| (a) |
| | Co(1)O6 in Na3CoP3O10·12H2O | | Co1 | O2 | O6 | O9 | O11 | O12 | O19 |
| | O2 | 2,061(2) | 90,35(8) | 94,87(8) | 91,45(8) | 171,96(8) | 91,01(8) | | O6 | 90,35(8) | 2,141(2) | 90,43(8) | 177,32(8) | 85,90(8) | 85,98(8) | | O9 | 94,87(8) | 90,43(8) | 2,060(2) | 91,40(8) | 92,27(8) | 173,13(8) | | O11 | 91,45(8) | 177,32(8) | 91,40(8) | 2,116(2) | 92,07(8) | 91,99(8) | | O12 | 171,96(8) | 85,90(8) | 92,27(8) | 92,07(8) | 2,098(2) | 81,64(8) | | O19 | 91,01(8) | 85,98(8) | 173,13(8) | 91,99(8) | 81,64(8) | 2,142(2) |
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〈d(Co–O)〉 = 2,103(2)Å, ∠(O; Co; O)> range from 81,64(8) to 177,32(8)°.
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| (b) |
| | P3O10 in Na3CoP3O10·12H2O | | P1 | O1 | O2 | O3 | O4 |
| | O1 | 1,505(2) | 112,1(1) | 114,5(1) | 107,0(1) | | O2 | 112,1(1) | 1,523(2) | 111,7(1) | 107,7(1) | | O3 | 114,5(1) | 111,7(1) | 1,510(2) | 103,0(1) | | O4 | 107,0(1) | 107,7(1) | 103,0(1) | 1,619(2) |
| | P2 | O4 | O5 | O6 | O7 |
| | O4 | 1,594(2) | 109,1(1) | 109,1(1) | 100,9(1) | | O5 | 109,1(1) | 1,479(2) | 120,0(1) | 105,5(1) | | O6 | 109,1(1) | 120,0(1) | 1,495(2) | 110,5(1) | | O7 | 100,9(1) | 105,5(1) | 110,5(1) | 1,594(2) |
| | P3 | O7 | O8 | O9 | O10 |
| | O7 | 1,624(2) | 106,5(1) | 107,8(1) | 102,3(1) | | O8 | 106,5(1) | 1,506(2) | 112,2(1) | 113,4(1) | | O9 | 107,8(1) | 112,2(1) | 1,519(2) | 113,8(1) | | O10 | 102,3(1) | 113,4(1) | 113,8(1) | 1,521(2) |
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∠(P1; O4; P2) = 158,3(2)°, 〈d(P–OINT)〉 = 1.603 Å, 〈d(P–OTER)〉 = 1.500 Å, 〈d(P–OALL)〉 = 1,553 Å.
∠(P2; O7; P3) = 70.9(2)°, 〈d(P–OINT)〉 = 1.609 Å, 〈d(P–OTER)〉 = 1.5507 Å, 〈d(P–OALL)〉 = 1.5798 Å.
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| (c) |
| | Ni(1)O6 in Na3NiP3O10·12H2O | | Ni1 | O2 | O6 | O9 | O11 | O12 | O19 |
| | O2 | 2,046(2) | 90,91(9) | 93,51(9) | 90,12(9) | 173,7(1) | 91,51(9) | | O6 | 90,91(9) | 2,081(2) | 91,32(9) | 178,45(9) | 86,63(9) | 86,27(9) | | O9 | 93,51(9) | 91,32(9) | 2,052(2) | 89,76(9) | 92,41(1) | 174,5(1) | | O11 | 90,12(9) | 178,45(9) | 89,76(9) | 2,067(2) | 92,22(9) | 92,55(9) | | O12 | 173,7(1) | 86,63(9) | 92,41(1) | 92,22(9) | 2,065(3) | 82,5(1) | | O19 | 91,51(9) | 86,27(9) | 174,5(1) | 92,55(9) | 82,5(1) | 2,097(3) |
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〈d(Ni–O)〉 = 2,0615(2) Å, ∠(O; Ni; O)> range from 82,5(1)°–178,45(9)°
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| (d) |
| | P3O10 in Na3NiP3O10·12H2O | | P1 | O1 | O2 | O3 | O4 |
| | O1 | 1,501(3) | 112,5(1) | 114,3(1) | 106,91(1) | | O2 | 112,5(1) | 1,524(2) | 111,7(1) | 107,7(1) | | O3 | 114,3(1) | 111,7(1) | 1,513(2) | 103,0(1) | | O4 | 106,91(1) | 107,7(1) | 103,0(1) | 1,624(3) |
| | P2 | O4 | O5 | O6 | O7 |
| | O4 | 1,589(3) | 109,2(1) | 108,9(1) | 100,9(1) | | O5 | 109,2(1) | 1,480(2) | 119,5(1) | 106,0(1) | | O6 | 108,9(1) | 119,5(1) | 1,499(2) | 110,7(1) | | O7 | 100,9(1) | 106,0(1) | 110,7(1) | 1,592(3) |
| | P3 | O7 | O8 | O9 | O10 |
| | O7 | 1,627(2) | 106,0(1) | 107,7(1) | 102,4(1) | | O8 | 106,0(1) | 1,508(2) | 112,1(1) | 113,2(1) | | O9 | 107,7(1) | 112,1(1) | 1,520(2) | 114,4(1) | | O10 | 102,4(1) | 113,2(1) | 114,4(1) | 1,516(2) |
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∠(P1; O4; P2) = 157.2(2)°, 〈d(P–OINT)〉 = 1.606 Å, 〈d(P–OTER)〉 = 1.5051 Å, 〈d(P–OALL)〉 = 1,553 Å.
∠(P2; O7; P3) = 71.3(2)°, 〈d(P–OINT)〉 =1,6095 7 Å, 〈d(P–OTER)〉 = 1.551 Å, 〈d(P–OALL)〉 = 1.5802 Å.
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