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Advances in Chemistry
Volume 2014, Article ID 182327, 8 pages
http://dx.doi.org/10.1155/2014/182327
Review Article

Increasing the Stability of Metal-Organic Frameworks

1Department of Chemistry, Texas A&M University, College Station, TX 77842, USA
2Department of Materials Science and Engineering, Texas A&M University, College Station, TX 77842, USA

Received 10 March 2014; Revised 13 June 2014; Accepted 16 June 2014; Published 18 September 2014

Academic Editor: Qiaohui Fan

Copyright © 2014 Mathieu Bosch et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. H.-C. Zhou, J. R. Long, and O. M. Yaghi, “Introduction to metal-organic frameworks,” Chemical Reviews, vol. 112, no. 2, pp. 673–674, 2012. View at Publisher · View at Google Scholar · View at Scopus
  2. H. Li, M. Eddaoudi, M. O'Keeffe, and O. M. Yaghi, “Design and synthesis of an exceptionally stable and highly porous metal- organic framework,” Nature, vol. 402, no. 6759, pp. 276–279, 1999. View at Publisher · View at Google Scholar · View at Scopus
  3. J. H. Cavka, S. Jakobsen, U. Olsbye et al., “A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability,” Journal of the American Chemical Society, vol. 130, no. 42, pp. 13850–13851, 2008. View at Publisher · View at Google Scholar · View at Scopus
  4. G. Ferey, C. Mellot-Draznieks, C. Serre et al., “A chromium terephthalate-based solid with unusually large pore volumes and surface area,” Science, vol. 309, no. 5743, pp. 2040–2042, 2005. View at Publisher · View at Google Scholar
  5. S. S.-Y. Chui, S. M.-F. Lo, J. P. H. Charmant, A. G. Orpen, and I. D. Williams, “A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n,” Science, vol. 283, no. 5405, pp. 1148–1150, 1999. View at Publisher · View at Google Scholar · View at Scopus
  6. S. Ma, J. M. Simmons, D. Sun, D. Yuan, and H. Zhou, “Porous metal-organic frameworks based on an anthracene derivative: syntheses, structure analysis, and hydrogen sorption studies,” Inorganic Chemistry, vol. 48, no. 12, pp. 5263–5268, 2009. View at Publisher · View at Google Scholar · View at Scopus
  7. H. Li, M. Eddaoudi, T. L. Groy, and O. M. Yaghi, “Establishing microporosity in open metal-organic frameworks: gas sorption isotherms for Zn(BDC) (BDC = 1,4-benzenedicarboxylate),” Journal of the American Chemical Society, vol. 120, no. 33, pp. 8571–8572, 1998. View at Publisher · View at Google Scholar · View at Scopus
  8. H. Li, W. Shi, K. Zhao, H. Li, Y. Bing, and P. Cheng, “Enhanced hydrostability in Ni-doped MOF-5,” Inorganic Chemistry, vol. 51, no. 17, pp. 9200–9207, 2012. View at Publisher · View at Google Scholar · View at Scopus
  9. J. T. Hupp and K. R. Poeppelmeler, “Chemistry: better living through nanopore chemistry,” Science, vol. 309, no. 5743, pp. 2008–2009, 2005. View at Publisher · View at Google Scholar · View at Scopus
  10. T. Tsuruoka, S. Furukawa, Y. Takashima, K. Yoshida, S. Isoda, and S. Kitagawa, “Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth,” Angewandte Chemie, vol. 48, no. 26, pp. 4739–4743, 2009. View at Publisher · View at Google Scholar · View at Scopus
  11. N. L. Rosi, M. Eddaoudi, J. Kim, M. O'Keeffe, and O. M. Yaghi, “Infinite secondary building units and forbidden catenation in metal-organic frameworks,” Angewandte Chemie International Edition, vol. 41, no. 2, pp. 284–287, 2002. View at Google Scholar
  12. D. Mustafa, E. Breynaert, S. R. Bajpe, J. A. Martens, and C. E. A. Kirschhock, “Stability improvement of Cu3(BTC)2 metal-organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate,” Chemical Communications, vol. 47, no. 28, pp. 8037–8039, 2011. View at Publisher · View at Google Scholar · View at Scopus
