Research Article
Simulation for Supporting Scale-Up of a Fluidized Bed Reactor for Advanced Water Oxidation
Table 2
Reactions and rate constants for complete mineralization of phenol by Fe3+/Fe2+/H2O2.
| | No. | Reaction | Rate constant | Reference |
| | R1 | | 1 × 10−2 M−1s−1 | [20, 35] | | R2 | | 3.3 × 105 M−1s−1 | [36] | | R3 | | 6.3 × 101 M−1s−1 | [35, 36] | | R4 | | 3.3 × 107 M−1s−1 | [36] | | R5 | | 8.3 × 105 s−1 | [37] | | R6 | | 4.2 × 109 s−1 | [35] | | R7 | | 3.3 × 109 M−1s−1 | [35] | | R8 | | 7.0 × 103 M−1s−1 | [35] | | R9 | | 7.0 × 103 M−1s−1 | [35] | | R10 | | 2.0 × 1010 M−1s−1 | [35] | | R11 | | 1.1 × 1010 M−1s−1 | [20] | | R12 | | 7.0 × 103 M−1s−1 | [35] | | R13 | + fumaric acid | 1.0 × 101 M−1s−1 | [35] | | R14 | Fumaric acid + oxalic acid + CO2 | 6.0 × 109 M−1s−1 | [20] | | R15 | Oxalic acid + CO2 | 1.4 × 106 M−1s−1 | [20] | | R16 | Phenol + aromatics | 0.3805 M−1s−1 | [38] | | R17 | Phenol + muconic acid | 1.933 × 10−2 M−1s−1 | [38] | | R18 | Phenol + fumaric acid | 1.5 × 10−2 M−1s−1 | [39] | | R19 | H2O2 | 0.0012 s−1 | From this study | | R20 | TOC1 + TOC2 + H2O | 6.35 × 10−5 M−1s−1 | From this study | | R21 | TOC2 + final product | 9.6 × 10−7 M−1s−1 | From this study |
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DHCD: di-hydroxy-cyclohexa-di-enyl radical; THB: tri-hydroxy-benzene; THCD: di-hydroxy-cyclohexa-di-enyl radical.
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