Research Article | Open Access
R. Pässler, "Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe", Advances in Condensed Matter Physics, vol. 2017, Article ID 9321439, 37 pages, 2017. https://doi.org/10.1155/2017/9321439
Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe
Detailed analytical and numerical analyses are performed for combinations of several complementary sets of measured heat capacities, for ZnSe and ZnTe, from the liquid-helium region up to 600 K. The isochoric (harmonic) parts of heat capacities, , are described within the frame of a properly devised four-oscillator hybrid model. Additional anharmonicity-related terms are included for comprehensive numerical fittings of the isobaric heat capacities, . The contributions of Debye and non-Debye type due to the low-energy acoustical phonon sections are represented here for the first time by unprecedented, integral-free formulas. Indications for weak electronic contributions to the cryogenic heat capacities are found for both materials. A novel analytical framework has been constructed for high-accuracy evaluations of Debye function integrals via a couple of integral-free formulas, consisting of Debye’s conventional low-temperature series expansion in combination with an unprecedented high-temperature series representation for reciprocal values of the Debye function. The zero-temperature limits of Debye temperatures have been detected from published low-temperature data sets to be significantly lower than previously estimated, namely, 270 (±3) K for ZnSe and 220 (±2) K for ZnTe. The high-temperature limits of the “true” (harmonic lattice) Debye temperatures are found to be 317 K for ZnSe and 262 K for ZnTe.
Since the invocation of the concept of apparently characteristic, material-specific temperature parameters, , within Debye’s classical paper  on specific heats of solids, one was concerned with a large variety of quotations of corresponding values (so-called “Debye temperatures”) within numerous thermophysical research papers, including various representative review articles [2–5] and books [6–10]. A brief inspection of the enormous data material published hitherto, however, showed readily that it is obviously not possible to find unique values for the individual materials in question, which should apply to duly broad temperature regions. In order to save, nevertheless, the apparently rather popular concept of Debye temperatures, it became thus already long ago a widely accepted custom to adopt the physically somewhat problematic notion of variable (-dependent) Debye temperatures, . Accordingly, Debye’s heat capacity model function  used to be employed in practice in the general form [3, 4, 6, 10–15]where the upper limits of integration are given by the ratios, , of adjustable Debye temperatures versus the respective lattice temperatures and represents the familiar Dulong-Petit limiting value for the isochoric lattice heat capacity in harmonic approximation (i.e., in particular , for binary materials).
In the course of numerical fittings of measured (isobaric) heat capacities, , on the basis of (1), it has continually been found that, in contrast with Debye’s original suggestion , proper simulations of such heat capacity curves can in fact be realized only by admitting rather strong -dependencies of the material-specific Debye temperatures, . This statement applies above all to the liquid-helium-hydrogen region, where the adjusted values are as a rule rapidly falling [3–5, 12–17] from their limiting levels, , to certain minimum values, , which used to be located in the vicinities of . Furthermore, towards higher temperatures, many curves show a more or less pronounced increase up to certain material-specific maxima, , the actual magnitudes of which are in many cases significantly higher than the respective levels. Such typical nonmonotonic behaviours of curves in the cryogenic region have been found in particular for Si and Ge [18–21] as well as for a large variety of III–V [11, 12, 15, 22–30], II–VI [14, 31–38], and I–VII [16, 39, 40] materials.
Globally one can thus assess that Debye’s original idea, according to which heat capacities of solids might be represented by Debye function integrals (of type (1)), whose upper limits of integration should be based on fixed, material-specific values, is largely illusionary. Actually, not a single binary or ternary material could be found hitherto, within a wealth of thermophysical researches, for which it would have been possible to simulate in adequate way the temperature dependence of measured heat capacities, from the liquid-helium region up to the vicinity of room temperature, in terms of a unique value. This means, among other things, that there is hardly a chance to come to appropriate quantitative descriptions of the temperature dependencies of heat capacities mainly via constructions of various, highly elaborate analytical models [41–44] for integrals of Debye’s type and imputing, at the same time, only some fixed (-independent) values for Debye temperatures (like = 632 K for GaN  or = 920 K for ZnO  and = 946 K for MgO ).
The basic cause of the occurrence of relatively deep minima, , in the cryogenic region had been indicated already many years ago by Schrödinger  to be obviously due to the onset of thermal activation of short-wavelength transverse acoustical (TA) phonons, which are quantum-theoretically manifested by pronounced peaks (singularities) in the respective material-specific phonon density of states (PDOS) spectra (see, e.g., the calculated spectra shown in [45, 46] for ZnSe and ZnTe). Such drastic deviations of physically realistic PDOS spectra from Debye’s naïve (quadratic) PDOS model function , , are continually confirmed to be indeed the main cause of the obviously typical, nonmonotonic (non-Debye) behaviours of curves.
