Research Article

Synthesis, Crystal Structure, and Antimicrobial Properties of [Diaquabis(hexamethylenetetramine)diisothiocyanato-κN]nickel(II)  Complex

Table 3

Comparison of bond parameters for similar structures [M(hmt)2(H2O)2(NCS)2] (M = Cu, Co, Mn, and Ni).

M-N (HMTA)Bond length (Å)M-N (NCS)Bond length (Å)M-O (H2O)Bond length (Å)Ref.

Cu-N2.09(5)
2.10(5)
Cu-N1.98(6)
2.08(6)
1.98(7)
None[34]
Mn-N2.4213(13)Mn-N2.1342(15)Mn-O2.1865(12)[35]
Co-N2.341(5)Co-N2.058(5)Co-O2.104(5)[36]
Co-N2.3274(16)Co-N2.0411(19)Co-O2.1025(16)[37]
Ni-N2.238(2)Ni-N2.031(2)Ni-O2.058(2)This work