Research Article
Kinetics and Mechanism of Nanoparticles-Catalyzed Piperidinolysis of Anionic Phenyl Salicylate
Table 1
The values of , calculated from (1) for the piperidinolysis of under the variety of experimental conditionsa.
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3H
0 = 0.2 mM, = 370 nm, 35°C, 30 mM NaOH, 100 mM Pip, and 15 mM CTABr. = and , = 1, 2. cNaOH/XH. dNaOH/XH = 2.50. eCalculated from (1) by the use of observed data ( versus reaction time ) obtained for the kinetic runs at 0.2 mM 3H, 10 mM NaOH, 100 mM Pip, 370 nm, and 35°C and within CH3CN content range of 2–92%v/v in mixed aqueous solvents. fError limits are standard deviations. |