Of course, when a representative set of properly determined values is actually available for one or the other material in question, one can readily calculate the respective heat capacities, either via direct numerical evaluations of the integral occurring in (1) or by interpolations between discrete values quoted in some of the more or less comprehensive or tables presented by various authors [6, 8, 47–49] (see also the list of presently obtained high-accuracy sample values given in Table 7).
Considerably more problematic and difficult, however, is a proper computational solution of the hitherto largely ignored inverse problem, namely, the reliable determination of effective Debye temperatures, , on the basis of measured heat capacities, . In view of the longstanding absence of corresponding integral-free formulas, it was the custom in thermophysical investigations over a long time to resort to some of the tables quoted above and to perform thus approximate estimations of the respective -ratios via interpolations between discrete -ratios quoted for the couples of the two neighbouring (or ) values. Such conventional interpolation procedures were still feasible as long as one used to be concerned only with relative small sets (limited to few dozens) of measured data points. However, in contemporary literature, one is repeatedly concerned with rather large sets (of hundreds) of data points (like the presently analyzed data sets given in  for ZnSe and ZnTe). With respect to the latter such clumsy point-by-point interpolation procedures appear to be largely obsolete. A practicable computational alternative, however, requires the availability of a duly elaborate analytical framework for the inverse relationship, which should hence enable performing straightforward evaluations of the actual -ratios directly on the basis of given heat capacity values, . It is the main purpose of the present study to develop here (within Appendix B) such a representative analytical framework of integral-free formulas and to present corresponding sample results for Debye temperatures of ZnSe and ZnTe.
Concerning the successive development of this novel analytical apparatus for Debye temperatures, we would still like to note that some partial results in form of asymptotic (approximate) Debye temperature expressions had already been published in two preceding papers, namely, in  for the low-temperature region (),and in  for the complementary range of higher temperatures (),
However, due to a lack of space, the somewhat unusual derivation procedure for this highly useful high-temperature formula (i.e., Eq. in ) could not be included into the former paper. A duly detailed display of the corresponding analytical derivation procedure is now made up, among other things, in Appendix B.
In Section 2 we briefly sketch the basic arguments and equations of the analytical framework for theoretical calculations of isobaric heat capacities. In Section 3 we display a reformulated, integral-free version of the multioscillator hybrid model [14, 21, 50]. This is based mainly on the usage of novel, unprecedented analytical formulas (derived in Appendix A) for the contributions of the continuous, long-wavelength sections of transverse acoustical (TA) phonons to the resulting lattice heat capacities. In Section 4 we adopt (in analogy to ) a special 4-peak Einstein oscillator constellation of the hybrid model, and we use the respective analytical heat capacity expression for careful fittings of compatible sets of low- and high-temperature data available for ZnSe and ZnTe (up to 600 K). In Section 5 we perform, on the basis of a couple of precision formulas derived in Appendix B, transformations of the experimental heat capacity data in question (including the corresponding theoretical and curves), into the respective Debye temperature representations. The results are discussed in Section 6.
2. Basic Equations for Temperature Dependencies of Heat Capacities in Solids
Within the frame of the harmonic lattice regime, the temperature dependencies of the isochoric heat capacities, , are well known to be given by corresponding heat capacity shape functions, , of the general form [4, 6, 45, 50–55]where we have denoted by the energies of the individual phonons and represents the material-specific PDOS spectral function [3, 4, 19, 56]. The latter is supposed within the present context to have been normalized to unity [6, 45, 52, 53, 55]; that is, .
