Journal of Nanomaterials The latest articles from Hindawi Publishing Corporation © 2014 , Hindawi Publishing Corporation . All rights reserved. Tribological Performance and Lubrication Mechanism of Alkylimidazolium Dialkyl Phosphates Ionic Liquids as Lubricants for Si3N4-Ti3SiC2 Contacts Wed, 16 Apr 2014 14:15:08 +0000 The tribological performance of Si3N4-Ti3SiC2 contacts lubricated by alkylimidazolium dialkyl phosphates ionic liquids (ILs) was investigated using an Optimol SRV-IV oscillating reciprocating friction and wear tester at room temperature (25°C) and 100°C. Glycerol and tributyl phosphate (TBP) were also selected as lubricants for Si3N4-Ti3SiC2 contacts to study the tribological properties under the same experimental conditions for comparison. Results show that the alkylimidazolium dialkyl phosphates ILs were effective in reducing the friction and wear for Si3N4-Ti3SiC2contacts, and their performance is superior to that of glycerol and TBP. The SEM/EDS and XPS results reveal that the excellent tribological endurance of alkylimidazolium dialkyl phosphates ILs is mainly attributed to the high load-carrying capacity of the ILs and the formation of surface protective films consisting of TiO2, SiOx, titanium phosphate, amines, and nitrogen oxides by the tribochemical reactions. Hai-zhong Wang, Dan Qiao, Song-wei Zhang, Da-peng Feng, and Jin-jun Lu Copyright © 2014 Hai-zhong Wang et al. All rights reserved. Performance Study of CdS/Co-Doped-CdSe Quantum Dot Sensitized Solar Cells Wed, 16 Apr 2014 09:39:49 +0000 In order to optimize the charge transfer path in quantum dot sensitized solar cells (QDSCs), we employed successive ionic layer adsorption and reaction method to dope CdSe with Co for fabricating CdS/Co-doped-CdSe QDSCs constructed with CdS/Co-doped-CdSe deposited on mesoscopic TiO2 film as photoanode, Pt counter electrode, and sulfide/polysulfide electrolyte. After Co doping, the bandgap of CdSe quantum dot decreases, and the conduction band and valence band all improve, forming a cascade energy level which is more conducive to charge transport inside the solar cell and reducing the recombination of electron-hole thus improving the photocurrent and ultimately improving the power conversion efficiency. This work has not been found in the literature. Xiaoping Zou, Sheng He, Gongqing Teng, and Chuan Zhao Copyright © 2014 Xiaoping Zou et al. All rights reserved. Tribological Performance of Silahydrocarbons Used as Steel-Steel Lubricants under Vacuum and Atmospheric Pressure Wed, 16 Apr 2014 07:02:08 +0000 The silahydrocarbons of tetraalkylsilanes with different substituted alkyl groups (named as SiCH) were synthesized and evaluated as lubricants for steel-steel contacts by a home-made vacuum four-ball tribometer (VFBT-4000) under atmospheric pressure and under vacuum pressure ( Pa). The SiCH oils possess better thermal stability, low temperature fluidity, and lower saturated vapor pressure than those of multialkylatedcyclopentanes (MACs). The tribological performances of the SiCH oils are also superior to those of MACs and PFPE-Z25 in terms of friction-reduction ability and antiwear capacity under sliding friction at vacuum. The SEM/EDS and XPS results reveal that the boundary lubricating film consisting of compounds is formed by tribochemical reactions and serious adhesion wear under atmospheric pressure and the film consisting of compounds is formed on the worn surface under vacuum pressure. Hai-Zhong Wang, Song-Wei Zhang, Dan Qiao, Da-Peng Feng, and Wei-Min Liu Copyright © 2014 Hai-Zhong Wang et al. All rights reserved. Applications of Dendrimers in Drug Delivery Agents, Diagnosis, Therapy, and Detection Tue, 15 Apr 2014 16:30:48 +0000 In recent years, the application of dendrimers in biomedicine attracted much attention from scientists. Dendrimers are interesting for biomedical applications because of their characteristics, including: a hyperbranching, well-defined globular structures, excellent structural uniformity, multivalency, variable chemical composition, and high biological compatibility. In particular, the three-dimensional architecture of dendrimers can incorporate a variety of biologically active agents to form biologically active conjugates. This review of dendrimers focuses