Influence of Shell Parameters on Optical Properties of Spherical Metallic Core-Oxide Shell Nanoparticles

Pustovalov, Victor K.; Astafyeva, Liudmila G.

doi:https://doi.org/10.1155/2015/812617

Journal of Nanomaterials

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Computational Modeling of Physical and Chemical Properties of Nanomaterials

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Volume 2015 | Article ID 812617 | https://doi.org/10.1155/2015/812617

Influence of Shell Parameters on Optical Properties of Spherical Metallic Core-Oxide Shell Nanoparticles

Victor K. Pustovalov¹and Liudmila G. Astafyeva²

Academic Editor: Ottorino Ori

Received30 Dec 2014

Accepted21 Jan 2015

Published04 Oct 2015

Abstract

Different metal homogeneous nanoparticles have been extensively studied in recent years due to their wide range of potential applications. It is very interesting to investigate core-shell nanoparticles with oxide shell from core metal. The formation of oxide shell on metallic nanoparticles can be achieved by different chemical and physical methods including also natural oxidation of pure metallic nanoparticles in gaseous or liquid media, containing oxygen components (air, water, etc.). We numerically calculated efficiency factors of absorption K_abs, scattering K_sca, and extinction K_ext of radiation with wavelength λ in the spectral interval 150–1000 nm by spherical homogeneous metallic and two-layered (metal core – oxide metal shell) nanoparticles: Al, Al-Al₂O₃ and Zn, Zn-ZnO with core radii in the range 5–50 nm and shell thickness 5 nm. Analysis of presented results has been carried out.

1. Introduction

Recent advances in photothermal nanotechnology based on the use of nanoparticles (NPs) and optical (laser) radiation have been demonstrated their great potential. In recent years the absorption and scattering of radiation energy by NP have become a great interest and an increasingly important topic in photothermal nanotechnology [1–27] (also see the references in these papers). There are many reasons for this interest in nanophotonics including applications of NPs in different fields, such as catalysis [1, 2], nanoelectronics [3, 4], nanooptics and nonlinear optics [5, 6], and energetic nanotechnology (e.g., photovoltaics [7] and light-to-heat conversion [8, 9]). Laser applications in nanotechnology include laser nanobiomedicine [10–15] with determination of selected properties of NPs [16, 17] and laser processing of metallic NPs in nanotechnology [18–23]. Metallic NPs are mostly interesting for different nanotechnologies among other NPs.

In recent years, the optical properties of metal NPs have been under extensive research mainly due to their unique optical properties arising from the localized surface plasmon resonance (LSPR) [25–30]. The LSPR causes a relatively narrow absorption peak, which leads to high optical selectivity. Most of the abovementioned technologies rely on the position and strength of the surface plasmon on a nanosphere and successful applications of NPs in nanophotonics are based on appropriate plasmonic and optical properties of NPs. High absorption of radiation by NPs can be used for conversion of absorbed energy into NP thermal energy, heating of NP itself and ambient medium, and following photothermal phenomena in laser and optical nanotechnology and nanomedicine. High scattering of radiation is used as a powerful tool in optical diagnostics and biological and molecular imaging.

Different metal (gold, silver, platinum, zinc, etc.) NPs have been extensively studied in recent years due to their wide range of potential applications [1–30]. Thermooptical analysis and selection of the properties of metal NPs for laser applications in nanotechnology were carried out in [9, 16, 17, 25–30]. Metal NPs have their LSPR in the ultraviolet and visible spectral intervals of optical radiation. The possibility of controllably tuning the LSPR wavelength through the visible to near infrared region is very important and promising for the technological applications. Possible effective way of adjusting NP optical properties and shifting the LSPR peak position to near-infrared wavelength is to combine the metal NPs with dielectric material and by changing the NP geometrical parameters.