Within the frame of numerical analyses of experimental heat capacity data, however, one is continually concerned with a basic theoretical complication due to the inherent differences between the temperature dependencies of theoretical functions, on the one hand, and those of measured (isobaric) heat capacities, , on the other hand. The latter are well known to be throughout somewhat higher, , than their theoretical (isochoric) counterparts pertaining to the harmonic lattice regime [4, 50, 54]. The respective differences, , are usually found to be very small from 0 up to temperatures of order , where the heat capacity amounts to about 50% of the Delong-Petit limiting value, . On the other hand, one is usually concerned with a relatively strong monotonic increase of these differences, , at higher temperatures (). These differences are generally ascribed to cumulative effects of lattice expansion and lattice anharmonicities [3, 11, 18, 21, 23, 39, 50, 54, 56, 57]. We have repeatedly found within a larger series of heat capacity studies [14, 15, 21, 50, 54] that, within regions from up to temperatures of order (at least), the rapid increase of these differences can be simulated in good approximation by a proportionality of type (note that the structure of the latter is analogous to the known Nernst-Lindemann formula [2, 3, 58], , for the differences between isobaric and isochoric heat capacities). Admitting, furthermore, that at sufficiently high temperatures (up to melting points, if necessary) some additional higher-order power terms of may come into play, it appeared reasonable to simulate the -dependencies of isobaric heat capacities by a duly general algebraic expression of the form [14, 15, 21, 50, 54, 59]where the empirical Taylor series expansion coefficients, , are quantifying the material-specific weights of contributions of the individual, anharmonicity-related power terms [15, 21, 54, 57]. Furthermore we have still included into (5) an additional linear term, , which has to represent possible contributions of a degenerate electronic system [4, 6, 13, 23, 60–63] to the measured heat capacities. Such electronic contributions (“Sommerfeld terms” [4, 6, 60]) are known to be rather strong (tending to become even the dominant ones, at sufficiently low temperatures) in metals, due to large concentrations of conduction electrons. In contrast to this, such electronic contributions are as a rule rather weak in semiconductors and insulators due to the relatively low concentrations of free electrons associated with lattice imperfections (impurities). Accordingly, the actual strengths of such electronic contributions can vary considerably even between different samples of one and the same semiconductor material [4, 62]. We will find below (in Section 4) indications for some weak electronic contributions to the isobaric heat capacities measured at liquid-helium temperatures , for both ZnSe and ZnTe.
3. Multioscillator Hybrid Model and Its Integral-Free Representation
Physically realistic, material-specific phonon density of states (PDOS) functions, (like those shown, e.g., in Figure 3 of  or in Figure 4 of , for ZnSe and ZnTe), which are determining the -dependencies of the respective harmonic heat capacity shape functions, (see (4)), are known to consist in general of numerous peaks (critical points) in combination with various continuous curve sections and/or gaps between them. Many fine details of such material-specific PDOS spectra, however, are practically not detectible via analyses of experimental heat capacity data [3, 64]. Their possible influence on thermal properties used to be strongly reduced by the thermal averaging process (in (4)), so that they are not discernable from the background of accidental experimental uncertainties (being usually of the order 1%). Consequently, it is as a rule possible to realize rather good fittings of available data on the basis of relatively simple theoretical model functions for PDOS spectra , provided that the latter are sufficiently general and flexible for reasonable reproductions of various prominent features, at least. This concerns above all the liquid-helium-hydrogen region [13, 64], where the lattice heat capacities are known to be represented in good approximation by Taylor series of odd-order terms [13, 16, 18, 23, 35, 39, 65]
This limiting behaviour is the automatic consequence of the well-known fact that the low-energy (TA phonon) tails of PDOS spectra for three-dimensional crystals are generally given by Taylor series [13, 16, 18, 23, 35, 39, 64, 65] of exclusively even-order power terms, , of the phonon energy. An incorporation of a corresponding continuous low-energy section into theoretical model functions is therefore indispensable for their actual applicability to the cryogenic region. At the same time it is also clear that such continuous low-energy tail sections are naturally ending (i.e., ) at the positions of the first critical points [14, 21, 50, 64], , which are usually corresponding to the first peaks of short-wavelength TA phonons (note that, for materials with zinc blende structure like ZnSe and ZnTe, the energy positions of the first critical points are corresponding to those of the L-points on the first Brillouin zone boundaries, i.e., [7, 32, 36, 45, 46, 66, 67]).
3.1. General Analytical Framework of Multioscillator Hybrid Models
Less critical than the general ansatz for the region is the modelling of spectra for energies higher than the first critical points, . Numerous analyses have shown that excellent simulations of dependencies (4), from cryogenic to room temperatures, can be realized on the basis of combinations of several (macroscopic) Einstein oscillators , ( = 1 to ), the ordered energy positions of which, , including their actual weights, , are to be properly adjusted in the course of least-mean-square fitting processes for heat capacities. Thus one can take the normalized PDOS function in (4) to be generally representable by a multioscillator hybrid model function of the sufficiently general form [14, 21, 50]where we have denoted by ( for and 0 for ) the step function, which realizes the cut of the continuous part of the function just at the first singular point. By integrating (7) over the whole spectrum (from 0 beyond the highest Einstein oscillator), we see that the supposed normalization of the function to unity is equivalent to a normalization condition of the form [14, 21, 50]for the whole set of weighting factors. This condition is to be strictly fulfilled within any fitting process of experimental data on the basis of the model function (7).
