Research Letters in Organic Chemistry
Volume 2008 (2008), Article ID 404936, 5 pages
doi:10.1155/2008/404936
Research Letter
Dynamical Model to Describe the Interactions between the Chemical
Components in Environment of Photopolymerization of MMA by Dye/Amine Systems
Universidade do Vale do Paraíba (UniVap), Avenida Shishima Hifumi 2991, Urbanova, CEP 12244-000 São José dos Campos, SP, Brazil
Received 24 June 2008; Accepted 12 August 2008
Academic Editor: Daniel Little
Copyright © 2008 Marcio Magini and Máira R. Rodrigues. This is an open access article distributed under the
Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Linked References
- D. R. Randall, Radiation Curing of Polymers II, Royal Society of Chemistry, Cambridge, UK, 1991.
- D.C. Sherrington and P. Hodge, Synthesis and Separations Using Functional Polymers, John Wiley & Sons, New York, NY, USA, 1988.
- J. P. Fouassier, Photoinitiation, Photopolymerization and Photocuring: Fundamentals and Applications, Hanser, Munich, Germany, 1995.
- P. Pappas, UV Curing Science and Technology, Technology Marketing, New York, NY, USA, 1992.
- F. Higashi and S. Koyanagi, “The effect of compositions and combinations of the reactants upon the copolycondensation of isophthalic acid/terephthalic acid with a combination of hydroquinones and bisphenols by tosyl
chloride/dimethylformamide/pyridine,” Journal of Polymer Science Part A, vol. 42, no. 5, pp. 1100–1106, 2004. View at Publisher · View at Google Scholar
- X. Allonas, J. Lalevée, and J.-P. Fouassier, “Investigation of cleavage processes in photoinitiators: from experiments to molecular modeling,” Journal of Photochemistry and Photobiology A, vol. 159, no. 2, pp. 127–133, 2003. View at Publisher · View at Google Scholar
- M. G. Neumann and M. R. Rodrigues, “A study of the elemental reactions involved in the initiation of the polymerization of tetrahydrofuran inducted by the photosensitization of a triphenylsulphonium salt by perylene,” Journal of the Brazilian Chemical Society, vol. 14, no. 1, pp. 76–82, 2003. View at Publisher · View at Google Scholar
- M. R. Rodrigues and M. G. Neumann, “Cationic photopolymerization of tetrahydrofuran: a mechanistic study on the use of a sulfonium salt-phenothiazine initiation system,” Journal of Polymer Science Part A, vol. 39, no. 1, pp. 46–55, 2001. View at Publisher · View at Google Scholar
- M. R. Rodrigues and M. G. Neumann, “Mechanistic study of tetrahydrofuran polymerization photoinitiated by a sulfonium salt/thioxanthone system,” Macromolecular Chemistry and Physics, vol. 202, no. 13, pp. 2776–2782, 2001. View at Publisher · View at Google Scholar
- M. G. Neumann and M. R. Rodrigues, “The mechanism of the photoinitiation of the polymerization of MMA by the thionine-triethanolamine system,” Polymer, vol. 39, no. 8-9, pp. 1657–1661, 1998. View at Publisher · View at Google Scholar
- M. R. Rodrigues, F. Catalina, and M. G. Neumann, “Photoinitiation of MMA polymerization by thionine/amine systems in the presence of SDS micelles,” Journal of Photochemistry and Photobiology A, vol. 124, no. 1-2, pp. 29–34, 1999. View at Publisher · View at Google Scholar
- M. R. Rodrigues, F. Catalina, and M. G. Neumann, “MMA photopolymerization initiated by thionine/triethylamine,” Journal of Photochemistry and Photobiology A, vol. 127, no. 1–3, pp. 147–152, 1999. View at Publisher · View at Google Scholar
- M. H. Gehlen, S. F. Buchviser, M. R. Rodrigues, and M. G. Neumann, “Photoinitiation of vinyl polymerization,” Química Nova, vol. 21, no. 6, pp. 794–801, 1998.
- M. R. Rodrigues and M. G. Neumann, “Fotopolimerização: princípios e métodos,” Polímeros: Ciência e Tecnologia, vol. 13, no. 4, pp. 277–287, 2003.
