Research Article

Trace Level Arsenic Quantification through Cloud Point Extraction: Application to Biological and Environmental Samples

Table 5

Determination of arsenic in different environmental samples.

SampleAs(V) found in samples As(III) + As(V) found in samplesAs(V) added (ng)Total arsenicRecovery (%)
Proposed methodProposed methodICPAES methodProposed methodICPAES methodProposed methodICPAES method

Polluted water*ND 5 0 0 ± 1 2 4 9 9 ± 1 3
Bore well water*ND 2 0 0 ± 1 3 2 0 0 ± 1 1 20 2 2 0 ± 1 2 2 2 0 ± 1 2 100100
Polluted soil 3 2 ± 2 . 0 9 9 . 0 ± 9 . 1 9 8 . 0 ± 8 . 3
Spinach leaves (Spinacia oleracea)ND 2 1 0 ± 1 2 2 0 9 ± 1 2 20 2 3 0 ± 1 0 2 2 9 ± 1 2 100 99.5
Tomato leaves (Lycopersicon esculentum)ND 5 0 0 ± 1 5 4 4 9 ± 1 1 10 5 9 0 ± 1 2 6 0 0 ± 1 5 98.3100

𝑛 = 5 ; the values given here are average of five measurements.
ND: Not detected.
*Concentration in ng mL−1.
Concentration in ng g−1.