Inserting, finally, the function (see (7)) into the integral (4) and denoting by ( = 1 to ) the characteristic Einstein temperatures corresponding to the energy positions of the individual macroscopic oscillators we obtain for the normalized (harmonic) heat capacity shape function the general expression [14, 21, 50]where the functions (being due to the two continuous components, , in (7)) are given in form of integrals of Debye and non-Debye type [14, 21]
Here we have denoted bythe ratio of the characteristic phonon temperature associated with the first (lowest) special point, , versus lattice temperature, (in analogy with the notation used within Debye’s theory, ; cf. (1) and Appendix A).
Informative byproducts of numerical fittings of measured data sets via (5), in combinations with (9) for the harmonic heat capacity shape function, (including (10), for the components), are the moments, , of material-specific PDOS spectral functions [3, 4, 16, 18, 19, 21, 50, 52, 56, 69–72], which are generally defined by
3.2. Integral-Free Formulas for the Contributions of Long-Wave Acoustical (TA) Phonons
On the basis of the hitherto used original (i.e., integral) expressions (see (10)) for the two low-phonon-energy contributions, (in (9)), the corresponding least-mean-square analysis procedures performed in several preceding studies [14, 21, 50] turned out to be somewhat heavy and time-consuming. This disadvantage of the former hybrid model versions [14, 21, 50] was one of the main motivations for performing here (in Appendix A) a comprehensive analytical study aiming at the construction of more practicable, integral-free formulas for the integrals (10) of Debye and non-Debye type.
Consider first the integral (10) for the low-energy component of Debye type, (see Figure 1). A detailed analyses (in Section A.2 of Appendix A) has shown that the corresponding dependence (see (A.13)) can be represented in good approximation in terms of a proper combination (A.16) of truncated low- and high-temperature expansions, (see (A.14)) and (see (A.15)), assuming a switch between the two complementary branches just at their crossing point, = 6.5135 (cf. the upper inset of Figure 1). This means for the low-temperature branch, ,and for the high-temperature branch, , (the respective expansion coefficients of which, , are listed in Table 6).
Concerning the integral (10) for the second low-energy component, (see Figure 1), we have found within the frame of a detailed study (in Section A.2, of Appendix A) that the corresponding dependence of non-Debye type (see (A.17)) can be represented in good approximation in terms of the combination (A.24) of the truncated low- and high-temperature expansions, (see (A.18)) and (see (A.23)), assuming again a switch between the two complementary branches at the respective crossing point, (cf. the lower inset of Figure 1). This means for the low-temperature branch, , explicitlyand for the high-temperature branch, , (the respective expansion coefficients of which, , are listed in Table 6).
The large scale representations of the and curves in Figure 1 are suggesting apparently perfect coincidences between the exact (solid) curves and the respective approximate curve sections. At the same time we see, from the insets of Figure 1, that the approaches to the exact functions are really excellent only in the regions < 5 and > 9, whereas one is concerned in the vicinities of the crossing points, that is, at = 6.5135, for the Debye-like component, and at = 7.0962, for the non-Debye component, with certain overestimations of the exact values by the approximate formulas (up to a maximum order of 0.008%, for = 1, or of 0.015%, for = 2). Yet, such computational inaccuracies are by 1 to 2 orders of magnitude smaller than the typical uncertainties of measured heat capacities, . Thus, these computational inaccuracies are usually negligible within the frame of practical applications.