- P. Bosch, A. Fernández, E. F. Salvador, T. Corrales, F. Catalina, and C. Peinado, “Polyurethane-acrylate based films as humidity sensors,” Polymer, vol. 46, no. 26, pp. 12200–12209, 2005. View at Publisher · View at Google Scholar
- G. Odian, Principles of Polymerization, John Wiley & Sons, Hoboken, NY, USA, 2004.
- R. Dickman, Nonequilibrium Statiscal Mechanics in One Dimension, Cambridge University Press, Cambridge, UK, 1997.
- J. A. Corzo E, N. Davidenko, and R. Alvarez, “Photoinitiated bulk polymerization of furfuryl methacrylate. Stochastic simulation results using the new model CORUB,” Computational and Theoretical Polymer Science, vol. 11, no. 2, pp. 89–94, 2001. View at Publisher · View at Google Scholar
- J. Lange, J. Rieumont, N. Davidenko, and R. Sastre, “Kinetics modelling of the crosslinking in the photopolymerization of furfuryl methacrylate in bulk,” Computational and Theoretical Polymer Science, vol. 9, no. 1, pp. 63–72, 1999. View at Publisher · View at Google Scholar
- O. L. Bottecchia, “A model of the growth of copper selenide thin films controlled by diffusion and chemical reaction,” Journal of the Brazilian Chemical Society, vol. 9, no. 6, pp. 515–520, 1998. View at Publisher · View at Google Scholar
- J. R. Pliego, Jr., A. F. de C. Alcântara, D. P. Veloso, and W. B. de Almeida, “Theoretical and experimental investigation of the formation of - and -aldimines from the reaction of methylamine with acetaldehyde,” Journal of the Brazilian Chemical Society, vol. 10, no. 5, pp. 381–388, 1999. View at Publisher · View at Google Scholar
- L. Krentsel, F. Chaubet, A. Rebrov, et al., “Anticoagulant activity of functionalized dextrans. Structure analyses of carboxymethylated dextran and first Monte Carlo simulations,” Carbohydrate Polymers, vol. 33, no. 1, pp. 63–71, 1997. View at Publisher · View at Google Scholar
- L. M. Racz, L. Li, and B. Abedian, “Cure kinetics of light-activated polymers,” Journal of Polymer Science Part B, vol. 36, no. 16, pp. 2887–2894, 1998. View at Publisher · View at Google Scholar
- G. A. Miller, L. Gou, V. Narayanan, and A. B. Scranton, “Modeling of photobleaching for the photoinitiation of thick polymerization systems,” Journal of Polymer Science Part A, vol. 40, no. 6, pp. 793–808, 2002. View at Publisher · View at Google Scholar
- L. Lecamp, B. Youssef, C. Bunel, and P. Lebaudy, “Photoinitiated polymerization of a dimethacrylate oligomer: 2. Kinetic studies,” Polymer, vol. 40, no. 6, pp. 1403–1409, 1999. View at Publisher · View at Google Scholar
- T. M. Lovestead, J. A. Burdick, K. S. Anseth, and C. N. Bowman, “Understanding multivinyl monomer photopolymerization kinetics through modeling and GPC investigation of degradable networks,” Polymer, vol. 46, no. 16, pp. 6226–6234, 2005. View at Publisher · View at Google Scholar
- M. Magini and M. R. Rodrigues, “A dynamical system to describe the cationic photopolymerization of tetrahydrofuran initiated by systems sensitizer-sulfonium salt,” Polymer, vol. 46, no. 10, pp. 3489–3495, 2005. View at Publisher · View at Google Scholar
- J. Lalevée, X. Allonas, and J.-P. Fouassier, “N-H and (C-H) bond dissociation enthalpies of aliphatic amines,” Journal of the American Chemical Society, vol. 124, no. 32, pp. 9613–9621, 2002. View at Publisher · View at Google Scholar
- T. Corrales, F. Catalina, C. Peinado, and N. S. Allen, “Free radical macrophotoinitiators: an overview on recent advances,” Journal of Photochemistry and Photobiology A, vol. 159, no. 2, pp. 103–114, 2003. View at Publisher · View at Google Scholar