Table 2: Correlation of the specific rates of reaction of , at C using equations (1)-(4).

Substrate S 1; 25.0oC 0.76 0.03 −0.25 0.08 0.975 571 0.09 0.09 0.79 0.04 −0.21 0.09 0.976 288 0.79 0.03 0.47 0.20 −0.30 ± 0.08 0.979 331 0.33 0.08 0.91 0.04 0.97 0.21 −0.20 ± 0.07 0.987 340 0.79 0.03 −0.33 ± 0.08 0.979 664 0.09 0.08 0.82 ± 0.04 −0.29 ± 0.09 0.980 337 0.82 0.03 0.49 0.17 −0.38 ± 0.07 0.984 416 0.33 0.06 0.95 0.03 1.00 0.16 −0.29 ± 0.06 0.992 551 0.73 0.03 −0.15 ± 0.08 0.977 594 0.06 0.74 0.04 −0.13 ± 0.09 0.978 291 0.75 0.03 0.37 0.19 −0.21 ± 0.08 0.980 327 0.36 0.11 0.90 0.05 0.88 0.23 −0.15 ± 0.07 0.986 295

Using data at C from Table 1; values from refs. [9, 10]; values from refs.[5, 6]; the 70-0% MeOH, 80-10% Acetone, 100TFE, 70TFE(w/w), 50TFE(w/w) values are from reference [23]; is the number of solvents. With associated standard error. Accompanied by standard error of the estimate. Correlation coefficient. F-test value. All solvents. Probability that the contribution to the linear free energy relationship is insignificant. Excluding 100EtOH. In exactly the same solvents as 2.