3.3. Connection with Conventional Cryogenic Heat Capacity Parameters
At sufficiently low (liquid-helium) temperatures, where , the first terms ( or ) in the respective low-temperature expressions (see (14) and (16)) are strongly dominating. Thus the Debye-like and non-Debye components, ((see (10) for = 1 and 2, resp.), tend here to the known and asymptotes [14, 21]
The asymptote of the component is of Debye type , whereas the asymptote of the component is responsible for the onset of the typical non-Debye behaviour. The latter is frequently emerging already at very low temperatures (of order ), where the Einstein oscillator terms in (9) for the dependence are practically negligible (owing to their plateau behaviour, ; cf. also the curve in Figure 1). In this way we satisfy ourselves that the low-temperature dependence of the harmonic lattice heat capacity, (see (4)), reduces, as expected, to a couple of two odd-order terms [13, 16, 18, 23, 35, 39, 65], (see (6)). The respective expansion coefficients, and , are readily seen to be given in terms of the weighting factors and , the characteristic phonon temperature associated with the first Einstein peak, , and the classical Dulong-Petit heat capacity value, , by the relations
Comparing, finally, the analytical expression for the limiting (cubic) asymptote implied by the present formalism, (due to (19)), with its conventional predecessor, (due to Debye’s theory [1–3, 8, 13]), we see that these two expressions are coincident when the weighting factor for the Debye-like component, , is just given by the cube [14, 21] of the ratio between the characteristic phonon temperature associated with the first Einstein peak, , and the limit value, of the conventional Debye temperature; that is,
4. Sample Analyses of Heat Capacity Data Sets for ZnS and ZnTe
For the sake of numerical analyses of given experimental heat capacity data within the frame of a multioscillator hybrid model like that displayed above, it is still necessary to specify the material-specific constellation (in particular the total number, ) of Einstein oscillators to be taken into consideration. A relatively simple version in form of a three-oscillator-based hybrid model  had been used in  for a large variety of III–V and II–VI materials with partly different crystal structures. Within the present (more detailed) study, for ZnSe and ZnTe, we shall consider a structure-specific constellation of four discrete oscillators (in analogy to ), which offers a physically adequate association with the contributions of the 6 phonon branches in zinc blende structure materials (consisting of 2 TA branches and 1 LA branch, for the lower parts, and 2 TO branches and 1 LO branch, for the upper parts, of the respective PDOS spectra [7, 32, 36, 45, 46, 66, 67]). Let us briefly sketch the basic arguments in favour of the corresponding four-oscillator model .
4.1. Four-Oscillator Constellation Chosen for ZnSe and ZnTe
In the course of numerous analyses of experimental data sets by different versions of the multioscillator hybrid model [14, 21, 50] we have repeatedly made the experience that a necessary condition for the contributions of two oscillator peaks to be actually discernible, in the course of least-mean-square fitting processes, consists in a sufficiently large distance (of more than 10%, at least) between their respective ( versus ) energy positions. Considering under this aspect the known positions of the dominating optical ( versus ) phonon peaks [7, 32, 36, 45, 46, 66, 67] in ZnSe and ZnTe we see that their relative distances are markedly smaller than 10%, so that their individual contributions to the measured dependencies are practically indiscernible. Consequently, the contributions of the three optical phonon branches can be lumped together, being thus representable within the four-oscillator hybrid model  by a single oscillator with the highest energy, , and a fixed weight of
Qualitatively quite different is the state of affairs for the three acoustical phonon branches. From the theoretically calculated PDOS spectra [7, 32, 36, 45, 46, 66, 67] one can see that the distances of the dominating short-wave LA peaks from the prominent TA peaks (as well as from LO/TO peaks) are larger than 30%. The contributions of the dominating LA peaks, (= centres of gravity of the LA branches), are thus well discernible from the contributions of TA phonons as well as from those of the LO/TO phonons. This corresponds in reasonable approximation to a fixed weight offor the -oscillator. Finally, with respect to the 2 TA phonon branches, we observe that the energy differences, for example, between the special points and , are larger than 20% [7, 32, 36, 45, 46, 66, 67], so that their individual contributions have good chances to be still discernible within the frame of duly careful numerical analysis procedures. This observation suggests representing the whole variety of short-wave TA phonons by two discrete model oscillators, ( = 1 and 2). Concerning their actual weights, and , we observe that, owing to the preceding fixations of the weights for the LA and LO/TO oscillators (i.e., (21) and (22)), the global normalization condition (8) for the weights of all contributions associated with the two TA phonon branches (i.e., and , in combination with and ) reduces, consequently, to a normalization condition of the TA phonon-related weighting factors of the special form 
Accordingly, only 3 of these 4 weighting factors are actually playing the role of independent fitting parameters; that is, the magnitude of one of them is automatically fixed by the set of the three other ones (e.g., ). In summary, within this special 4-oscillator hybrid model , which turns out to be obviously well suited for binary materials with zinc blende structure, the normalized heat capacity shape function, (9), reduces to a parameterized function of just 7 independent parameters (consisting of the 4 discrete phonon temperatures , = 1 to 4, in combination with the three weighting factors , , and ).
Furthermore we would still like to observe that, in many cases, one knows at least approximate values for the 0 limiting values of Debye temperatures, (either as results of former analyses of cryogenic heat capacity data [13, 34] or from independent estimations on the basis of elastic constants [35, 73–77]). This preliminary knowledge allows us, if necessary, to substitute the weight, , of the Debye-like component, , by (according to (20)).
4.2. Additional Empirical Parameters Involved by the Isobaric Heat Capacities
It has already been pointed out above (in Section 2) that, for numerical simulations of measured isobaric heat capacity data, , by means of (5), it is generally necessary to envisage the inclusion of further empirical parameters (like , , and/or ) into the fitting process. Such additional parameters have been introduced above for a quantification of the deviations, , of measured values from the theoretical (harmonic) lattice heat capacities, (see (4)), due to lattice anharmonicities and possible electronic contributions. The actual inclusion (or exclusion) of one or the other additional parameter depends, of course, on the concrete constellation of the whole set of experimental data in consideration.