  13. K. Tan, N. Nijem, P. Canepa et al., “Stability and hydrolyzation of metal organic frameworks with paddle-wheel SBUs upon hydration,” Chemistry of Materials, vol. 24, no. 16, pp. 3153–3167, 2012. View at Google Scholar
  14. P. Küsgens, M. Rose, I. Senkovska et al., “Characterization of metal-organic frameworks by water adsorption,” Microporous and Mesoporous Materials, vol. 120, no. 3, pp. 325–330, 2009. View at Publisher · View at Google Scholar · View at Scopus
  15. D. Q. Yuan, D. Zhao, D. Sun, and H. Zhou, “An isoreticular series of metal-organic frameworks with dendritic hexacarboxylate ligands and exceptionally high gas-uptake capacity,” Angewandte Chemie, vol. 49, no. 31, pp. 5357–5361, 2010. View at Publisher · View at Google Scholar · View at Scopus
  16. D. Zhao, D. Yuan, D. Sun, and H.-C. Zhou, “Stabilization of metal-organic frameworks with high surface areas by the incorporation of mesocavities with microwindows,” Journal of the American Chemical Society, vol. 131, no. 26, pp. 9186–9188, 2009. View at Publisher · View at Google Scholar · View at Scopus
  17. M. Li, D. Li, M. O'Keeffe, and O. M. Yaghi, “Topological analysis of metal–organic frameworks with polytopic linkers and/or multiple building units and the minimal transitivity principle,” Chemical Reviews, vol. 114, no. 2, pp. 1343–1370, 2013. View at Publisher · View at Google Scholar
  18. M. Zhang, Y.-P. Chen, and H.-C. Zhou, “Structural design of porous coordination networks from tetrahedral building units,” CrystEngComm, vol. 15, no. 45, pp. 9544–9552, 2013. View at Google Scholar
  19. Z. Wei, W. Lu, H. Jiang, and H. Zhou, “A route to metal-organic frameworks through framework templating,” Inorganic Chemistry, vol. 52, no. 3, pp. 1164–1166, 2013. View at Publisher · View at Google Scholar · View at Scopus
  20. M. V. Veidis, G. H. Schreiber, T. E. Gough, and G. J. Palenik, “Jahn-Teller distortions in octahedral copper(II) complexes,” Journal of the American Chemical Society, vol. 91, no. 7, pp. 1859–1860, 1969. View at Publisher · View at Google Scholar · View at Scopus
  21. M. K. Bhunia, J. T. Hughes, J. C. Fettinger, and A. Navrotsky, “Thermochemistry of paddle wheel MOFs: Cu-HKUST-1 and Zn-HKUST-1,” Langmuir, vol. 29, no. 25, pp. 8140–8145, 2013. View at Publisher · View at Google Scholar · View at Scopus
  22. Y. Kim, S. Das, S. Bhattacharya et al., “Metal-ion metathesis in metal-organic frameworks: a synthetic route to new metal-organic frameworks,” Chemistry, vol. 18, no. 52, pp. 16642–16648, 2012. View at Publisher · View at Google Scholar · View at Scopus
  23. H. Chevreau, T. Devic, F. Salles, G. Maurin, N. Stock, and C. Serre, “Mixed-linker hybrid superpolyhedra for the production of a series of large-pore iron(III) carboxylate metal-organic frameworks,” Angewandte Chemie, vol. 52, no. 19, pp. 5056–5060, 2013. View at Publisher · View at Google Scholar · View at Scopus
  24. M. Zhang, Y.-P. Chen, M. Bosch et al., “Symmetry-guided synthesis of highly porous metal-organic frameworks with fluorite topology,” Angewandte Chemie International Edition, vol. 53, no. 3, pp. 815–818, 2014. View at Publisher · View at Google Scholar
  25. L. Valenzano, B. Civalleri, S. Chavan et al., “Disclosing the complex structure of UiO-66 metal organic framework: a synergic combination of experiment and theory,” Chemistry of Materials, vol. 23, no. 7, pp. 1700–1718, 2011. View at Publisher · View at Google Scholar · View at Scopus
  26. J. B. Decoste, G. W. Peterson, H. Jasuja, T. G. Glover, Y. Huang, and K. S. Walton, “Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit,” Journal of Materials Chemistry A, vol. 1, no. 18, pp. 5642–5650, 2013. View at Publisher · View at Google Scholar · View at Scopus
  27. V. Guillerm, F. Ragon, M. Dan-Hardi et al., “A series of isoreticular, highly stable, porous zirconium oxide based metal-organic frameworks,” Angewandte Chemie, vol. 51, no. 37, pp. 9267–9271, 2012. View at Publisher · View at Google Scholar · View at Scopus
