|
| Author/year | Composition | Connectivity | Fabrication method | Test condition (DC bias/freq.) | ME (mV/cmOe) | Remark |
|
|
Van Suchtelen, Van den Boomgaard1972,1974 [25, 28, 30, 31] | 0.62BaTiO3-.0.38CoFe2O4 (eutectic composition with 1.5 wt% excess TiO2) | 3-3/Unidirection solidification | Bridgman/1 atm O2/50 cm h−1 | ? | 50 | The 1st ME composite |
| Van den Boomgaard and Born1978 [29] | 0.60BaTiO3-.0.40Ni0.97Co0.03Mn0.1Fe1.90O4 | 3-0/Particulate | Sintered at 1,300°C/24 h | 500 Oe/1 kHz | 80 | The 1 st ME particulate composite |
| Suryanarayana, 1994 [49] | 0.3CuFe2O4-.0.7PbZr0.53Ti0.47O3 | 3-0/Particulate | Sintered at 950°C/2 h | 460 Oe/100 kHz | 421 | The 1st resonance type ME composite |
| Bichurin and Petrov 1994 [50] | 90% of yttrium-iron garnet and 10% PZT ceramics | 3-0/Particulate | Standard ceramic method | — | — | The 1st time interaction between ME phases is discussed by striction model. |
| Bichurin et al. 1997 [51] | (Ni-Co)-ferrite/PZT ceramics and YIG/BaTiO3 | 3-0/Particulate | Standard ceramic method | 0.8–0.9 kOe at RT | 110 | The 1st theoretical approach on the magnetoelectric effect |
| Srinivasan et al. 2004 [52] | Ni0.8Zn0.2Fe2O4-0.41 vol% PZT | 3-0/Particulate | Hot pressed at 1,000°C/7 Mpa | 250 Oe/100 Hz | 45 | The 1st hot pressing method |
| Srinivasan et al. 2004 [52] | Ni0.8Zn0.2Fe2O4-0.75 vol% PZT | 3-0/Particulate | Hot pressed at 1,000°C/7 Mpa | >1,000 Oe/270 kHz | 3300 | ME property optimization by resonance |
| Muzumder and Bhattacharyya 2004 [53] | BaO–TiO2–CoO–FeO solution | 3-0/Particulate | Sintered in @ 1,000–1,200°C/3 h | 30 Oe/1,070 Hz | 5.58 | Homogeneous dispersion |
| Fuentes et al. 2006 [54] | Bi8Fe4Ti3O4 | Single phase | Sintering | 4,500 (f=?) | 0.35 | Highest ME properties from single phase material |
| Ryu et al. 2001, 2002 [27, 55] | PZT -20 wt%NiCo0.02Cu0.02Mn0.1Fe1.8O4 | 3-0/Particulate | Sintered at 1,250°C | 1,250 Oe/1 kHz | 115 | ME effect optimization from particulates composites |
| Kambale et al. 2009, 2010 [56, 57] | BaZr0.08Ti0.92O3/NiFe1.9Mn0.1O4 and BaZr0.08Ti0.92O3/Co1.2-yMnyFe1.8O4 | 3-0/Particulate | Solid-state reaction sintered at 1250°C for 10 h with heating rate 5°C/min | 4 kOe/50 Hz | 2.34 | Low ME response in bulk composites |
| B.K.Chougule and S.S. Chougule, 2008 [58] | Ni0.8Zn0.2Fe2O4 + PZT | 3-0/Particulate | Solid-state reaction | 6 kOe, 2.5 kV/cm | 0.78 | Low ME response in bulk composites |
| Mathe and Sheikh 2009 [59] | NiFe2O4 + PMN-PT | 3-0/Particulate | Solid-state reaction sintered at 1250°C | Static ME measurement | 10.43 | Effect of different connectivity schemes on ME coefficient |
| Patankar etal. 2000 [60] | 0.45CuFe1.6Cr0.4O4-0.55BaTiO3 | 3-0/Particulate | Sintered at 1,100°C/ 24 h | 1,570 Oe/DC | 0.0956 | Low-temperature sintering |
| Priya and Islam 2006 [61] | NiFe1.9Mn0.1O4-Pb(Zr0.52Ti0.48)O3 | 3-0/Particulate | Controlled precipitation route | 1 kOe and 100 Oe | 140 | Annealing and aging effect were studied |
