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Journal of Nanoparticles
Volume 2013 (2013), Article ID 274894, 8 pages
Synthesis of ZnO Nanostructures by Microwave Irradiation Using Albumen as a Template
1Nanotechnology Laboratory, Department of Physics, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, Tamil Nadu 641020, India
2Department of Electronic Engineering, Chemistry and Industrial Engineering, University of Messina, 98166 Messina, Italy
3Department of Physics, B. R. Ambedkar Bihar University, Muzaffarpur, Bihar 842001, India
Received 10 January 2013; Accepted 1 February 2013
Academic Editor: Amir Kajbafvala
Copyright © 2013 T. Prakash et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
ZnO nanostructures have been successfully prepared by a microwave irradiation method. The role of albumen as a template in addressing the size and morphology of ZnO has been investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG-DTA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. A heterogeneous mixture of Zn(OH)2 and ZnO was obtained in absence of albumen. Pure ZnO nanostructures, consisting of rod- and whisker-like nanoparticles embedded in a sheet matrix, were obtained in the presence of albumen. Optical and photoluminescence (PL) properties of the synthesized samples were also compared. Results obtained indicate that the microwave-assisted method is a promising low temperature, cheap, and fast method for the production of ZnO nanostructures.
Recently, metal oxides which exhibit morphologies at the nanoscale (<100 nm) have become increasingly important. One of them is ZnO, a wide band gap n-type semiconductor (3.37 eV) with large exciton binding energy of (60 meV) at room temperature, which has attracted much attention due to its unique properties. ZnO nanoparticles have found numerous applications, such as in gas sensors , transparent electrodes , pH sensors , biosensors , acoustic wave devices , and UV photodiodes .
Up to now, a number of investigations have focused on the synthesis of nano- and microarchitectures through different methods like hydrothermal , sol-gel , electrochemical deposition , and vapor-phase process . Previous studies on the microwave radiation synthesis of ZnO with a variety of morphologies, such as nanowires , nanorods , nanoneedles , hollow structures, and self-assembled architectures , were widely reported.
In this work, we synthesized ZnO nanostructures via a microwave irradiation method in the presence of albumen as a biotemplate. Microwave irradiation as a heating method has found a number of applications in chemistry. The utilization of microwave irradiation in the preparation of nanoparticles has been reported in recent years . Compared to the conventional methods, the microwave synthesis has the advantages of producing small particle size metal oxides with high purity owing to short reaction time [15–19]. Due to the “in situ” mode of energy conversion, the microwave heating process is fundamentally different from conventional heating processes. Heat will be generated internally within the material, instead of originating from external sources. By means of this method, many functional materials and compounds with novel structures and properties have been obtained . In recent studies, it has been shown that nanoparticles, such as Co3O4 , , SnO2  , MgO , ZnO , and TiO2 , can be prepared by the microwave synthesis process. Though the application of microwave irradiation in synthetic chemistry started in 1980s, only in the recent years, its use has provided a new, efficient, and environmentally benign methodology for the synthesis of various metal oxide nanoparticles of diverse morphologies and sizes. These radiations have unique properties like homogenous volumetric heating, which causes heating directly inside the sample, high reaction rate, selectivity, and increased product yield. Moreover, it is an energy saving process [14, 28, 29].
The process here proposed to synthesize ZnO nanostructures by a microwave-assisted process is simple, cheap, and fast and is characterized by a low synthesis temperature (130°C). As compared to conventional heating, microwaves cause the uniform distribution of temperature between the surface and the bulk material thereby leading to the fast formation of ZnO nanoparticles [30, 31]. Another advantage is that no postannealing process is necessary to obtain ZnO crystalline nanometer-sized structures compared to other microwave irradiation methods reported in the literature [32, 33]. To investigate the role of template in the synthesis of ZnO nanostructure by this method, a comparative study has been carried characterizing the products obtained in the presence or not of albumen as a biotemplate. The ZnO nanomaterials obtained were thoroughly characterized through X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG-DTA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. Furthermore, their optical properties were assessed by UV-Vis DRS spectra and photoluminescence (PL) measurements.
2. Experimental Procedure
Zinc nitrate Zn(NO3)2 and ammonia solution (NH4OH) were supplied from (Merk, 98%) Mumbai, India. All the chemicals were of analytical grade and used as received without further purification. The albumen, extracted from white part of egg, was used for the synthesis. Double distilled water was used through the experiments.
The synthesis of ZnO nanostructures by the microwave irradiation method was carried out as follows. First, a 0.1 M of zinc hydroxyl solution was prepared by dissolving zinc nitrate (Zn(NO3)2) in deionized water. Then pH of the solution was maintained at 8 by adding liquid ammonia solution dropwise. The resulting product was filtered and washed with double distilled water and ethanol until it became free from impurities. The precipitate was irradiated for 5 minutes in household microwave (radiation frequency 2.45 GHZ, Power up to 1 KW) with convection mode, giving a white product. Finally the sample was dried at 130°C (sample A) for 5 hours.