The crucial experimental basis of the present heat capacity analyses, for ZnSe and ZnTe, was provided by Kremer et al.  in form of unusually comprehensive and informative sets of data points comprising the regions from 2 K up to 277 K, for natural ZnSe, and up to about 150 K, for natural ZnTe (see the sets of and data points  represented by empty circles in Figures 2 and 3, resp., and cf. Figure in ). Yet, particularly from the inset of Figure 2 we see that the sequence of the respective data points () for ZnSe are indicative of some nonmonotonic (local minimum) behaviour in the liquid-helium region. This is at variance in particular to earlier data (+) given for the interval 1.7 K to 24.8 K by Birch (see Table of ), which showed an exclusively monotonic behaviour of the sequence of the respective data points (+) in the same region.
The more or less pronounced nonmonotonic behaviours of Kremer’s data points for natural ZnSe (Figure 2) and ZnTe (Figure 3), in the vicinities of 3.7 K or 2.6 K, respectively, can be ascribed to relatively weak (nevertheless not completely negligible) contributions of degenerate electronic systems to the measured dependencies (in analogy to similar observations reported for semiconductor materials like Si , Ge , several III–V materials , and FeGa3 ). Such electronic contributions are analytically represented within the present context by the respective linear (electronic) term, , in (5).
The subsequent least-mean-square fitting processes are thus to be performed on the basis of (5) in combination with (9), (14) to (17), and (20). For present purposes we shall limit the sets of high-temperature data, which are to be actually included into the fitting processes, to temperatures up to 600 K (for both materials under study). Owing to these limitations we found that couples of just the first two anharmonicity-related expansion coefficients, and (in (5)), are sufficient for good simulations of the respective high-temperature curve sections. The present least-mean-square fitting processes are thus involving simultaneous adjustments of the (more or less strongly correlated) magnitudes of altogether 10 model-specific parameters.
4.3. Combined Fittings of Low- and High-Temperature Data and Results
Concerning the case of ZnSe (Figure 2) we have performed a simultaneous fit of the comprehensive set of data () given by Kremer et al.  in combination with a series of directly measured values (△) given for the region 400 K 600 K by Pashinkin and Malkova (cf. Table in ). The resulting total set of adjusted parameters is listed in Table 1. For comparisons of the presently analyzed data with some former ones given by various authors we have still shown in Figure 2 the fine K data points due to Birch  (+), the more or less strongly deviating data points due to Adachi et al. [10, 33] (◊) and Sirota et al.  (□), two data points given (for = 300 and 600 K) by Gadzhiev et al.  (●), and several smoothed values estimated by Pashinkin and Malkova  ().
For the case of ZnTe (Figure 3), the present fit comprises the set of data () given by Kremer et al.  in combination with the upper section (102 K < < 327 K) of the set of data points (□) given by Gavrichev et al. (in Table of ), including a set of approximate data points () due to Gadzhiev et al. (which we have redigitalized from Figure 1 shown in ), and a series of equidistant (smoothed) data points () available from the SGTE data review . The resulting total set of adjusted parameters is listed in Table 1. For comparisons of the presently analyzed data with some former ones given by various authors we have still shown in Figure 3 the data points due to Adachi et al. [10, 33] (◊), Demidenko and Maltsev  (+), and the compatible sections (up to 600 K) of a series of smoothed values (□) quoted by Gavrichev et al. .
The fitted (continuous) and dependencies, which are implied by the material-specific sets of fitted parameter values (listed for ZnSe and ZnTe in the upper part of Table 1), are represented by solid and dashed curves, respectively, in Figures 2 and 3. In the insets of these figures we have represented the respective magnitudes of ratios. The series of empty circles  as well as the corresponding solid curves, , show pronounced non-Debye behaviours (maxima) in the vicinities of = 16.9 K (for ZnSe) and = 13.6 K (for ZnTe). The levels indicate the estimated limiting values, , of the curves, which are due exclusively to the lattice contributions to the measured heat capacities; that is, (within the liquid-helium-hydrogen region).