Recently, in addition to pure metal NPs also metal-dielectric (dielectric-metal) core-shell NPs are studied for the improvement and manipulation of the plasmon resonances of NP properties. For example, SiO₂-gold and gold-SiO₂ core-shell NPs are widely investigated and applied in experiments [10, 16, 31–33]. The position of the LSPR for such core-shell NPs is strongly influenced by the presence of the geometrical characteristics: the core radius, the thickness of the oxide layer, and the ratio between them [10, 16, 31–33].

But in many cases oxide (dielectric) shells are formed on the surface of metal NPs and we investigate core-shell NPs with oxide shell from core metal. The formation of oxide shell on metallic NP can be achieved by different chemical [33, 34] and physical [35] methods. The formation of thick oxide shell promotes the use of core-shell metal-oxide NPs in chemical nanotechnology. The presence of oxide shell on metallic NP surface can prevent the origination of chemical reaction on NP surface in chemical reactive atmosphere and further consequences that can be used in some technologies.

Natural oxidation of pure metallic NPs in gaseous or liquid media, containing oxygen components (air, water, etc.), leads to the formation of thin oxide shell with thicknesses of about 3–5 nm on metallic NPs and core-shell two-layered metallic-oxide NPs during short period of time. The action of intensive optical (laser) radiation and NP heating can cause oxidation of surface layer of metallic NP and the formation of oxide shell on NP. The laser processing of metallic NPs in air atmosphere can cause simultaneously increasing of oxide shell thickness on particle surface and its evaporation [35].

The fabrication and investigation of core-shell NPs formed by a metal core and its own oxide shell were carried out in [36–46]. For example, Ag-Ag₂O NPs were investigated by physical and chemical methods in [36–39] and Al-Al₂O₃ NPs were experimentally investigated in [40–42]. Determination of the oxide layer thickness in core-shell zerovalent iron NPs was made in [43]. Investigation of microstructure control of Zn-ZnO core-shell NPs was carried out in [44]; the surface plasmon resonance of Cu-Cu₂O core-shell NPs was studied in [45].

On the other side, a comparative analysis of the optical parameters of different metal-oxide NPs for using them as agents in laser nanotechnology is still missing. In this paper, we study systematically influence of shell parameters on optical properties of spherical metallic core-oxide shell Al-Al₂O₃, Zn-ZnO NPs using a computational method.

2. Numerical Results and Discussions

We numerically calculated the efficiency factors of absorption , scattering , and extinction K_ext of radiation with wavelength by spherical homogeneous and two-layered NPs on the base of Mie theory [26]. Numerical results are presented for cases of homogeneous metallic and two-layered (metal core, oxide metal shell) NPs: Al, Al-Al₂O₃, and Zn, Zn-ZnO. Values of optical indexes of refraction and absorption of metals, oxides, and surrounding media were used from [46–49]. Figures 1–4 presented below describe the dependencies of efficiency factors of absorption , scattering , and extinction K_ext for homogeneous (Figures 1(a)–1(c), 2(a)–2(c), 3(a)–3(c), and 4(a)–4(c)) and two-layered NPs (Figures 1(e)–1(l), 2(e)–2(l), 3(e)–3(l), and 4(e)–4(l)) on radiation wavelength, NP core radii, and shell thickness. The positions , , and of maximum values of efficiency factors of , , and on axis are denoted in Figures 1–4 by different vertical lines; locations of maximum value of absorption factor on axis are denoted by solid lines, , dashed lines and , dashed-dotted lines in the case of different values of , , and . In some cases solid lines denote the simultaneous locations of all maximums of efficiency factors. We investigated two situations, when NPs were placed into two different surrounding media, air and water.

Figure 1

Dependencies of the efficiency factors of absorption (solid), scattering (dashed), and extinction K_ext (dashed-dotted) of radiation and parameter (solid) on wavelength for spherical homogeneous Al NPs with radii (a), 25 (b), and 50 (c) nm, for (1), 25 (2), and 50 (3) nm (d), for two-layered core-shell Al-Al₂O₃ NPs with shell thicknesses nm, (e), 20 (f), and 45 (g) nm, for core-shell NP radii (1), 25 (2), and 50 (3) nm (h); for Al-Al₂O₃ NPs with nm and (i), 25 (j), and 50 (k) nm, and for (1), 30 (2), and 55 (3) nm (l). NPs are placed in air.

