Table of Contents
Advances in Chemistry
Volume 2014, Article ID 864286, 7 pages
http://dx.doi.org/10.1155/2014/864286
Research Article

Synthesis of Disperse Dyes from Pyridone and Resorcinol Coupled to Diazotized 2-Amino-4-chloro-5-formylthiazole and Application to Polyester

1Department of Textile Technology and Fashion Design, College of Science and Technology, Kaduna Polytechnic, PMB 2021, Kaduna, Nigeria
2Department of Textile Science and Technology, Ahmadu Bello University, Zaria, Nigeria
3Department of Applied Science, College of Science and Technology, Kaduna Polytechnic, PMB 2021, Kaduna, Nigeria

Received 17 April 2014; Revised 16 June 2014; Accepted 26 June 2014; Published 17 July 2014

Academic Editor: Claudio Cameselle

Copyright © 2014 Yusuf Y. Lams et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The aim of this study was to synthesize disperse dyes in the derivative of 2-amino-4-chloro-5-formylthiazole by conventional diazotization and couplings with pyridone and resorcinol. The dyes were characterized by visible absorption spectroscopy, IR spectral studies, and 1H and 13C NMR. The pyridone and resorcinol substituted dyes exhausted well with good depth on 100% polyester fabrics with a shade of brown and purple colours, respectively. The heteroatom and the intrinsic conjugation in the thiazole structure results in high bathochromic shifts and lead to brightness of shades. The dyed fabrics showed very good to excellent wash fastness and moderate to good light and perspiration fastness properties.