on their use as protein mimics, drug delivery agents, anticancer and antiviral therapeutics, and in biomedical diagnostic applications such as chemically modified electrodes. B. Noriega-Luna, Luis A. Godínez, Francisco J. Rodríguez, A. Rodríguez, G. Zaldívar-Lelo de Larrea, C. F. Sosa-Ferreyra, R. F. Mercado-Curiel, J. Manríquez, and E. Bustos Copyright © 2014 B. Noriega-Luna et al. All rights reserved. Efficient Photocatalytic Degradation of Rhodamine B Dye by Aligned Arrays of Self-Assembled Hydrogen Titanate Nanotubes Tue, 15 Apr 2014 14:13:44 +0000 We show that an aligned array of hydrothermally grown, multiwalled hydrogen titanate (H2Ti3O7) nanotubes—anchored to both faces of a metallic Ti foil—acts as an efficient photocatalyst. We studied the degradation of rhodamine B dye in the presence of the nanostructured photocatalyst under UV irradiation, by monitoring the optical absorption of the dye. Rhodamine B was chosen as a representative—and particularly harmful—industrial pollutant dye. The inner and outer diameters of the H2Ti3O7 nanotubes were 5 nm and 10 nm, respectively. The nanotube array catalyst is recyclable and structurally stable. Most importantly, it shows comparable or higher photodecomposition rate constant than those of both H2Ti3O7 nanotube powder and P-25 (Degussa). The enhanced photocatalytic performance may be ascribed to the nanotube array having a superhydrophilic surface with a high accessible surface area. Sriparna Chatterjee, Avesh K. Tyagi, and Pushan Ayyub Copyright © 2014 Sriparna Chatterjee et al. All rights reserved. Hydrothermal Synthesis, Characterization, and Optical Properties of Ce Doped Bi2MoO6 Nanoplates Tue, 15 Apr 2014 14:06:12 +0000 Undoped and Ce doped Bi2MoO6 samples were synthesized by hydrothermal reaction at 180°C for 20 h. Phase, morphology, atomic vibration, and optical properties were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectrophotometry, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and UV-visible spectroscopy. In this research, the products were orthorhombic Bi2MoO6 nanoplates with the growth direction along the [0b0], including the asymmetric and symmetric stretching and bending modes of Bi–O and Mo–O. Undoped and Ce doped Bi2MoO6 samples show a strong absorption in the UV region. Anukorn Phuruangrat, Nuengruethai Ekthammathat, Budsabong Kuntalue, Phattranit Dumrongrojthanath, Somchai Thongtem, and Titipun Thongtem Copyright © 2014 Anukorn Phuruangrat et al. All rights reserved. Facile Deposition of Ultrafine Silver Particles on Silicon Surface Not Submerged in Precursor Solutions for Applications in Antireflective Layer Tue, 15 Apr 2014 13:01:18 +0000 Using a facile deposition method, the ultrafine silver particles are successfully deposited on the Si surface that is not submerged in precursor solutions. The ultrafine silver particles have many advantages, such as quasiround shape, uniformity in size, monodisperse distribution, and reduction of agglomeration. The internal physical procedure in the deposition is also investigated. The results show that there are more particles on the rough Si surface due to the wetting effect of solid-liquid interface. The higher concentration of ethanol solvent can induce the increase of quantity and size of particles on Si surface not in solutions. The ultrafine particles can be used to prepare porous Si antireflective layer in solar cell applications. Bing Jiang, Meicheng Li, Dandan Song, Yingfeng Li, and Trevor Mwenya Copyright © 2014 Bing Jiang et al. All rights reserved. Adsorption of Reactive Black 5 on Synthesized Titanium Dioxide Nanoparticles: Equilibrium Isotherm and Kinetic Studies Tue, 15 Apr 2014 08:56:27 +0000 The synthesized titanium dioxide nanoparticles (TiO2-NPs) were used as adsorbent to remove reactive black 5 (RB 5) in aqueous solution. Various factors affecting adsorption of RB 5 aqueous solutions such as pH, initial concentration, contact time, dose of nanoparticles, and temperature were analyzed at fixed solid/solution ratio. Langmuir and Freundlich isotherms were used as model adsorption equilibrium data. Langmuir isotherm was found to be the most adequate model. The pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were used to describe the adsorption kinetics. The