Application of Hyphenated Techniques in Speciation Analysis of Arsenic, Antimony, and Thallium

Table 1

Selected examples of application of hyphenated techniques in arsenic speciation.

Analytes	Analytical column	Mobile phase	Method of separation and detection	Matrix	Reference
As^3+, As^5+, MMA, DMA	Hamilton PRP-X100; Dionex AS7, AG7	75 mM Na3PO4,; 2.5–50 mM HNO3	HPLC-ICP-MS	Surface water, mining water, underground water	[22]
As^3+, As^5+, MMA, DMA, AB, AC	Waters IC-Pak CM/D; Waters Guard-Pak CM/D	NaHCO3/Na2CO3, HNO3	HPLC-ICP-MS	Water	[23]
As^3+, As^5+, MMA, DMA	Hamilton PRP-X100	10–200 mM NH4H2PO4	HPLC-ICP-DRC-MS	Sediments	[24]
As^3+, As^5+, MMA, DMA	Hamilton PRP-X100	30 mM NH4H2PO4	HPLC-ICP-MS	Soils	[25]
As^3+, As^5+, MMA, DMA, AB	Hamilton PRP-X100	20 mM NH4H2PO4	HPLC-ICP-DRC-MS	Polluted waters, leach	[26]
As^3+, As^5+, MMA, DMA, AB	Dionex AG-11, AS-11	NaOH, HNO3	HPLC-ICP-MS	Urine	[27]
As^3+, As^5+,; MMA, DMA, AB, AC	Hamilton PRP-X100	0.3% HNO3, 10% methanol	HPLC-ICP-MS, HPLC-ESI MS	Fish sauce	[28]
As^3+, As^5+	Hamilton PRP X-100	Na2CO3	HPLC-ICP-MS	Surface water	[29]
As^3+, As^5+, MMA, DMA	Dionex AS7	HNO3	HPLC- ICP-MS, HPLC- INAA	Waters, rice extracts	[30]
As^3+, As^5+	Dionex AS9	NaOH, Na2CO3, NaHCO3	HPLC-SF-ICP-MS	Soils	[31]
As^3+, As^5+	Wescan Anion-S C18	EDTA	HPLC- ICP-MS	River waters, sludge	[32]
As^3+, As^5+	Biosil 125 SEC	CH3COONH4	HPLC- ICP-MS	Fish tissues	[33]
As^3+, As^5+	Waters IC-Pak A HC	NaOH, KNO3	HPLC- ICP-MS	Water, sludge	[34]
As^3+, As^5+, MMA, DMA, AB, AC	Develosil C30-UG-5, Chemcosorb 7SAX	sodium butanesulfonate, malonic acid, tetramethylammonium hydroxide, methanol, ammonium tartrate	HPLC- ICP-MS	Biological and environmental samples	[35]
As^3+, As^5+, MMA, DMA, AB	Dionex AG7, AS7	nitric acid, 1-benzene-2-disulfonic acid dipotassium salt	HPLC-ICP-MS	Seafood	[36]
As^3+, As^5+, MMA, DMA	Hamilton PRP-X100	NH4H2PO4, NH4HPO4, CH3COONH4, NaHCO3, NH4NO3	HPLC-ICP-MS	Soils, plant tissues	[37]
As^3+, As^5+	Dionex AG12A/AS 12A	disodium carbonate, sodium hydroxide, methanol	HPLC-ICP-MS	Iron rich water samples	[38]
As^3+, As^5+, MMA, DMA	Hamilton PRP X100	NH4NO3	HPLC-ICP-MS	Water	[39]
As^3+, As^5+, MMA, DMA	Hamilton PRP X100,	NH4H2PO4	HPLC- DF-ICP-MS	Cucumber sap	[40]
As^3+, As^5+, MMA, DMA, AB	Hamilton PRP X100	NH4H2PO4, NH4HPO4, MeOH	HPLC-ICP-MS	Rice, soil, straw, hair, nails	[41]
As^3+, As^5+, MMA, DMA, AB, AC, TMAO	Hamilton PRP X100, Zorbax 300-SCX	pyridine, NH4H2PO4	HPLC-SF-MS	Water, sediments, plants	[42]
As^3+, As^5+, DMA	G 3154A/101	EDTA, NH4H2PO4	HPLC-ICP-MS	Soils	[43]
As^3+, As^5+, MMA, DMA, AB	65001 and 65002	Na2EDTA, NH4H2PO4	HPLC-ICP-MS	Urine	[44]
