Table 1:
N-arylation of 1,2,4 triazoles.
Entry
Azoles
Aryl iodide
Reaction temperature/h
(Yield)
a
(1)
RT/2 h
84%
(2)
RT/2 h
91%
(3)
RT/4 h
72%
(4)
RT/4 h
56%
(5)
RT/2 h
78%
(6)
RT/4 h
60%
a
Isolated yield: 1,2,4-triazoles (3 mmol), iodobenzene (3.3 mmol), CuO nanoparticles (0.15 mmol), K
2
CO
3
(3 mmol), and N–N dimethyl formamide (10 mL) at room temperature.