About this Journal Submit a Manuscript Table of Contents
Journal of Thermodynamics
Volume 2012 (2012), Article ID 575728, 6 pages
http://dx.doi.org/10.1155/2012/575728
Research Article

Glass Transition Behavior of the Quaternary Ammonium-Type Ionic Liquid: N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium Bromide-H2O Mixtures

1Department of Applied Chemistry, National Defense Academy, Yokosuka, Kanagawa 239-8686, Japan
2Department of Materials Science and Engineering, National Defense Academy, Yokosuka, Kanagawa 239-8686, Japan
3Department of Applied Chemistry, Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan

Received 14 July 2011; Revised 22 August 2011; Accepted 23 August 2011

Academic Editor: Ramesh Gardas

Copyright © 2012 Yukihiro Yoshimura et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. T. Sato, G. Masuda, and K. Takagi, “Electrochemical properties of novel ionic liquids for electric double layer capacitor applications,” Electrochimica Acta, vol. 49, pp. 3603–3611, 2004. View at Publisher · View at Google Scholar
  2. M. J. Earle, P. B. McCormac, and K. R. Seddon, “Diels-Alder reactions in ionic liquids: a safe recyclable alternative to lithium perchlorate-diethyl ether mixtures,” Green Chemistry, vol. 1, no. 1, pp. 23–25, 1999. View at Scopus
  3. D. Kerle, R. Ludwig, A. Geiger, and D. Paschek, “Temperature dependence of the solubility of carbon dioxide in imidazolium-based ionic liquids,” Journal of Physical Chemistry B, vol. 113, no. 38, pp. 12727–12735, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. M. Galiński, A. Lewandowski, and I. Stepniak, “Ionic liquids as electrolytes,” Electrochimica Acta, vol. 51, no. 26, pp. 5567–5580, 2006. View at Publisher · View at Google Scholar · View at Scopus
  5. Y. Imai, H. Abe, T. Goto, Y. Yoshimura, Y. Michishita, and H. Matsumoto, “Structure and thermal property of N,N-diethyl-N-methyl-2-methoxyethyl ammonium tetrafluoroborate-H2O mixtures,” Chemical Physics, vol. 352, pp. 224–230, 2008.
  6. W. Xu, L. M. Wang, R. A. Nieman, and C. A. Angell, “Ionic liquids of chelated orthoborates as model ionic glassformers,” Journal of Physical Chemistry B, vol. 107, no. 42, pp. 11749–11756, 2003. View at Scopus
  7. J. G. Huddleston, A. E. Visser, W. M. Reichert, H. D. Willauer, G. A. Broker, and R. D. Rogers, “Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation,” Green Chemistry, vol. 3, no. 4, pp. 156–164, 2001. View at Publisher · View at Google Scholar · View at Scopus
  8. J. L. Anderson, J. Ding, T. Welton, and D. W. Armstrong, “Characterizing ionic liquids on the basis of multiple solvation interactions,” Journal of the American Chemical Society, vol. 124, no. 47, pp. 14247–14254, 2002. View at Publisher · View at Google Scholar · View at Scopus
  9. K. R. Seddon, A. Stark, and M. J. Torres, “Influence of chloride, water, and organic solvents on the physical properties of ionic liquids,” Pure and Applied Chemistry, vol. 72, no. 12, pp. 2275–2287, 2000. View at Scopus
  10. K. Nishikawa and K. I. Tozaki, “Intermittent crystallization of an ionic liquid: 1-isopropyl-3-methylimidazolium bromide,” Chemical Physics Letters, vol. 463, no. 4–6, pp. 369–372, 2008. View at Publisher · View at Google Scholar · View at Scopus
  11. G. J. Kabo, A. V. Blokhin, Y. U. Paulechka, A. G. Kabo, M. P. Shymanovich, and J. W. Magee, “Thermodynamic properties of 1-butyl-3-methylimidazolium hexafluorophosphate in the condensed state,” Journal of Chemical and Engineering Data, vol. 49, no. 3, pp. 453–461, 2004. View at Publisher · View at Google Scholar · View at Scopus
  12. O. Yamamuro, Y. Minamimoto, Y. Inamura, S. Hayashi, and H. O. Hamaguchi, “Heat capacity and glass transition of an ionic liquid 1-butyl-3-methylimidazolium chloride,” Chemical Physics Letters, vol. 423, no. 4-6, pp. 371–375, 2006. View at Publisher · View at Google Scholar · View at Scopus