  28. A. Schaate, P. Roy, A. Godt et al., “Modulated synthesis of Zr-based metal-organic frameworks: from nano to single crystals,” Chemistry A, vol. 17, no. 24, pp. 6643–6651, 2011. View at Publisher · View at Google Scholar · View at Scopus
  29. A. Schaate, P. Roy, T. Preuße, S. J. Lohmeier, A. Godt, and P. Behrens, “Porous interpenetrated zirconium-organic frameworks (PIZOFs): a chemically versatile family of metal-organic frameworks,” Chemistry, vol. 17, no. 34, pp. 9320–9325, 2011. View at Publisher · View at Google Scholar · View at Scopus
  30. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann, “OLEX2: a complete structure solution, refinement and analysis program,” Journal of Applied Crystallography, vol. 42, no. 2, pp. 339–341, 2009. View at Publisher · View at Google Scholar · View at Scopus
  31. T. A. Makal, X. Wang, and H. C. Zhou, “Tuning the moisture and thermal stability of metal-organic frameworks through incorporation of pendant hydrophobic groups,” Crystal Growth & Design, vol. 13, no. 11, pp. 4760–4768, 2013. View at Google Scholar
  32. D. W. Feng, Z. Y. Gu, J. R. Li, H. L. Jiang, Z. W. Wei, and H. C. Zhou, “Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts,” Angewandte Chemie, vol. 51, no. 41, pp. 10307–10310, 2012. View at Publisher · View at Google Scholar · View at Scopus
  33. D. W. Feng, W. C. Chung, Z. W. Wei et al., “Construction of ultrastable porphyrin zr metal-organic frameworks through linker elimination,” Journal of the American Chemical Society, vol. 135, no. 45, pp. 17105–17110, 2013. View at Google Scholar
  34. H. L. Jiang, D. W. Feng, K. C. Wang et al., “An exceptionally stable, porphyrinic Zr metal-organic framework exhibiting pH-dependent fluorescence,” Journal of the American Chemical Society, vol. 135, no. 37, pp. 13934–13938, 2013. View at Google Scholar
  35. M. Yoon, R. Srirambalaji, and K. Kim, “Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis,” Chemical Reviews, vol. 112, no. 2, pp. 1196–1231, 2012. View at Publisher · View at Google Scholar · View at Scopus
  36. M. Zhang, M. Bosch, T. Gentle, and H.-C. Zhou, “Rational design of metal–organic frameworks with anticipated porosities and functionalities,” CrystEngComm, vol. 16, pp. 4069–4083, 2014. View at Publisher · View at Google Scholar
  37. M. Kandiah, M. H. Nilsen, S. Usseglio et al., “Synthesis and stability of tagged UiO-66 Zr-MOFs,” Chemistry of Materials, vol. 22, no. 24, pp. 6632–6640, 2010. View at Publisher · View at Google Scholar · View at Scopus
  38. V. Bon, V. Senkovskyy, I. Senkovska, and S. Kaskel, “Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology,” Chemical Communications, vol. 48, no. 67, pp. 8407–8409, 2012. View at Publisher · View at Google Scholar · View at Scopus
  39. M. Dinča, A. Dailly, Y. Liu, C. M. Brown, D. A. Neumann, and J. R. Long, “Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites,” Journal of the American Chemical Society, vol. 128, no. 51, pp. 16876–16883, 2006. View at Publisher · View at Google Scholar · View at Scopus
  40. R. Banerjee, A. Phan, B. Wang et al., “High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture,” Science, vol. 319, no. 5865, pp. 939–943, 2008. View at Publisher · View at Google Scholar · View at Scopus
  41. X.-C. Huang, Y.-Y. Lin, J.-P. Zhang, and X.-M. Chen, “Ligand-directed strategy for zeolite-type metal-organic frameworks: zinc(II) imidazolates with unusual zeolitic topologies,” Angewandte Chemie, vol. 45, no. 10, pp. 1557–1559, 2006. View at Publisher · View at Google Scholar · View at Scopus
  42. Y. Liu, V. C. Kravtsov, R. Larsen, and M. Eddaoudi, “Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities,” Chemical Communications, no. 14, pp. 1488–1490, 2006. View at Publisher · View at Google Scholar · View at Scopus
