Understanding the Polar Character Trend in a Series of Diels-Alder Reactions Using Molecular Quantum Similarity and Chemical Reactivity Descriptors
Table 1
Reaction rate constant () with the factor 105 [M−1S−1] and activation energy (kcal/moL) for the DA reactions of cyclopentadiene (Cp) as nucleophile with dienophiles at 20°C; see [13] reported by Sauer et al. [14] and also see [15–20].