experimental data was fitted to pseudo-second-order kinetics. The thermodynamic parameters such as Gibbs-free energy, enthalpy, and entropy changes were determined. These parameters indicated the endothermic and spontaneity nature of the adsorption. The results demonstrated the fact that the TiO2-NPs are promising adsorbent for the removal of RB 5 from aqueous solutions. Majeed A. Shaheed and Falah H. Hussein Copyright © 2014 Majeed A. Shaheed and Falah H. Hussein. All rights reserved. Assessment of Morphology, Activity, and Infiltration of Astrocytes on Marine EPS-Imbedded Electrospun PCL Nanofiber Mon, 14 Apr 2014 13:18:17 +0000 Tissue engineering using a biomaterial including bioactive compounds has been researched as a way to restore injured neural systems. Extracellular polymeric substances (EPS) extracted from marine seaweeds have been known to produce positive effects on physiological activities in human tissues. In this study, an electrospun nanofiber containing brown seaweed EPS was proven to be a candidate biomaterial for neural tissue engineering. Glial fibrillary acidic protein (GFAP) as a specific marker protein increased in the astrocytes cultured on the polycaprolactone (PCL) nanofiber containing EPS (EPS-PCL nanofiber), compared with PCL nanofiber. The upregulation of GFAP indicates that the EPS-PCL nanofiber induced astrocyte activation, which supports physiological agents favorable to restore injured neural tissue. Astrocytes could infiltrate into the EPS-PCL nanofiber mat without toxicity, comparable to PCL nanofiber. These results imply that EPS-PCL nanofiber could be a useful biomaterial to regulate astrocyte activity at a molecular level and could be considered as a novel therapeutic material for neural tissue engineering. Seul Ki Min, Cho Rong Kim, Sung Hoon Kim, and Hwa Sung Shin Copyright © 2014 Seul Ki Min et al. All rights reserved. Nanostructural Colouration in Malaysian Plants: Lessons for Biomimetics and Biomaterials Mon, 14 Apr 2014 11:57:04 +0000 Plant tissues include leaves, flower petals, and fruits. These can provide us with variety of design inspirations. Biomimetics allows us to learn from nature and transfer the knowledge we gain from studying sophisticated and amazing biological structures, materials and processes to engineering and the arts. The microstructures of morphology and anatomy of plant tissue have potential applications in technology through bioinspired design, which can mimic the properties found in nature or use them as inspiration for alternative applications. Many applications have been developed as a result of studying physical properties of plant tissues. Structural colours, for example, have been applied in the design of thin films both with regard to single or multilayer thin film interference, scattering, and diffraction gratings. Iridescent, metallic, or greyish colouration found naturally in plants is the result of physical structures or physical effects and not pigmentation. Phenotypical appearance of plants with structural colouration in tropical Malaysia is correlated with environmental parameters such as location (shady understory rainforest, sunny conditions) and altitude (highlands, lowlands). Various examples of bioinspired technical innovations with structural colours highlight the importance of inspiration by structural colours in living nature. S. Zaleha M. Diah, Salmah B. Karman, and Ille C. Gebeshuber Copyright © 2014 S. Zaleha M. Diah et al. All rights reserved. Catalytic Hydrolysis of Ammonia Borane by Cobalt Nickel Nanoparticles Supported on Reduced Graphene Oxide for Hydrogen Generation Mon, 14 Apr 2014 11:02:00 +0000 Well dispersed magnetically recyclable bimetallic CoNi nanoparticles (NPs) supported on the reduced graphene oxide (RGO) were synthesized by one-step in situ coreduction of aqueous solution of cobalt(II) chloride, nickel (II) chloride, and graphite oxide (GO) with ammonia borane (AB) as the reducing agent under ambient condition. The CoNi/RGO NPs exhibits excellent catalytic activity with a total turnover frequency (TOF) value of 19.54 mol H2 mol catalyst−1 min−1 and a low activation energy value of 39.89 kJ mol−1 at room temperature. Additionally, the RGO supported CoNi NPs exhibit much higher catalytic