In the lower part of Table 1 we have still quoted a series of characteristic, material-specific quantities, the actual values of which are resulting in unambiguous way from the fitted parameter sets. This concerns in particular the associated magnitudes (due to (19)) of the coefficients and (referring to the conventional cryogenic odd-order series expansion (6)), the first- and second-order moments of the PDOS model function, and (due to (13)), the respective average phonon temperatures [14, 21, 50], , the dispersion coefficients [14, 21, 50], , and the high-temperature () limiting values of the true Debye temperatures [14, 21, 50], (cf. (42) below). Furthermore, with respect to the frequently considered (thermochemical) reference temperature, 298.15 K, we have still quoted the fitted (smoothed) isobaric heat capacity values, [14, 50], and the respective entropy values and enthalpy differences defined by [14, 15, 50]
We have given in Table 2, for a series of selected -values, a list of smoothed isobaric lattice heat capacity values, , including the corresponding (effective) lattice Debye temperatures, , which have been calculated on the basis of precision formulas to be presented below (in Section 5).
5. Transformation of Heat Capacities into Debye Temperatures
Expressive visualizations of typical non-Debye features of the temperature dependencies of heat capacities of solids are based above all on the results of point-by-point transformations of isobaric heat capacity data, , into the respective (effective) Debye temperature values, . The latter are well known from Debye’s classical paper  to be defined in implicit way [1–4, 13–15, 56] by an integral of the form (1), where the magnitudes of the characteristic (dimensionless) variable, , are representing the upper limits of integration. The original task of calculating temperature dependencies of heat capacities within the frame of Debye’s theory  involved thus, primarily, the necessity of preparing good approximations for the dependence of Debye’s model-specific heat capacity function, , on . A detailed analytical study of the corresponding function (see (A.1)) is performed in Appendix A. Crucial results of this study are given, above all, in terms of approximate algebraic expressions for the respective low- and high-capacity dependencies, and , which can be, fortunately, transformed in exact way into corresponding algebraic expressions for the respective inverse dependencies, (see (B.1)) and (see (B.3)). Starting from these approximate expressions for low- and high-capacity curve sections, we succeeded to construct in Appendix B an unprecedented, integral-free analytical apparatus for approximate (more or less rough) estimations up to high-precision calculations of the complete dependence. Let us display in explicit form the integral-free formulas which are actually to be used here for the transformations of the heat capacity data under study (for ZnSe and ZnTe) into the respective Debye temperatures.
5.1. Asymptotic Low- and High-Temperature Formulas
The asymptote of Debye’s low-temperature expansion [1, 3], (cf. (A.4)), was already found in  to be of primary importance for a proper interpretation of the behaviour in the liquid-helium-hydrogen region. From the latter followed readily for the inverse function, , an asymptotic dependence of the form (see (B.1)). The respective limiting () dependence of the Debye temperature, , was thus explicitly given by the asymptotic expression [13, 15] (cf. Eq. in ), where the last representation of the dependence in (25) is in accordance with the general relation (cf. Eq. (6) in ). However, the inherent deviations (overestimations) of approximate values (due to (25)) from exact values are found to be lower than 1% only for very low magnitudes of heat capacities, 0 < 0.03, which are corresponding to values higher than 14 (cf. Table 9 and Figure 9).
A good basis for establishing an appropriate algebraic formula for the qualitatively different behaviour at considerably smaller values is provided by the unprecedented Taylor series expansion (see (B.3)), which we have shown here to follow in unambiguous way for the reciprocal version, (see (A.11) and (B.2)), of the function (see (A.10)). Accordingly, the temperature dependence of the Debye temperature, , for moderate-to-high heat capacities, is clearly confirmed to be given by the approximate algebraic expression 
Note that the latter formula corresponds just to Eq. () in , where it had already been taken into consideration for data discussions of various III–V materials. This formula is seen to provide a reasonable approximation (within possible deviations up to ±0.7%) to the exact curve throughout the range 0.05 < 1 (as shown in the upper inset of Figure 9 by the relative deviations, , of the approximate curve from the exact dependence).
5.2. Couple of High-Precision Formulas for Effective Debye Temperatures
In view of the sample character of the numerical analyses performed within the present study for the unusually fine and comprehensive data provided by Kremer et al. , we have constructed in Appendix B (Section B.3) a high-precision framework for the dependence. This consists in a combination of a highly elaborate (12-parameter) low-capacity formula, (see (B.8)), with a duly modified (11-parameter) high-capacity formula, (see (B.9)) (where = 0.26 represents the position of the point of crossing between the two complementary branches). The respective low- and high-temperature formulas for the Debye temperature, , are thus given explicitly by the couple of analytical expressions of the formfor the interval (with expansion coefficients , , and listed in the second column of Table 8), andfor the interval (with expansion coefficients listed in the third column of Table 8). Note that we have still endowed the functions in (27) and (28) by an additional subscript “” (included in brackets) in order to indicate that precisely the same formulas can also be used, alternatively, for high-accuracy calculations of the “true” Debye temperatures, , which are visualizing the characteristic non-Debye features of the harmonic parts of lattice heat capacity curves, (see (4); Figures 4 and 5).
