Research Article
Synthesis, Crystal Structure, and Antimicrobial Properties of [Diaquabis(hexamethylenetetramine)diisothiocyanato-κN]nickel(II) Complex
Table 3
Comparison of bond parameters for similar structures [M(hmt)2(H2O)2(NCS)2] (M = Cu, Co, Mn, and Ni).
| M-N (HMTA) | Bond length (Å) | M-N (NCS−) | Bond length (Å) | M-O (H2O) | Bond length (Å) | Ref. |
| Cu-N | 2.09(5) 2.10(5) | Cu-N | 1.98(6) 2.08(6) 1.98(7) | None | — | [34] | Mn-N | 2.4213(13) | Mn-N | 2.1342(15) | Mn-O | 2.1865(12) | [35] | Co-N | 2.341(5) | Co-N | 2.058(5) | Co-O | 2.104(5) | [36] | Co-N | 2.3274(16) | Co-N | 2.0411(19) | Co-O | 2.1025(16) | [37] | Ni-N | 2.238(2) | Ni-N | 2.031(2) | Ni-O | 2.058(2) | This work |
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