [13], while saturation like behavior results from the failure of hopping of ions from one site to another with increasing frequency. The overall a.c. conductivity can be best described by Jonscher’s power law expressed aswhere is the d.c. conductivity (the extrapolation of plateau region to zero frequency gives the value of dc conductivity), A the preexponential factor and the fractional exponent between 0 and 1. This kind of behavior has been reported for wide range of nanocomposite polymer electrolytes [14, 17] and also for PVA:DMSO:NH4SCN:Al2O3 electrolytes. It is observed that the increase in filler content enhances a.c. conductivity. The calculated value of power law exponent (), generally for ionic conductor can be in between 1.0 and 0.5, indicating the ideal long-range pathway and diffusion limited hopping [34]. If the motion is completely random and independent Debye like ion hops. In the present case, the exponent factor was found to be 0.56 for pristine electrolyte and it increases to 0.61 for 6 wt% MWNT loading (Table 3) which suggest supportive role played by MWNT particles in ion conduction. The observed frequency dispersion for different composite can be rationalized with the help of jump relaxation model [35] since the dynamical effect of polymer host caused by segmental renewal rates, is less significant below microwave frequencies. According to this model, an ion can hop from a site to neighbouring vacant site successfully to contribute to conductivity. At high frequencies the probability for ion to hop back increases due to short time periods. This forward-backward hopping at high frequencies together with relaxation of dynamic cage potential seems to be responsible for high frequency plateau [13, 35]. It has been observed that the maximum value of a.c. conductivity was found to be 4.1 × 10−3 S/cm for 6 wt% MWNTs concentration at room temperature.

4. Conclusions

The objective of this study was to investigate the role of MWNT filler on the dynamic mechanical and electrical properties of the PVA:NH4SCN:DMSO system. Experimental investigations show that dynamical values (shift from 102 to 87.6°C) and other mechanical relaxation parameters like storage and loss modulus of nanocomposite electrolytes are affected by the presence of filler. Also the mechanical strength and stability of polymer electrolytes is immensely improved in the presence of MWNT filler (increase in storage modulus in magnitude). XRD patterns exhibit broadening of diffraction patterns of composite system on addition of fillers suggesting improved amorphousness (decrease in crystallinity from 26% to 3.2%; Table 2). Addition of MWNT in PVA:NH4SCN:DMSO system improves its ionic conductivity which is associated to improved amorphous behaviour of films. The optimum ionic conductivity is achieved (4.5 × 10−3 S/cm) for 6 wt% MWNT loaded membranes. Such high ionically conductive membranes with superior mechanical stability suggest their applicability in electrochemical devices particularly high performance solid state batteries.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.