activity than the monometallic and RGO-free CoNi counterparts. Moreover, the as-prepared catalysts exert satisfying durable stability and magnetically recyclability for the hydrolytic dehydrogenation of AB, which make the practical reusing application of the catalysts more convenient. The usage of the low-cost, easy-getting catalyst to realize the production of hydrogen under mild condition gives more confidence for the application of ammonia borane as a hydrogen storage material. Hence, this general method indicates that AB can be used as both a potential hydrogen storage material and an efficient reducing agent, and can be easily extended to facile preparation of other RGO-based metallic systems. Yuwen Yang, Fei Zhang, Hualan Wang, Qilu Yao, Xiangshu Chen, and Zhang-Hui Lu Copyright © 2014 Yuwen Yang et al. All rights reserved. Application of a Novel Semiconductor Catalyst, CT, in Degradation of Aromatic Pollutants in Wastewater: Phenol and Catechol Mon, 14 Apr 2014 08:29:48 +0000 Water-soluble phenol and phenolic compounds were generally removed via advanced oxidation processes. A novel semiconductor catalyst, CT, was the first-time employed in the present study to degrade phenol and catechol. The phenolic compounds (initial concentration of 88 mg L−1) were completely mineralized by the CT catalytic nanoparticles (1%) within 15 days, under acidic condition and with the presence of mild UV radiation (15 w, the emitted wavelength is 254 nm and the light intensity <26 μw/cm2). Under the same reaction condition, 1% TiO2 (mixture of rutile and anatase, nanopowder, <100 nm) and H2O2 had lower removal efficiency (phenol: <42%; catechol: <60%), whereas the control (without addition of catalysts/H2O2) only showed <12% removal. The processes of phenol/catechol removal by CT followed pseudo-zero-order kinetics. The aromatic structures absorbed the UV energy and passed to an excited state, which the CT worked on. The pollutants were adsorbed on the CT’s surface and oxidized via charge-transfer and hydroxyl radical generation by CT. Given low initial concentrations, a circumstance encountered in wastewater polishing, the current set-up should be an efficient and less energy- and chemical-consumptive treatment method. Xiao Chen, Yanling Zhang, Xuefei Zhou, Shoji Ichimura, Guoxiu Tong, Qiming Zhou, Xi Chen, Wenzhao Wang, and Yan Liang Copyright © 2014 Xiao Chen et al. All rights reserved. Nanocatalysts for Hydrogen Generation from Ammonia Borane and Hydrazine Borane Mon, 14 Apr 2014 06:48:44 +0000 Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3 and N2H4BH3. Zhang-Hui Lu, Qilu Yao, Zhujun Zhang, Yuwen Yang, and Xiangshu Chen Copyright © 2014 Zhang-Hui Lu et al. All rights reserved. Seed-Mediated Growth of Gold Nanorods: Limits of Length to Diameter Ratio Control Mon, 14 Apr 2014 00:00:00 +0000 The effects of the seed reaction conditions on the two-step seed-mediated growth of gold nanorods and the effect of gold and reducing agent content in the growth solution were evaluated. Results indicate that the reaction conditions used to produce the seeds have a significant impact on the aspect ratio of the gold nanorods produced. Increasing the concentration of gold or the reaction temperature in the seed production step results in lower length to diameter (aspect ratio) gold rods. In addition, the amount of prepared seed added to the growth solution impacts the rod aspect ratio, with increasing amounts of seed reducing the aspect ratio. The effects of reducing agent, ascorbic acid (AA), and gold content of the growth solution on the aspect ratio of the produced rods are strongly interrelated. There exists a minimum ascorbic acid to gold concentration below which rods will not form; however, increasing the ratio above this minimum results in shorter rods being formed. Characterization of nanorod growth is performed by UV-vis-NIR spectrophotometry and transmission electron microscopy (TEM). Christopher J. Ward, Robert Tronndorf, Alicia S. Eustes, Maria L. Auad, and Edward W. Davis Copyright © 2014 Christopher J. Ward et al. All rights reserved. Optical Properties of Nanoparticles and Nanocomposites Sun, 13 Apr 2014 07:45:23 +0000 Pathik Kumbhakar, Suprakas Sinha Ray, and Andey L. Stepanov Copyright © 2014 Pathik