Figure 2

Dependencies of the efficiency factors of absorption (solid), scattering (dashed), and extinction K_ext (dashed-dotted) of radiation and parameter (solid) on wavelength for spherical homogeneous Al NPs with radii (a), 25 (b), and 50 (c) nm, for (1), 25 (2), and 50 (3) nm (d), for two-layered core-shell Al-Al₂O₃ NPs with shell thicknesses nm, (e), 20 (f), and 45 (g) nm, for core-shell NP radii (1), 25 (2), and 50 (3) nm (h), for Al-Al₂O₃ NPs with nm and (i), 25 (j), and 50 (k) nm, and for (1), 30 (2), and 55 (3) nm (l). NPs are placed in water.

Figure 3

Dependencies of the efficiency factors of absorption (solid), scattering (dashed), and extinction K_ext (dashed-dotted) of radiation and parameter (solid) on wavelength for spherical homogeneous Zn NPs with radii (a), 25 (b), and 50 (c) nm, for (1), 25 (2), and 50 (3) nm (d), for two-layered core-shell Zn-ZnO NPs with shell thicknesses nm, (e), 20 (f), and 45 (g) nm, for core-shell NP radii (1), 25 (2), and 50 (3) nm (h), for Zn-ZnO NPs with nm and (i), 25 (j), and 50 (k) nm, and for (1), 30 (2), and 55 (3) nm (l). NPs are placed in air.

Figure 4

Dependencies of the efficiency factors of absorption (solid), scattering (dashed), and extinction K_ext (dashed-dotted) of radiation and parameter (solid) on wavelength for spherical homogeneous Zn NPs with radii (a), 25 (b), and 50 (c) nm, for (1), 25 (2), and 50 (3) nm (d), for two-layered core-shell Zn-ZnO NPs with shell thicknesses nm, (e), 20 (f), and 45 (g) nm, for core-shell NP radii (1), 25 (2), and 50 (3) nm (h), for Zn-ZnO NPs with nm and (i), 25 (j), and 50 (k) nm, for (1), 30 (2), and 55 (3) nm (l). NPs are placed in water.

The parameter is used for the description of the optical properties of NPs:The parameter describes the correlation between absorption and scattering of radiation by NP.

Figure 1 presents the dependencies of the efficiency factors of absorption , scattering , and extinction K_ext of radiation and the parameter on wavelength for spherical homogeneous Al NPs with radii , 25, and 50 nm; for two-layered core-shell Al-Al₂O₃ NPs with shell thicknesses nm and core radii , 20, and 45 nm and for core-shell NP radii , 25, and 50; for Al-Al₂O₃ NPs with nm, , 25, and 50 nm, and for , 30, and 55 nm. NPs are placed in air.

The formation of oxide shell on NP with substitution of surface metal layer by oxide layer with approximately equal thickness because of natural oxidation in air atmosphere is presented in Figures 1(e)–1(h). The influence of the formation of oxide shell on metal NP with equal radii leads to next consequences. The plasmon maxima are created and shifted to bigger values of the wavelength. Figures 1(i)–1(l) present the influence of the increasing oxide shell thickness on metal core with = const in chemical gaseous atmosphere. It leads to a decrease of factors for nm and small influence for all optical factors for , 50 nm. The values of the parameter decrease with increasing () and increase with increasing wavelength bigger than 300 nm. The formation of oxide shell on metal NP leads to decreasing in the spectral interval 150–300 nm for all values of . The formation of oxide shell on metal core with nm leads to significant decreasing of the values of for all spectral interval 150–1000 nm (Figure 1(l)). The increase of for homogeneous and core-shell NPs and increase of oxide shell thickness leads to increase of , K_ext in comparison with .

