Research Article

A Simple Approach for Measuring Emission Patterns of Vapor Phase Mercury under Temperature-Controlled Conditions from Soil

Table 3

Summary of experiments using three soil samples with a total weight of 100 ga.
(a) Hg concentration exiting the chamber (ng m−3)

TempC(S1)bC(S2)C(S3-1)C(S3-2)C(S3-3)

25 17.101 3.684 7.502 NMNM
30 14.702 3.116 4.782 0.089 0.016
40 48.746 7.647 9.515 0.328 0.131
50 60.455 12.350 34.146 1.316 0.699
60 38.728 10.452 56.805 4.208 2.559
70 NM12.696 35.930 11.619 6.715

(b) Hg emission flux (ng m−2 h−1)

TempF(S1)F(S2)F(S3-1)F(S3-2)F(S3-3)

25 169.9 36.6 74.5 NMNM
30 146.1 31.0 47.5 0.9 0.2
40 484.4 76.0 94.6 3.3 1.3
50 600.7 122.7 339.3 13.1 6.9
60 384.8 103.9 564.5 41.8 25.4
70 126.2 357.0 115.5 66.7

(c) Relationship between 1 / 𝑇 versus ln(emission flux)

1 / 𝑇 (abs)ln(F(S1))ln(F(S2))ln(F(S3-1)) ln(F(S3-2))ln(F(S3-3))

0.0034 5.1354 3.6003 4.3114
0.0033 4.9842 3.4329 3.8612 −0.1230 −1.8362
0.0032 6.1829 4.3306 4.5492 1.1805 0.2617
0.0031 6.3981 4.8099 5.8269 2.5705 1.9384
0.0030 5.9528 4.6431 6.3359 3.7333 3.2360
0.0029  4.8376 5.8778 4.7488 4.2005

aThree soil samples are named S1, S2, and S3, and the number of repetition is given after the hyphen.
b Initiation dates for each experiment: S1 (22 December 2009), S2 (30 December 2009), S3-1 (26 January 2010), S3-2 (2 February 2010), and S3-3 (11 February 2010).