Kumbhakar et al. All rights reserved. Morphology and Electrical Conductivity of Carbon Nanocoatings Prepared from Pyrolysed Polymers Sun, 13 Apr 2014 00:00:00 +0000 Conductive carbon nanocoatings (conductive carbon layers—CCL) were formed on -Al2O3 model support using three different polymer precursors and deposition methods. This was done in an effort to improve electrical conductivity of the material through creating the appropriate morphology of the carbon layers. The best electrical properties were obtained with use of a precursor that consisted of poly-N-vinylformamide modified with pyromellitic acid (PMA). We demonstrate that these properties originate from a specific morphology of this layer that showed nanopores (3-4 nm) capable of assuring easy pathways for ion transport in real electrode materials. The proposed, water mediated, method of carbon coating of powdered supports combines coating from solution and solid phase and is easy to scale up process. The optimal polymer carbon precursor composition was used to prepare conductive carbon nanocoatings on LiFePO4 cathode material. Charge-discharge tests clearly show that C/LiFePO4 composites obtained using poly-N-vinylformamide modified with pyromellitic acid exhibit higher rechargeable capacity and longer working time in a battery cell than standard carbon/lithium iron phosphate composites. Marcin Molenda, Michał Świętosławski, Marek Drozdek, Barbara Dudek, and Roman Dziembaj Copyright © 2014 Marcin Molenda et al. All rights reserved. Influence of Temperature on Characters of Thermoelectric Generators Based on Test Bed Sun, 13 Apr 2014 00:00:00 +0000 In order to achieve the energy recovery of the coolant heat for internal combustion engine (ICE) using the thermoelectric generation (TEG) technology, one test bed for studying the influence of temperature on the characters of thermoelectric generators was established and the relationship between the temperature and characters of thermoelectric generator was researched based on it. The results showed that the cooling effect improved with the increase of fan speed which the fan was installed in the vertical direction of the radiator, but the cooling effect had a limit speed value. And it also indicated that the forced air cooling was better than the natural convection cooling method which can effectively reduce the temperature of the cold end while it has little effect on the hot end temperature. Moreover, the Seebeck coefficient was reduced with the increase of temperature difference between the two ends of thermoelectric generator and the Seebeck coefficient was also declined with one end temperature rise when the other end temperature was constant. Zongzheng Ma, Xinli Wang, and Anjie Yang Copyright © 2014 Zongzheng Ma et al. All rights reserved. Nanomaterials for Sensor Device Applications Thu, 10 Apr 2014 09:35:38 +0000 Liang-Wen Ji, Sheng-Joue Young, Chih-Hung Hsiao, and Artde Donald Kin-Tak Lam Copyright © 2014 Liang-Wen Ji et al. All rights reserved. Terahertz Performance of a GaN-Based Planar Nanochannel Device Thu, 10 Apr 2014 09:34:32 +0000 Using a combined two-dimensional-three-dimensional (2D-3D) ensemble Monte Carlo (EMC) model, the performance of a planar nanochannel device is studied at the terahertz (THz) region. The device is based on a GaN/AlGaN heterostructure in which a two-dimensional electron gas (2DEG) forms at the interface. Simulation results reveal that, at low working frequencies, the performance of the device is almost frequency independent. However, when the working frequency is higher than 0.5 THz, obvious enhancements in the device performance have been observed. The enhancements are characterized by two resonant peaks at frequencies of about 4 THz and 8 THz. Also, the frequency-dependent performance exhibits nonmonotonicity. Further studies show that the performance enhancements can be attributed to the excitations of 2D plasma waves in the device, with the emergence of the above resonant peaks corresponding to the formation of standing plasma waves. Moreover, simulation results show that the device performance increases monotonically with signal amplitude, when the device is unbiased. However, when a DC bias is applied, the performance remains almost unchanged