| Analytes | Analytical column | Mobile phase | Method of separation and detection | Matrix | Reference |
| Sb3+, Sb5+ | Hamilton PRP-X100 | 15 mM HNO3 | HPLC- ICP-MS | Plants | [74] | Sb3+, Sb5+ | Develosil C30-UG-5, Chemcosorb 7SAX | Malonic acid, sodium, 1-butylosulfonian, ammonium citrate, methanol | HPLC- ICP-MS | Biological and environmental samples | [35] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100, Dionex AS 14, AG 14 | 20 mM EDTA | HPLC- ICP-MS | Urine | [75, 76] | Sb3+, Sb5+ | Hamilton PRP-X100 | Phthalic acid, EDTA | HPLC- ICP-MS | Soil | [77, 78] | Sb3+, Sb5+ | Hamilton PRP-X100 | 10 mM EDTA, 1 mM phthalic acid | HPLC- ICP-MS | Airborne particulate matter | [79, 80] | Sb3+, Sb5+, TMSbCl2, TMS(OH)2 | Hamilton PRP-X100, Asahipak GS520HG | 10 mM TMAH | HPLC-ICP-MS | Airborne particulate matter | [81, 82] | Sb3+, Sb5+ | Hamilton PRP-X100 | 10 mM EDTA, 1 mM phthalic acid | HPLC-ICP-MS | Soils | [77, 78] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP X-100 | 50 mM diammonium tartrate, 20 mM KOH | IC-HG-AFS, HPLC-ICP-MS | Plant extracts | [83] | Sb3+, Sb5+ | Silica-based solid-phase extraction cartridges | Ammonium pyrrolidine dithiocarbamate | SPE-ICP-MS | Water | [84] | Sb3+, Sb5+ | Hamilton PRP X-100 | 20 mM EDTA | HPLC-ICP-MS | Soil | [85] | Sb3+, Sb5+ | Hamilton PRP X-100 | 10 mM EDTA, 1 mM phthalic acid | HPLC-ICP-MS | Thirteen fractions of airborne particulate matter | [86] | Sb3+, Sb5+, | Dimercaptosuccinic acid chemically modifying mesoporous titanium dioxide microcolumn | Water | SPE-ICP-OES | Natural waters | [87] | Sb3+, Sb5+, TMSbCl2, TMS(OH)2 | Hamilton PRP-X100, Hamilton PRPX-200, Supelcosil LC-SCX, Hamilton PRP1, Phenomenex Intersil 5 ODS | KH2PO4/K2HPO4 0.5–5 mM, KHCO3/K2CO3 1–50 mM, pyridine, 2,6 dicarboxylic acid (PDCA): 5–20 mM EDTA, 5–50 mM HNO3, 1–4 mM, ethylenediamine | HPLC-ICP-MS, HPLC-FAAS | Environmental samples | [88] | Sb3+, Sb5+ | Dionex AS14 | 2 mM NH4HCO3, 2.2–45 mM tartaric acid | HPLC-ICP-MS | Fish extracts | [89] | Sb3+, Sb5+ | — | Chloranilic acid (2,5-dichloro-3,6-dihy-droxy-1,4-benzoquinone) | HMDE | Water | [90] | Sb3+, Sb5+, MMSb4+, DMSb3+, TMSb2+ | Teflon tube packed with SE-30 on Chromosorb W-HP | Liquid nitrogen | HG-SPE-ICP-MS | Surface waters | [91] | Sb3+, Sb5+ | — | 40 mM thioglycolic acid | SPE-ICP-OES, SPE-ICP-MS | Water, yeast extract | [92] | Sb3+, Sb5+ | Hamilton PRP-X100 | 20 mM EDTA, 2 mM KHP | HPLC-ICP-MS | Waters | [93] | Sb3+, Total Sb | — | l-cysteine, hydrochloric acid | HG -AFS | Herbs | [94] | Sb3+, Sb5+ | — | H2O, 0.05 M EDTA, 0.25 M H2SO4 | HG -AFS | Soil | [95] | Sb3+, Sb5+ | Hamilton PRP-X100 | 10 mM EDTA, 1 mM phthalic acid | HPLC-ICP-MS | Moat water | [79, 80] | Sb3+, Sb5+ | Hamilton PRP-X100 | 20 mM EDTA, 2 mM KHP | HPLC-ICP-MS | Citrus juices Mineral water | [96] | Sb3+, Sb5+ | Hamilton PRP-X100 | 5 mM HNO3 | HPLC-ICP-MS | Cell extracts | [74] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100 | 20 mM EDTA, 2 mM KHP | HPLC-HG-AFS | Sea water, | [97] | Sb3+, Sb5+, | Hamilton PRP-X100 | EDTA 2–20 mM | HPLC-ICP-MS, FI-HG-ICP-MS | Biological samples | [98] | Sb3+, Sb5+, TMSbCl2 | Dionex AS15/AG15 | 20 mM EDTA, NH4OH, 1 mM EDTA | HPLC-ICP-MS | Pteris vittata samples | | Sb3+, Sb5+ | Microcolumn with immobilized aminoacid | HCl | HG-ICP-OES | Urine | [99] | Sb3+, Sb5+ | Hamilton PRP-X100 | 200 mM diammonium tartrate | HPLC-HG-AFS | Airborne particulate matter | [100] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100 | 20 mM EDTA + 2 mM potassium hydrogen phthalate, 50 mM diammonium hydrogen phosphate | HPLC-(UV)-HG-AFS | Algae and mollusk extracts | [101] | Sb3+, Sb5+, TMSbO | Hamilton PRP-X100 | 2 mM phthalic acid 2 mM 4-hydroxybenzoic acid | HPLC-ICP-MS, HPLC-ICP-OES | Surface water, soil extracts | [102] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100 | EDTA-K2HPO4 20 mM | HPLC-HG-AFS | Sediments | [103] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100 | 20 mM EDTA, 8 mM KHP 1 mM K2CO3 | HPLC-HG-AFS | Environmental samples | [104] | Sb3+, Sb5+ | Hamilton PRP-X100 | 250 mM diammonium tartrate, 20 mM KOH | HPLC-ICP-MS | Volcanic ash | [105] | Sb3+, Sb5+ | — | 1.5 M HAc, 0.5 M H2SO4 | FIA-HG-AAS | Biological samples | [106] | Sb3+, Sb5+, TMSbCl2 | CETAC ION-120 Dionex AS 14 | 2 mM NH4HCO3, 1 mM tartaric acid, 1.25 mM EDTA | HPLC-ICP-MS | Tap water | [75, 76] | Sb3+, Sb5+ | — | 5.0*10−5 M BPHA, Triton X-114 (0.20% (v=v)) | SPE-FAAS | Water | [107] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100 | 20 mM EDTA, 2 mM KHP, 50 mM (NH4)2HPO4 | HPLC-HG-AFS | Sea water | [97] | Sb3+, Total Sb | — | — | HS-SDME-ETAAS | Lake water, soils | [108] | Sb3+, Sb5+, TMSbCl2 | Hamilton PRP-X100, Dionex AS4A-SC | 12 mM tetra-methylammonium hydroxide 3 mM tetra-methylammonium hydroxide | HPLC-ICP-MS | Environmental samples | [109] | Sb3+, Sb5+ | Dionex AS 14, AG 14 | 2 mM ammonium hydrogen carbonate, 2.2 mM tartaric acid, 2 mM ammonium hydrogen carbonate, 45 mM tartaric acid, | HPLC-ICP-MS | Synthetic samples | [110] | Sb3+, Sb5+ | Hamilton PRP-X100 | 250 mM diammonium tartrate, 20 mM KOH | HPLC-HG-AFS, HPLC-ICP-MS | Coal fly ash | [111] | Sb3+, Sb5+ | Synchropak Q300 | 5 mM EDTA, 2 mM phthalic acid | HPLC-ICP-MS | Tap water | [81, 82] | Sb3+, Sb5+ | Hamilton PRP-X100 | 20 mM EDTA, 2 mM phthalic acid | HPLC-ICP-MS, HPLC-ESI-MS | Yoghurt, juice, urine | [112] | Sb3+, Sb5+ TMSbCl2 | Phenomenex SAX-SB | 100 mM ammonium tartrate | HPLC-ICP-MS | Synthetic solutions | [113] | Sb3+, Sb5+, TMSbCl2 | ION-120, Supelcosil SAX Hamilton PRP-X100, Dionex AS 14, Dionex AS 9 | NH4HCO3, EDTA, Tartaric acid | HPLC-HG-AAS | Environmental samples | [114] | Sb3+, Sb5+ | Supelcosil LC-SAX 1 | 50 mM ammonium tetrate | HPLC-HG-AAS | Water | [115] | Sb3+, Sb5+ | — | 3 g/L L-cysteine | HG-ICP-AES | Spiked water samples | [116] |
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