  43. J. An, O. K. Farha, J. T. Hupp, E. Pohl, J. I. Yeh, and N. L. Rosi, “Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework,” Nature Communications, vol. 3, article 604, 2012. View at Publisher · View at Google Scholar · View at Scopus
  44. J. An, S. J. Geib, and N. L. Rosi, “Cation-triggered drug release from a porous zinc-adeninate metal-organic framework,” Journal of the American Chemical Society, vol. 131, no. 24, pp. 8376–8377, 2009. View at Publisher · View at Google Scholar · View at Scopus
  45. M. Zhang, W. Lu, J.-R. Li et al., “Design and synthesis of nucleobase-incorporated metal-organic materials,” Inorganic Chemistry Frontiers, vol. 1, no. 2, pp. 159–162, 2014. View at Google Scholar
  46. V. Colombo, S. Galli, H. J. Choi et al., “High thermal and chemical stability in pyrazolate-bridged metal-organic frameworks with exposed metal sites,” Chemical Science, vol. 2, no. 7, pp. 1311–1319, 2011. View at Publisher · View at Google Scholar · View at Scopus
  47. Z. R. Herm, B. M. Wiers, J. A. Mason et al., “Separation of hexane isomers in a metal-organic framework with triangular channels,” Science, vol. 340, no. 6135, pp. 960–964, 2013. View at Publisher · View at Google Scholar · View at Scopus
  48. C. Yang, U. Kaipa, Q. Z. Mather et al., “Fluorous metal-organic frameworks with superior adsorption and hydrophobic properties toward oil spill cleanup and hydrocarbon storage,” Journal of the American Chemical Society, vol. 133, no. 45, pp. 18094–18097, 2011. View at Publisher · View at Google Scholar · View at Scopus
  49. P. Horcajada, F. Salles, S. Wuttke et al., “How linker's modification controls swelling properties of highly flexible iron(III) dicarboxylates MIL-88,” Journal of the American Chemical Society, vol. 133, no. 44, pp. 17839–17847, 2011. View at Publisher · View at Google Scholar · View at Scopus
  50. N. M. Padial, E. Quartapelle Procopio, C. Montoro et al., “Highly hydrophobic isoreticular porous metal-organic frameworks for the capture of harmful volatile organic compounds,” Angewandte Chemie, vol. 52, no. 32, pp. 8290–8294, 2013. View at Publisher · View at Google Scholar · View at Scopus
  51. J. P. Zhang, Y. B. Zhang, J. B. Lin, and X. M. Chen, “Metal azolate frameworks: from crystal engineering to functional materials,” Chemical Reviews, vol. 112, no. 2, pp. 1001–1033, 2012. View at Publisher · View at Google Scholar · View at Scopus
  52. Y. B. Zhang, J. Su, H. Furukawa et al., “Single-crystal structure of a covalent organic framework,” Journal of the American Chemical Society, vol. 135, no. 44, pp. 16336–16339, 2013. View at Publisher · View at Google Scholar
  53. X. Q. Kong, H. X. Deng, F. Y. Yan et al., “Mapping of functional groups in metal-organic frameworks,” Science, vol. 341, no. 6148, pp. 882–885, 2013. View at Publisher · View at Google Scholar · View at Scopus
  54. H. Wu, Y. S. Chua, V. Krungleviciute et al., “Unusual and highly tunable missing-linker defects in zirconium metal-organic framework UiO-66 and their important effects on gas adsorption,” Journal of the American Chemical Society, vol. 135, no. 28, pp. 10525–10532, 2013. View at Publisher · View at Google Scholar · View at Scopus
  55. F. Vermoortele, B. Bueken, G. Le Bars et al., “Synthesis modulation as a tool to increase the catalytic activity of metal-organic frameworks: The unique case of UiO-66(Zr),” Journal of the American Chemical Society, vol. 135, no. 31, pp. 11465–11468, 2013. View at Publisher · View at Google Scholar · View at Scopus
  56. P. Horcajada, R. Gref, T. Baati et al., “Metal-organic frameworks in biomedicine,” Chemical Reviews, vol. 112, no. 2, pp. 1232–1268, 2012. View at Publisher · View at Google Scholar · View at Scopus