for large signals but is significantly enhanced for small signals. Therefore, the device performance shows a strong nonmonotonic dependence on signal amplitude, and its minimal value occurs when the signal amplitude is only about times the DC bias. K. Y. Xu, Y. N. Wang, C. J. Zheng, J. W. Xiong, and G. Wang Copyright © 2014 K. Y. Xu et al. All rights reserved. Effect of Different Catalyst Deposition Technique on Aligned Multiwalled Carbon Nanotubes Grown by Thermal Chemical Vapor Deposition Thu, 10 Apr 2014 00:00:00 +0000 The paper reported the investigation of the substrate preparation technique involving deposition of iron catalyst by electron beam evaporation and ferrocene vaporization in order to produce vertically aligned multiwalled carbon nanotubes array needed for fabrication of tailored devices. Prior to the growth at 700°C in ethylene, silicon dioxide coated silicon substrate was prepared by depositing alumina followed by iron using two different methods as described earlier. Characterization analysis revealed that aligned multiwalled carbon nanotubes array of 107.9 µm thickness grown by thermal chemical vapor deposition technique can only be achieved for the sample with iron deposited using ferrocene vaporization. The thick layer of partially oxidized iron film can prevent the deactivation of catalyst and thus is able to sustain the growth. It also increases the rate of permeation of the hydrocarbon gas into the catalyst particles and prevents agglomeration at the growth temperature. Combination of alumina-iron layer provides an efficient growth of high density multiwalled carbon nanotubes array with the steady growth rate of 3.6 µm per minute for the first 12 minutes and dropped by half after 40 minutes. Thicker and uniform iron catalyst film obtained from ferrocene vaporization is attributed to the multidirectional deposition of particles in the gaseous form. Mohamed Shuaib Mohamed Saheed, Norani Muti Mohamed, and Zainal Arif Burhanudin Copyright © 2014 Mohamed Shuaib Mohamed Saheed et al. All rights reserved. Synthesis and Characterization of Structure-Controlled Micro-/Nanocomposite TiO2 Fibers with Enhanced Photocatalytic Activity Wed, 09 Apr 2014 12:24:19 +0000 A series of structure-controlled composite TiO2 fibers combining micro- and nanostructures (hereafter, micro-/nanocomposite) were fabricated using a combination of electrospinning and calcination methods, and their photocatalytic activities were investigated. Smooth microscale fibers were obtained by electrospinning a precursor solution containing tetrabutyl titanate and TiF4. TiO2 nanocrystals formed on the microfibers with the help of HF which was produced from the decomposition of TiF4 in calcination. The size and quantity of TiO2 nanocrystals can be controlled by tuning the mass ratio of TiF4 in the sol-gel precursor solutions and the calcination time. The obtained micro-/nanocomposite TiO2 fibers were found to exhibit enhanced photocatalytic properties when compared with the bare microfibers. These micro-/nanocomposite structures exhibit the advantages of both the nanocrystals and microfibers, which will lead to new developments in photocatalysis. Chengcheng Liu, Chunmei Ding, Tianyi Zhao, and Lei Jiang Copyright © 2014 Chengcheng Liu et al. All rights reserved. Formulation of Synthesized Zinc Oxide Nanopowder into Hybrid Beads for Dye Separation Wed, 09 Apr 2014 09:25:26 +0000 The sol-gel prepared zinc oxide nanopowder was immobilized onto alginate-polyvinyl alcohol polymer blend to fabricate novel biocomposite beads. Various physicochemical characterization techniques have been utilized to identify the crystalline, morphological, and chemical structures of both the fabricated zinc oxide hybrid beads and their corresponding zinc oxide nanopowder. The thermal stability investigations demonstrate that ZnO nanopowder stability dramatically decreased with its immobilization into the polymeric alginate and PVA matrix. The formulated beads had very strong mechanical strength and they are difficult to be broken up to 1500 rpm. Moreover, these hybrid beads are chemically stable at the acidic media (pH < 7) especially within the pH range of 2–7. Finally, the applicability of the formulated ZnO hybrid beads for C.I. basic blue 41 (BB41) decolorization from aqueous solution was examined. H. Shokry Hassan, M. F. Elkady, A. H. El-Shazly, and Hisham S. Bamufleh Copyright © 2014 H. Shokry Hassan et al. All rights reserved. Advanced Nanomaterials and Nanostructures for Tribological Applications Wed, 09 Apr 2014 08:36:49 +0000 Yongsheng Zhang, Tianchang Hu, Xianjin Ning, and Qi Ding Copyright © 2014 Yongsheng Zhang et al. All rights reserved. Chitosan and Its Derivatives Applied in Harvesting Microalgae for Biodiesel Production: An Outlook Wed, 09 Apr 2014 07:19:39 +0000 Although oil-accumulating microalgae are a promising feedstock for biodiesel production, large-scale biodiesel production is not yet economically feasible. As harvesting accounts for an important part of total production cost, mass production of microalgae biodiesel requires an efficient low-energy harvesting strategy so as to make biodiesel production economically attractive. Chitosan has emerged as a favorable flocculating agent in harvesting of microalgae. The aim of this paper is to review current research on the application of chitosan and chitosan-derived materials for harvesting microalgae. This offers a starting point for future studies able to invalidate, confirm, or complete the actual findings and to improve knowledge in this field. Guanyi Chen, Liu Zhao, Yun Qi, and Yuan-Lu Cui Copyright © 2014 Guanyi Chen et al. All rights reserved. Ag-Cu Colloid Synthesis: Bimetallic Nanoparticle Characterisation and Thermal Treatment Tue, 08 Apr 2014 08:12:29 +0000 The Ag-Cu bimetallic colloidal nanoparticles (NPs) were prepared by solvothermal synthesis from metalloorganic precursors in a mixture of organic solvents. The nanoparticles were characterized by dynamic light scattering (DLS) and small angle X-ray scattering (SAXS). The properties of metallic core and organic shell of the nanoparticles were studied by direct inlet probe mass spectrometry (DIP/MS), Knudsen effusion mass spectrometry (KEMS), double-pulse laser-induced breakdown spectroscopy (DPLIBS), and differential scanning calorimetry (DSC). The transmission electron microscopy (TEM) and scanning electron microscopy (SEM) were used for particle characterization before and after thermal analysis. The experiment yielded results that were for AgCu nanoparticles for the first time. The detected liquidus temperature has been compared with the prediction obtained from calculation of the phase diagram of Ag-Cu nanoalloy. The experimental results show that of near-eutectic composition AgCu nanoparticles possess the fcc crystal lattice. Surprisingly, spinodal decomposition was not observed inside the AgCu nanoparticles at temperatures up to 230°C. The depression of the eutectic AgCu melting point was calculated but not observed. The eutectic AgCu microparticles are formed before melting. Jiří Sopoušek, Jiří Pinkas, Pavel Brož, Jiří Buršík, Vít Vykoukal, David Škoda, Aleš Stýskalík, Ondřej Zobač, Jan Vřešťál, Aleš Hrdlička, and Jan Šimbera Copyright © 2014 Jiří Sopoušek et al. All rights reserved. Nanofer ZVI: Morphology, Particle Characteristics, Kinetics, and Applications Mon, 07 Apr 2014 17:25:05 +0000 Nanofer zerovalent iron (nanofer ZVI) is a new and innovative nanomaterial capable of removing organic as well as inorganic contaminants in water. It displays a decrease in agglomeration, when it is coated with tetraethyl orthosilicate (TEOS). TEOS imparts an increase in reactivity and stability to nanofer ZVI. Characteristics of nanofer ZVI were determined using scanning electron microscope/electron dispersive spectroscope (SEM/EDS), transmission electron microscope (TEM), and X-ray diffraction (XRD). Nanoparticle size varied from 20 to 100 nm and its surface area was in the range of 25–30 m2g−1. The present study examined its structure before and after kinetic experiments. Kinetic experiments indicated that adsorption of heavy metals [Pb (II), Cd (II), and Cu (II)] and TCE is very rapid during the initial step which is followed by a much slower second step. Removal rates of 99.7% for Pb (II), 99.2% for Cd (II), 99.9% for Cu (II), and 99.9% for TCE were achieved in less than 180 minutes. Lagergren models (LM), liquid film diffusion model (LFDM), and interparticle diffusion model (IDM) were used to understand the