| Ryu et al. 2001, 2002 [55, 62] | Terfenol-D/Pb(Mg1/3Nb2/3)O3-PbTiO3/Terfenol-D (PZT based ceramics materials) | 2-2/Laminate | Epoxy-glued composites | 4,000 Oe/1 kHz | 5.150 (peak) | The 1st laminate ME composite with GMS metals |
| Bichurin et al., 2003 [63] | NiFe2O4-PZT | 2-2/Multilayer | 11 layers of 13 μm NiFe2O4 1 and 10 layers of 26 μm PZT | 1,050 Oe/350 kHz@ resonance | 1.200 | The 1st ME multilayer composites |
|
Zheng et al., 2004 [34] | 0.65BaTiO3-0.35CoFe2O4 (converse ME) | 1-3/Vertically aligned structure. | PLD; single-crystal SrTiO3 (001) substrates | — | — | The 1st ME 1-3 type ME composites |
| Dong et al., 2004 [64] | Terfenol-D/PMN-PT | 2-2/Laminate | L-L laminates | 550 < < 800 Oe. f = 1 kHz | 430 | L-L laminates with high ME coefficient |
| Wan et al., 2005 [74] | CoFe2O4-PZT | 0-3/Nanostructure | Sol-gel process and spin-coating technique | 1 kHz/6 kOe (10 Oe ac) | 220 | Successful preparation of ME composite thin films |
|
Dong et al., 2006 [81] | FeBSiC/piezofiber laminates (Metglas/PZT) | 2-1/Laminate | Epoxy-glued composites | L-L mode @ 5 Oe dc bias and f = 1 Hz | 22000 | Highest reported ME coefficient |
| Zhai et al., 2006 [65] | Metglas/PVDF | Layered laminate | Epoxy-glued composites | = 1 Oe and f = 1 kHz | 7200 and 238 V/cmOe @ resonance 50 kHz | Thin and flexible ME composites |
| Dong et al., 2007 [66] | FeBSiC/PZNPT-fiber laminate | Layered laminate | Epoxy-glued composites | = 1 Oe. | 10500@ low frequency with low dc bias 2 Oe | Long-type FeBSiC/ PZNPT-fiber laminates |
|
Park et al., 2010 [67] | Metglas/Terfenol-D/ PMN-PZT/Terfenol-D/Metglas | Five layer laminates | Epoxy-glued composites | L-T mode
= 1 Oe
f = 1 kHz | 1800 | Successfully investigated the ME effect in five layered laminates |
| Gao et al., 2010 [68] | Metgla + PMN-PT and PZN-PT single crystals | Laminated composites | Epoxy-glued composites | = 1 Oe
f = 1 kHz | 8500 | 2.8 times enhanced ME coefficient is observed |
|
Chashin et al., 2011 [69] | Metglas/PMN-PT | Laminate composites | Epoxy-glued composites | = 1 Oe
f = 1 kHz | 45000 | Highest reported ME coefficient |
|
Chen et al., 2008 [70] | Ni/PZT/Ni | 2-2/Laminate | Electrodeposition | 150 kHz/1.2 kOe | 530 | Magnetoelectric disk resonators |
| Park et al., 2009 [75] | PZT-PZN and (Ni0.6Cu0.2Zn0.2)Fe2O4 [NCZF] | 3-2/Nanocomposite thick films | Aerosol-deposition | = 1 Oe
f = 1 kHz | 150 | First 3-2 ME composite structure by AD |
|
Xu et al., 2010 [71] | CoFe2O4/Pb(Zr0.53Ti0.47)O3 | 3-0 Nanocomposite thick films | Sol-gel-processing and spin-coating technique | 10 kOe/50 Hz | 0.4 | Low magnetoelectric response |
|
Ryu et al., 2011 [72] | CoFe2O4/Pb(Zr0.53Ti0.47)O3 | 2-2 Nanocomposite thin films | Sol-gel process and spin-coating technique | 50 kHz/dynamic | 273 | Optimal annealing processes for ME composite thin films have been achieved. |
|
Wan et al., 2011 [74] | PZT-PMnN + NiZnFe2O4 | 3-0 Nanocomposite thick films | Aerosol deposition | = 1 Oe
f = 1 kHz | 68 | First 3-0 type ME composite structure by AD |
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