International Journal of Inorganic Chemistry

Research Article

Na3MP3O10·12H2O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Table 1

Crystal data and details of collection and structure refinement for Na3MP3O10·12H2O M = Co (1) and Ni (2).
Structural data(1)(2)
Empirical formulaNa3CoP3O10·12H2ONa3NiP3O10·12H2O
Formula weight (g/mol)597596.8
Temperature (K)120120
Wavelength Mo (Å)1.541841.54184
Crystal system, space groupMonoclinic, P21/n Monoclinic, P21/n
Unit cell dimensions  
 a (Å), α (°)15.0263(3), 9014,9906(4), 90
 b (Å), β (°)9.1972(2), 90.0492(16)9,1628(2), 90.098(2)
 c (Å), γ (°)14.6654(3), 90
14,6660(4), 90
Volume (Å3), Z 2026.76(7), 42014.46(9), 4
(Mg/m3)1.95591.967
Absorption coefficient (mm−1)10.4995.267
F(000)12201224
Crystal size (mm)0.3416 * 0.1882 * 0.1274
0.5021 * 0.0801 * 0.0527
Crystal shape, colourPrism, pinkNeedle, colorless
Limiting indices
Reflections collected35343181
Independent reflections34563107
DiffractometerOxford Diffraction Ltd.Oxford Diffraction Ltd.
Data/restraints/parameters3534/24/3363181/24/336
Goodness-of-fit on 1.612.11
Final R indices = 0.0261, = 0.0735 = 0.0277, = 0.0904
R indices (all data) = 0.0267, = 0.0738 = 0.0284, = 0.0907