removal mechanism associated with nanofer ZVI. In this study, interactions of nanofer ZVI with individual metals as well as TCE are examined. Mahmoud M. Eglal and Amruthur S. Ramamurthy Copyright © 2014 Mahmoud M. Eglal and Amruthur S. Ramamurthy. All rights reserved. Visualization of Iron-Binding Micelles in Acidic Recombinant Biomineralization Protein, MamC Mon, 07 Apr 2014 13:47:48 +0000 Biological macromolecules are utilized in low-temperature synthetic methods to exert precise control over nanoparticle nucleation and placement. They enable low-temperature formation of a variety of functional nanostructured materials with properties often not achieved via conventional synthetic techniques. Here we report on the in situ visualization of a novel acidic bacterial recombinant protein, MamC, commonly present in the magnetosome membrane of several magnetotactic bacteria, including Magnetococcus marinus, strain MC-1. Our findings provide an insight into the self-assembly of MamC and point to formation of the extended protein surface, which is assumed to play an important role in the formation of biotemplated inorganic nanoparticles. The self-organization of MamC is compared to the behavior of another acidic recombinant iron-binding protein, Mms6. Sanjay Kashyap, Taylor Woehl, Carmen Valverde-Tercedor, Miguel Sánchez-Quesada, Concepción Jiménez López, and Tanya Prozorov Copyright © 2014 Sanjay Kashyap et al. All rights reserved. Microstructures and Recording Mechanism of Mo/Si Bilayer Applied for Write-Once Blue Laser Optical Recording Mon, 07 Apr 2014 13:38:54 +0000 Mo/Si bilayer thin films were grown by magnetron sputtering and applied to write-once blu-ray disc (BD-R). The microstructures and optical storage properties of Mo/Si bilayer were investigated. From the temperature dependence of reflectivity measurement, it was revealed that a phase change occurred in the range of 255–425°C. Transmission electron microscopy analysis showed that the as-deposited film possessed Mo polycrystalline phase. The hexagonal MoSi2 and cubic Mo3Si phases appeared after annealing at 300 and 450°C, respectively. By measuring the optical reflectivity at a wavelength of 405 nm, the optical contrast of Mo/Si bilayer between as-deposited and 450°C-annealed states was evaluated to 25.8%. The optimum jitter value of 6.8% was obtained at 10.65 mW for 4× recording speed. The dynamic tests show that the Mo/Si bilayer has high potential in BD-R applications. Sin-Liang Ou, Kuo-Sheng Kao, Han-Feng Chang, Tsung-Shine Ko, and Chin-Yen Yeh Copyright © 2014 Sin-Liang Ou et al. All rights reserved. Fatigue Crack Behavior of Stainless Steel 304 by the Addition of Carbon Nanotubes Mon, 07 Apr 2014 13:36:34 +0000 Fatigue is the main source of almost half of whole mechanical failures. This research investigated the effect on cyclic fatigue behavior of stainless steel 304 (SS304) when including carbon nanotubes (CNTs) at the crack tip. The cyclic fatigue tests were conducted on compact tension (CT) specimens to establish the relationship between crack growth and the number of cycles (a-N). It is found that the incorporation of a small amount of CNTs increased the fatigue life of the SS304/metal. Micrographs showed that the enhancement in fatigue life is caused by CNTs dense arrangement around the crack tip, entangled with each other, and finer grain size. Smooth bonding at the interface of the CNTs and SS304 grains is also observed. Rizwanulhaque Syed and Wei Jiang Copyright © 2014 Rizwanulhaque Syed and Wei Jiang. All rights reserved. Investigation of Adsorption Behavior of Cu2O Submicro-Octahedra towards Congo Red Mon, 07 Apr 2014 12:47:08 +0000 Perfect cuprous oxide (Cu2O) nanocrystals with octahedron shape were successfully synthesized by a facile route without chemical additive in a short time. The products were characterized by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM). The adsorption ability of the products towards congo red (CR) as the pollutant was investigated and FTIR spectroscopy was employed to identify the adsorbed species. The adsorption behavior was analyzed based on the microstructure of Cu2O submicro-octahedra. Xu Zhang, Ying Zhang, Dong Wang, and Fengyu Qu Copyright © 2014 Xu Zhang et al. All rights reserved.