The same experimental procedure was followed for the synthesis of ZnO nanostructures carried out in the presence of albumen (sample B), by adding drop by drop 5 mL of freshly extracted albumen, mixed with 25 mL of deionized water and stirred, to 0.1 M zinc hydroxyl solution.
The sample microstructure was analyzed by X-ray diffraction (XRD) using a Bruker AXS D8 Advance instrument and the monochromatic CuKα1 wavelength of 1.5406 Ǻ. The average crystalline size of the crystallites was evaluated using Scherrer’s formula, , where is the mean crystalline size, is a grain shape dependent constant (0.9), λ is the wavelength of the incident beam, θ is a Bragg reflection angle, and β is the full width at half maximum (FWHM) of the main diffraction peak. The sample morphology was observed by scanning electron microscopy (SEM), using a JEOL 5600LV microscope at an accelerating voltage of 10 kV. High resolution transmission electron microscopy (HRTEM) and selected-area electron diffraction (SAED) were recorded on a Tecnai G20-stwin using an accelerating voltage of 200 kV. The Fourier transform infrared spectra (FT-IR) of the samples were recorded by using a Nicolet 5DX FTIR spectrometer. Thermal analysis was carried out by using a thermogravimetric and differential scanning calorimeter apparatus (TG-DSC Netzsch—Model STA 409PC). The analyses were carried out with a heating rate of 10°C/min in static air up to 800°C. The ultraviolet (UV) spectrum of the ZnO samples was recorded on a Perkin Elmer UV-visible DRS spectrophotometer. The room-temperature PL spectrum was performed on a spectrofluorometerinstrument (JY Fluorolog-FL3-11).
3. Results and Discussion
3.1. Morphological and Microstructural Analysis
3.1.1. Thermogravimetric Analysis
The thermal behavior of ZnO samples synthesized has been first investigated by TG-DTA. Figure 1(a) shows the TG-DTA curves of sample A. The weight loss monitored in the range 25–600°C is low and has been calculated to be less than 3.3% in total. This weight loss is ascribed to the removal of absorbed water molecules and ethanol and the loss of hydroxyl ions. The final step at higher temperature is attributed to the burnout of organic species still remained in the dried powder. By focusing the attention on sample B, TGA indicated that the weight loss is higher (about 20% in total). The first weight loss in the temperature range between 25°C and 150°C is ascribed to the removal of adsorbed water molecules. The second weight loss in the range between 230°C and 520°C comes from the decomposition of the organic template, which is also confirmed by the exothermic peak at about 384°C in the DTA curve.
3.1.2. X-Ray Diffraction
The phase identification of the synthesized ZnO nanostructures was determined by X-ray diffraction (XRD). Figures 2(a) and 2(b) show the XRD patterns of both samples. In Figure 2(a), XRD of sample A indicated that two phases, like ZnO hexagonal wurtzite phase structure (JCPDS number 897102) and Zn(OH)2 orthorhombic phase structure (JCPDS number 890138), are present. On the basis of diffraction peaks intensity, ZnO is the predominant phase. According to Scherrer’s equation, the average particle size of ZnO nanoparticles is about 29 nm.
Figure 2(b) shows the XRD pattern of sample B. The diffraction planes (100), (002), (101), (102), (110), (103), (200), (112), and (201) in the patterns can be perfectly indexed to the hexagonal wurtzite phase structure (JCPDS number 897102). Also no diffraction peaks corresponding to Zn, Zn(OH)2, and other impurities are observed. The value of lattice parameters ( = 3.2896 Å and = 5.2624 Å), as calculated by the XRD data, is in good agreement with those reported by other authors . The average particle size of ZnO is estimated to be around 14 nm.
XRD analysis indicates that the pure ZnO phase is obtained only in the presence of albumen. Furthermore, the average particle size of ZnO phase is markedly lower. It can be supposed that, in the formation processes in absence of albumen, the zinc hydroxide species was first produced step by step by the reaction between the Zn species and the hydroxyl ions coming from dissociation of hydrated ammonia molecules, and then in a consecutive reaction ZnO nanoparticles are formed. In the presence of template molecules, it appears that this second reaction is strongly promoted; so all initial zinc hydroxide species are transformed into ZnO.
3.1.3. Fourier Transform Infrared Spectroscopy
Figure 3(a) shows the typical FT-IR spectrum of sample A. The broad peak at 3706 cm−1 corresponds to the vibrational mode of O–H bond, indicating the presence of zinc hydroxide. The stretching mode of vibrations in asymmetric and symmetric C=O bonds that is observed at 1381 cm−1 is associated with residual organic impurity in the dried powder as suggested by TG-DTA analysis.