As^3+, As^5+,MMA, DMA, AB	Supelcosil LC-SCX	pyridine, NaHCO3, Na2CO3	HPLC-ICP-MS; HPLC-ES-MS	Hair, nail	[45]
As^3+, As^5+, MMA, DMA, AB, AC, TMAO	Dionex AG7, AS7	HNO3, MeOH	HPLC-ICP-MS	Seafood	[46]
As^3+, As^5+, MMA, DMA, AB	Dionex AS14, AS16, AS7	NaOH, NH4H2PO4	HPLC-ICP-MS	Poultry wastes	[47]
As^3+, As^5+, MMA, DMA, AB	Shodex Asahipak ES-502 N 7Ca	HNO3, MeOH	HPLC-ICP-MS	Biological samples	[48]
As^3+, As^5+, MMA, DMA, AB	Hamilton PRP X100	(NH4)2SO4, (NH4)3PO4, NH4HCO3	HPLC-ICP-MS	Urine	[49]
As^3+, As^5+, MMA, DMA	Hamilton PRP X100	MeOH, NH4H2PO4	HPLC-ICP-MS	Peanut butter	[50]
As^3+, As^5+, MMA, DMA	Hamilton PRP X100	(NH4)2HPO4, NH4H2PO4	HPLC-ICP-MS	Wool	[51]
As^3+, As^5+, MMA, DMA, AC, AB, TMAO, TMAs	Hamilton PRP X100	NH4HPO4, (NH4)2HCO3, pyridine, MeOH	HPLC-ICP-MS,; HPLC-ES-MS	Chinese seaweeds	[52]
As^3+, As^5+, MMA, DMA, AB	Hamilton PRP X100	NH4HPO4, NH4H2PO4	HPLC-ICP-MS	Biological samples (fish, rice, chicken)	[53]
As^3+, As^5+, MMA, DMA, AB	Dionex AS7	NH4H2PO4, NH4OH	HPLC-ICP-MS	Waters	[54]
As^3+, As^5+, MMA, DMA, AB, AC, TMAO, TMAI	Excelpak CHA-E11	HNO3	HPLC-ICP-MS	Rats urine	[55]
As^3+, As^5+, MMA, DMA, AB, AC	Dionex AS7, AG7	NaHCO3, Na2CO3	HPLC-ICP-MS	Fish, mussel extracts	[56]
As^3+, As^5+, MMA, DMA, AB, AC, TMAO, TeMAs^+	Dionex AS7, AG7	HNO3, benzene-1,2-disulfonic acid	HPLC-ICP-MS	Fish oil	[57]
As^3+, As^5+, MMA, DMA, AC, AB; TMAO, TeMAs^+	Dionex AG4, AS4A	HNO3	HPLC-ICP-MS	Marine samples	[58]
As^3+, As^5+, MMA, DMA	Hamilton PRP X100	(NH4)2HPO4, MeOH	HPLC-ICP-MS	Soil extracts	[59]
As^3+, As^5+	Hamilton PRP X100	CH3COOH, NH4NO3, EDTA	HPLC-ICP-MS	Drinking water	[60]
As^3+, As^5+	Dionex AS12	NaHCO3, Na2CO3	HPLC-HGAAS	Mine tailings	[61]
As^3+, As^5+, MMA, DMA	—	—	FIA-HGAAS	Seawater	[62]
As^3+, Total As	—	0.029 M HNO3, 0.024 M HCl	FIA-HGAAS	Water samples	[63]
As^3+, As^5+	—	—	FI-EHG-AAS	Synthetic samples	[64]
As^3+, As^5+, MMA, DMA	Hamilton PRP-X100	12 mM (NH4)2HPO4, 7.5 mM (NH4)2SO4 10 mM (NH4)2CO3	HPLC-ICP-AES	Synthetic samples	[65]
As^3+, As^5+, MMA, DMA, AC, AB	Hamilton PRP-X100	NH4H2PO4, (NH4)2HPO4	HPLC-NAA	Water samples	[66]
As^3+, As^5+, MMA, DMA	LiChrospher 100 RP-18e adsorbent	tetrabutylammonium hydrogen sulfate	HPLC-ETAAS	Water samples	[67]
As^3+, As^5+, MMA, DMA	Hamilton PRP X-100	2,5 mM NaH2PO4, 2,5 mM Na2HPO4	HPLC-HGAAS	Natural waters	[68]
As^3+, As^5+, MMA, DMA	Alltech All-guard Adsorbosphere SAX 5 μm	10 mM KH2PO4	HPLC-HG-AFS	Particulate matter	[69]
As^3+, As^5+, MMA, DMA	Dionex AS11, AG11	10 mM–100 mM NaOH	HPLC-HG-AFS	Polluted soil	[70]
As^3+, As^5+, MMA, DMA, AC, AB	Spherisorb ODS/NH2	5 mM NaH2PO4, 5 mM Na2HPO4,	HPLC-MO-HG-AAS, HPLC-ICP-MS	Water, urine	[71]