Morphology Effect on the Kinetic Parameters and Surface Thermodynamic Properties of Ag₃PO₄ Micro-/Nanocrystals

Table 2

Activation energy, activation Gibbs free energy, activation enthalpy, and activation entropy of Ag₃PO₄ micro-/nanocrystals.

Ag3PO4; Micro-/nanocrystals	T (K)	(kJ⋅mol^−1)	(kJ⋅mol^−1)	(kJ⋅mol^−1)	(J⋅K^−1⋅mol^−1)
Cube	298.15	87.132	8.653	6.093	−271.831
	303.15	88.518
	308.15	89.852
	313.15	91.204
	318.15	92.585
Rhombic dodecahedra	298.15	87.222	8.990	6.430	−270.987
	303.15	88.583
	308.15	89.941
	313.15	91.290
	318.15	92.643
Bulk	298.15	87.462	11.548	8.988	−263.123
	303.15	88.726
	308.15	90.056
	313.15	91.393
	318.15	92.708