  13. Y. Imai, H. Abe, T. Miyashita, T. Goto, H. Matsumoto, and Y. Yoshimura, “Two glass transitions in N, N- diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate-H2O mixed solutions,” Chemical Physics Letters, vol. 486, no. 1–3, pp. 37–39, 2010. View at Publisher · View at Google Scholar · View at Scopus
  14. Y. Imai, H. Abe, H. Matsumoto, O. Shimada, T. Hanasaki, and Y. Yoshimura, “Glass transition behaviour of the quaternary ammonium type ionic liquid, [DEME][I]-H2O mixtures,” Journal of Chemical Thermodynamics, vol. 43, no. 3, pp. 319–322, 2011. View at Publisher · View at Google Scholar · View at Scopus
  15. R. Kiefer, S. Y. Chu, P. A. Kilmartin, G. A. Bowmaker, R. P. Cooney, and J. Travas-Sejdic, “Mixed-ion linear actuation behaviour of polypyrrole,” Electrochimica Acta, vol. 52, no. 7, pp. 2386–2391, 2007. View at Publisher · View at Google Scholar · View at Scopus
  16. H. D. B. Jenkins, H. K. Roobottom, J. Passmore, and L. Glasser, “Relationships among ionic lattice energies, molecular (formula unit) volumes, and thermochemical radii,” Inorganic Chemistry, vol. 38, no. 16, pp. 3609–3620, 1999. View at Scopus
  17. M. S. Sethi and M. Satake, Periodic Tables and Periodic Properties, Discovery Publishing House, Delhi, India, 2003.
  18. E. R. Nightingale Jr., “Phenomenological theory of ion solvation. Effective radii of hydrated ions,” Journal of Physical Chemistry, vol. 63, no. 9, pp. 1381–1387, 1959. View at Scopus
  19. Z. B. Zhou, H. Matsumoto, and K. Tatsumi, “Low-melting, low-viscous, hydrophobic ionic liquids: aliphatic quaternary ammonium salts with perfluoroalkyltrifluoroborates,” Chemistry—A European Journal, vol. 11, no. 2, pp. 752–766, 2005. View at Publisher · View at Google Scholar · View at Scopus
  20. Y. Imai, H. Abe, T. Goto, Y. Yoshimura, Y. Michishita, and H. Matsumoto, “Structure and thermal property of N, N- diethyl-N-methyl-N-2-methoxyethyl ammonium tetrafluoroborate-H2O mixtures,” Chemical Physics, vol. 352, no. 1–3, pp. 224–230, 2008. View at Publisher · View at Google Scholar · View at Scopus
  21. H. Kanno, K. Shimada, and K. Katoh, “Two glass transitions in the tetraethylammonium chloride-water system: evidence for a metastable liquid-liquid immiscibility at low temperatures,” Chemical Physics Letters, vol. 103, no. 3, pp. 219–221, 1983. View at Scopus
  22. H. Kanno, K. Shimada, K. Yoshino, and T. Iwamoto, “Anomalous concentration dependence of the glass transition temperature for aqueous tetrapropylammonium chloride solution,” Chemical Physics Letters, vol. 112, no. 3, pp. 242–245, 1984. View at Scopus
  23. H. Kanno, K. Shimada, and T. Katoh, “A glass formation study of aqueous tetraalkylammonium halide solutions,” Journal of Physical Chemistry, vol. 93, no. 12, pp. 4981–4985, 1989. View at Scopus
  24. G. S. Fulcher, “Analysis of recent measurements of the viscosity of glasses,” Journal of the American Ceramic Society, vol. 6, pp. 339–355, 1925.
  25. Y. Yoshimura, T. Goto, H. Abe, and Y. Imai, “Existence of nearly-free hydrogen bonds in an ionic liquid, N, N- diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate-water at 77 K,” Journal of Physical Chemistry B, vol. 113, no. 23, pp. 8091–8095, 2009. View at Publisher · View at Google Scholar · View at Scopus
  26. L. Cammarata, S. G. Kazarian, P. A. Salter, and T. Welton, “Molecular states of water in room temperature ionic liquids,” Physical Chemistry Chemical Physics, vol. 3, no. 23, pp. 5192–5200, 2001. View at Publisher · View at Google Scholar · View at Scopus
  27. H. Kanno and J. Hiraishi, “Raman spectroscopic study of aqueous LiX and CaX2 solutions (X=Cl, Br, and I) in the glassy state,” Journal of Physical Chemistry, vol. 87, no. 19, pp. 3664–3670, 1983. View at Scopus
  28. Y. Yoshimura, H. Kimura, C. Okamoto, T. Miyashita, Y. Imai, and H. Abe, “Glass transition behaviour of ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate-H2O mixed solutions,” Journal of Chemical Thermodynamics, vol. 43, no. 3, pp. 410–412, 2011. View at Publisher · View at Google Scholar · View at Scopus