The dependencies of efficiency factors of , , and K_ext on for fixed values of homogeneous radii and core radii and shell thickness have complicated forms (Figures 1–4). In the case of homogeneous NPs of Al with nm (Figure 1(a)) there are no maxima in dependencies , , and K_ext(λ) in the considered region of wavelengths 150–1000 nm. Formally the maximal values of are placed at nm. However, for two-layered NP Al+Al₂O₃ (Figure 1(e)) with equal total NP size of nm, consisting of the aluminum core nm and aluminum oxide shell with thickness nm, maximums of , , and arise. Values of , , and are placed at the same nm. It follows that thin oxide shell influences optical properties of two-layered NP. As for homogeneous aluminum NPs with larger radii (Figure 1(b)) and 50 nm (Figure 1(c)) appearance of aluminum oxide shell thickness ( nm) on the NP surface (Figures 1(f) and 1(g)) leads to small shift of location of , , and in the direction of bigger (increasing) wavelengths up to (no more than) nm. The values of for two-layered NPs increase with ~50 ÷ 75%, and the values of increase with ~5 ÷ 10%.

The formation of oxide shell thickness for , 50 nm leads to formation of sharp peak oscillated dependencies with “plato” from wavelength value 150 nm till 400–450 nm.

Figure 2 presents the dependencies of the efficiency factors of absorption , scattering , and extinction K_ext of radiation and the parameter on wavelength for spherical homogeneous Al NPs with radii , 25, and 50 nm [30]; for two-layered core-shell Al-Al₂O₃ NPs with shell thicknesses nm, core radii , 20, and 45 nm, and for core-shell NP radii , 25, and 50; for Al-Al₂O₃ NPs with nm, , 25, and 50 nm, and for , 30, and 55 nm. NPs are placed in water. The data concerning spherical homogeneous Al NPs with radii , 25, and 50 nm, published in [30], are presented here for direct comparison with the results for core-shell Al-Al₂O₃ NPs and determination of the changes contributed by the formation of oxide shells on the surface of metal cores.

The substitution of surrounding medium (air to water) leads to formation of plasmon peaks for homogeneous metal NP at wavelength ~200 nm and more pronounced peaks for core-shell NPs with oxide shell. We have to note the shifting of the placements of all optical factors to bigger values of wavelength. The factor of decreases for nm, but for and 50 nm there is no decrease in with formation of oxide shell thickness.

Figures 3 and 4 present dependencies of efficiency factors of absorption , scattering , and extinction K_ext of radiation by spherical homogeneous Zn NPs with radii , 25, and 50 nm [30], two-layered core-shell NPs Zn+ZnO with nm, , 20, and 45 nm, and for , 20, 45 (h); Zn+ZnO NPs with nm and , 25, and 50 nm and for , 25, and 50 (l) on wavelength . NPs are placed in air (Figure 3) and in water (Figure 4). The data concerning spherical homogeneous Zn NPs with radii , 25, and 50 nm, published in [30], are presented here for direct comparison with the results for core-shell Zn+ZnO NPs and determination of the changes contributed by the formation of oxide shells on the surface of metal cores.

The formation of oxide shell with thickness nm on core with radius nm leads to significant decrease of the values of , , and K_ext in comparison with homogeneous metal NP with nm and core-shell NP with nm and nm.

In Figures 3(a)–3(l) the dependencies of efficiency factors of , , and K_ext on are shown for homogeneous NPs of Zn and two-layered NP Zn+ZnO, placed in air. As in the case of homogeneous aluminum NP with radius 10 nm, there are no maxima in dependencies , , and K_ext(λ) in the considered region of wavelengths for homogeneous Zn NP with radius 10 nm (Figure 3(a)). But for two-layered NP Zn+ZnO (Figure 3(e)) with equal total NP size of 10 nm, consisting of the Zn core ( nm) and Zn oxide shell with thickness ( nm), maxima in the dependencies of absorption, scattering, and extinction on arise. Values of , , and are placed at the same nm. As for homogeneous Zn NPs with larger radii (Figure 3(b)) and 50 nm (Figure 3(c)) appearance of Zn oxide shell thickness ( nm) on the NP surface (Figures 3(f) and 3(g)) leads to shift of location of , , and in the direction of increasing wavelength by 80 nm for nm and by 30 nm for nm. The values of for Zn homogeneous and two-layered NPs Zn+ZnO for nm decrease by ~20%, and the values of and increase by ~30 ÷ 100%. In the case of Zn homogeneous and two-layered NPs Zn+ZnO for nm and are practically the same, and increases no more than 5 ÷ 10%.

