Modified Lennard-Jones Potentials with a Reduced Temperature-Correction Parameter for Calculating Thermodynamic and Transport Properties: Noble Gases and Their Mixtures (He, Ne, Ar, Kr, and Xe)

Table 2

Deviations between experimental and calculated second virial coefficients of pure noble gases.

Compound	Number of data points	Average RMSD in 𝐵 (cm^3 mol^−1)					Δ𝑇 (K)	Reference
		Present study	Dymond et al.	L-J	Kihara	Tsonopoulos
Regression results
Helium	304	5.44	5.07^a	10.9	10.8	39.1	2–1473	[2]
Neon	55	0.28	0.34	0.45	1.38	1.56	44–873	[2]
Argon	105	0.40	0.53	2.43	1.73	1.88	75–773	[2]
Krypton	157	2.87	3.18	5.75	3.67	6.90	107–873	[2]
Xenon	114	2.50	2.67	4.32	2.53	3.51	160–973	[2]
Average	735	3.33	3.29	6.79	5.99	18.6
Prediction results
Helium	8	4.13	1.08	10.8	4.29	14.9	343–374	[27]
Xenon	9	0.50	1.37	2.57	2.11	2.57	206–273	[28]
Average	17	2.21	1.23	6.44	3.14	8.37

aTwo different smoothing functions were used in the temperature ranges between 1.59 K and 35.1 K, and between 35.1 K and 1473.15 K.