In the spectrum of sample B (Figure 3(b)), the appearance of a sharp band at 437 cm−1 in the FT-IR spectrum, characteristic for the Zn–O stretching vibration , confirms the presence of well-crystallized ZnO. Additionally broad absorption peaks centered at around 3470 cm−1 and 1652 cm−1 are caused by the O–H stretching of the absorbed water reabsorption during the storage of the sample in ambient air . The absence of features at 3706 cm−1 is an indication of the absence of Zn(OH)2 phase on this sample. In this sample are also seen the signatures of the organic template. The broad peak at 3470 cm−1 is in fact due to superimposition of N–H stretching of amide group at 3449 cm−1 of the biotemplate and O–H stretching mode of water molecules. Also some of the absorption bands in the range 1000–1600 cm−1 are due to C=O and C=C stretching vibrational modes of albumen, as well the weak peaks located at 2930 cm−1 are due to symmetric and asymmetric C–H bonds, respectively . A very small band originated at 887 cm−1 is probably due to the carbonate moieties which are generally observed when FT-IR samples are measured in air [37, 38].
3.1.4. Scanning and Transmission Electron Microscopy
SEM and TEM images of sample A are reported in Figure 4. SEM analysis shows extensive sheet-like nanostructure where spherical-shaped particles are also present. TEM analysis evidences clearly this composite structure and the large diameter distribution of the spherical-shaped nanoparticles. No attempt has been made to assign the two phases present, ZnO and Zn(OH)2, to each of these nanostructures. The thickness of the sheets and spherical particles is in the range of about 13–50 nm. The SAED pattern taken from one of the particles is shown in the inset, and it further confirms the crystalline nature of the sample. In addition, the EDS spectrum of the sample confirms the presence of Zn and O in sample without any other element contamination. The atomic percent ratio of O and Zn in dried sample is 41.15 : 58.85, which might indicate that there is a small content of oxygen vacancy defects on the surface of as-obtained product.
Figure 5 shows SEM and TEM images of sample B. SEM analysis shows that this sample is characterized by a more uniform surface sheet-like nanostructure. TEM analysis revealed the presence of nanowhiskers and nanorods of different length and diameter embedded within the sheet matrix. The thickness of the nanorods and nanowhiskers is in the range of about 10–57 nm. The SAED pattern of ZnO nanostructures further confirms the crystalline nature of the sample. EDS analysis reports that the atomic percent ratio of O and Zn in the dried sample is 85.59 : 14.11, which might indicate that there is a larger content of oxygen on the surface with respect to sample A.
3.2. Optical Properties
In order to determine the precise value of optical band gap UV-visible DRS of the ZnO nanoparticles in samples A and B, we used the optical absorption method on reflectance spectrum. The reflectance values were converted to absorbance by application of the Kubelka-Munk function [39–42]. The Kubelka-Munk theory is generally used for analyzing the diffuse reflectance spectra obtained from weakly absorbing samples. The Kubelka-Munk formula can be expressed by the following relation : where is the reflectance transformed according to Kubelka-Munk and is the reflectance (%).
The relationship is shown in Figures 6(a) and 6(b). The value can be obtained by extrapolating the linear portion to the photon energy axis. The reflectance shoulder onset peaks are located at 393 nm and 386 nm corresponding to the band gaps of 3.15 eV and 3.21 eV, respectively. The values are smaller than that of 3.3 eV reported for single crystalline ZnO samples. On comparison with ZnO nanoparticles prepared by other methods, ZnO nanoparticles are obtained by this microwave irradiation method showing larger band gap energy. It is well known that the difference in the band gap is related to the presence of vacancies and dopants . The red shift of the band gap energy also relates to structural morphologies, particle size, and surface microstructures . Then, the higher value of band gap of the sample B synthesized in the presence of albumen can be attributed to a minor amount of defects, due essentially to its more ordered crystalline structure.
The study of the photoluminescence properties is interesting because it can provide valuable information on the quality, purity, and the structural properties of the material. Moreover, recording PL spectrum is of paramount importance for evaluating their optical characteristics for various applications. The PL spectra of samples A and B are depicted in Figures 7(a) and 7(b). On sample A, three emission peaks, a blue light at 400 nm, a blue-green around 464 nm, and a green light at around 520 nm, were recorded. The main strong UV emission at 400 nm corresponds to the near-band-edge emission, while the blue-green and green emission peaks at 464 nm and 520 nm are instead possibly associated with oxygen vacancies [46, 47]. Specifically, the blue-green transition at 464 nm is caused due to transition from the level of ionized oxygen vacancy to the valence band, while the green emission, called deep-level emission, occurs by the recombination of the photogenerated holes with singly ionized oxygen vacancies in ZnO. On sample B, an additional UV emission peak at 385 nm, due to the recombination of photogenerated electrons and holes, appears as a shoulder of the main peak at 400 nm. The higher intensity of near-band-edge emission peaks compared to green emission peaks is an indication of the good quality of ZnO nanostructures produced.
The morphology, structure, and optical properties of ZnO nanostructures synthesized by microwave irradiation have been investigated in detail. The composition and morphology of the nanostructures are affected by the presence of albumen as a template. The optical band gap of the polycrystalline ZnO nanoparticles increases from 3.22 to 3.25 eV for the sample synthesized in the presence of albumen because of the defects’ decrease. The good quality of ZnO nanostructures produced was also demonstrated by PL studies which evidenced a higher intensity of near-band-edge emission peaks compared to green emission peaks. In summary, results obtained indicate that the microwave-assisted method is a promising low temperature, cheap, and fast method for the production of ZnO nanostructures.
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