In Figures 3(a)–3(l) the dependencies of efficiency factors of , , and K_ext on are shown for homogeneous NPs of Zn and two-layered NP Zn+ZnO, placed in air. As in the case of homogeneous aluminum NP with radius 10 nm, there are no maxima in dependencies , , and K_ext(λ) in the considered region of wavelengths for homogeneous Zn NP with radius 10 nm (Figure 3(a)). But for two-layered NP Zn+ZnO (Figure 3(e)) with equal total NP size of 10 nm, consisting of the Zn core ( nm) and Zn oxide shell with thickness ( nm), maxima in the dependencies of absorption, scattering, and extinction on arise. Values of , , and are placed at the same nm. As for homogeneous Zn NPs with larger radii (Figure 3(b)) and 50 nm (Figure 3(c)) appearance of Zn oxide shell thickness ( nm) on the NP surface (Figures 3(f) and 3(g)) leads to shift of location of , , and in the direction of increasing wavelength by 80 nm for nm and by 30 nm for nm. The values of for Zn homogeneous and two-layered NPs Zn+ZnO for nm decrease by ~20%, and the values of and increase by ~30 ÷ 100%. In the case of Zn homogeneous and two-layered NPs Zn+ZnO for nm and are practically the same, and increase no more than 5 ÷ 10%.

The dependencies of efficiency factors of , , and K_ext on for homogeneous NPs of Zn and two-layered NP Zn+ZnO, placed in water are shown in Figures 4(a)–4(l). As in the case of homogeneous aluminum NP in water with radius 10 ÷ 50 nm, there are maxima in dependencies , , and K_ext(λ) in the considered region of wavelengths for homogeneous Zn NP. For two-layered NP Zn+ZnO (Figure 4(e)) with equal total NP size of 10 nm, consisting of the Zn core ( nm) and Zn oxide shell with thickness ( nm), maxima in the dependencies of absorption, scattering, and extinction on are shifted more than 100 nm to increase wavelength. Values of , , and are placed at the same nm. As for homogeneous Zn NPs with larger radii (Figure 4(b)) and 50 nm (Figure 4(c)) appearance of Zn oxide shell thickness ( nm) on the NP surface (Figures 3(f) and 3(g)) leads to shift of location of , , and in the direction of increasing wavelength by ~50 nm for nm and by ~30 ÷ 50 nm for nm. The values of for Zn homogeneous and two-layered NPs Zn+ZnO for nm increase by ~10%, and the values of and decrease by ~20 ÷ 100%. In the case of Zn homogeneous and two-layered NPs Zn+ZnO for nm and are practically the same, and decreases no more than 10 ÷ 40%.

The substitution of surrounding medium air to water leads to formation of plasmon peaks for homogeneous metal NP at wavelength ~300 nm and more pronounced peaks for core-shell NPs with oxide shell. We have to note the shifting of the placements of all maxima of optical factors to bigger values of wavelength. The factor of increases for nm, but for and 50 nm there are no essential changes of with formation of oxide shell thickness.

It is seen from Figures 1–4 that the changes contributed by the appearance and the presence of thin metallic oxide shells on the surface of metallic NPs are essential for small aluminum NPs and all zinc NPs from considered metallic ones. Our results allow estimating the influence of oxide shells appearing on the surface of metallic nanoparticles on absorption, scattering, and extinction of radiation by NPs and influence of ambient properties for their photonic and technological applications.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

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Copyright © 2015 Victor K. Pustovalov and Liudmila G. Astafyeva. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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