By means of this couple of the high-accuracy formulas (27) and (28) we have performed, first of all, the point-by-point transformations, , for all those isobaric heat capacity data points, , with respect to which the concept of effective Debye temperatures is actually applicable, that is, for (cf. Figures 2 and 3). The respective Debye temperature values, > 0, are represented for ZnSe (in Figure 4) and for ZnTe (in Figure 5) by the same symbols as the original data points (shown in Figures 2 and 3, resp.).
Furthermore, we have transformed in the same way (i.e., via (27) or (28)) the continuous curves (solid curves shown in Figures 2 and 3), which resulted from the preceding numerical fittings in Section 4. These continuous curves (solid curves, in Figures 4 and 5) are naturally ending at those temperature points, , where the fitted curves (in Figure 2 or 3) are crossing just the classical Delong-Petit heat capacity value, , that is, at about 401 K for ZnSe (cf. Figures 2 and 4) and about 323 K for ZnTe (cf. Figures 3 and 5).
5.3. Calculation of “True” (Harmonic Lattice) Debye Temperatures
Of considerable interest, particularly from theoretical points of view [3, 14, 21, 28, 29, 32, 36, 56, 72], is the determination of the “true” (-related) Debye temperature curves, . The latter are defined with respect to the harmonic (isochoric) lattice heat capacities, (see (4)), by [14, 21]where the dimensionless variables are representing the respective upper boundaries of integration. Comparing (29) with (A.1) we see that the analytical connection of the upper boundaries of integration, , with the respective normalized (harmonic) heat capacity ratios, (in (29)), is just the same as the preceding connection between and (in (A.1)). Consequently, all the approximation formulas derived in Appendix B, for low- and high-capacity branches of the function (cf. Figure 9), can be readily used for calculations of the dependence implied by (29). This means, in particular, that (27) and (28) can be simultaneously used (as already indicated by the inclusion of the subscript “h”) for high-precision calculations of the dependencies of the “true” Debye temperatures, , on the respective harmonic (isochoric) heat capacities, . The corresponding material-specific curves are represented by dashed curves (for ZnSe and ZnTe in Figures 4 and 5, resp.).
With respect to this alternative use of (27) and (28), for calculations of curves, we would still like to point out that, apart from the liquid-helium-hydrogen region (see below), appreciable differences between and values, similarly to the differences between the underlying and values (cf. Section 4), are encountered as a rule only in ranges of moderately low to higher temperatures, , where the heat capacities in question are higher than about 50% of the classical Dulong-Petit limiting value, . This region is automatically comprised by the range of validity of (28). Thus it is mostly not necessary to involve (27) into separate calculations of curve sections.
On the other hand, significant differences between and values may also occur at very low (liquid-helium-hydrogen) temperatures, when we are (accidentally) concerned with nonnegligible contributions, , of a degenerate electronic system to the measured heat capacities, (cf. (5)). Consequently, in order to determine the respective temperature dependence of the curve within the liquid-helium-hydrogen region, we have to insert , instead of , into the respective asymptotic (low-) expression (see (25)). The monotonically decreasing sections, , of the “true” Debye temperature curves at sufficiently low temperatures, (see the insets of Figures 4 and 5), are thus adequately described by a corresponding asymptotic expression of the form where and (see also  and cf. the insets of Figures 2 and 3). These asymptotic dependencies are represented by dotted curve sections in the insets of Figures 4 and 5.
The present investigations were devoted above all to the finding of practicable solutions for longstanding computational problems which are frequently emerging within interpretations of the results of experimental heat capacity studies utilizing the somewhat troublesome concept of Debye temperatures [1, 3, 4, 6, 10–15]. The notorious computational complications are due to circumstance that the respective values are involved into the definition of the upper limits of integration, , due to the integral expression for isobaric heat capacities, (see (1)). Consequently, in view of the previous lack of integral-free formulas for dependencies on values, it was thus necessary either to calculate the individual values via numerical integration procedures (using (1)) for all the individual points in consideration or to determine the values approximately, via point-by-point interpolations, using some of the available tables [6, 8, 47–49].
Within our detailed study of the analytical properties of the conventional dependence (in Appendix A) we succeeded to derive, first of all, an unprecedented, rapidly converging high-temperature Taylor series expansion, (see (A.11)). Combining the latter with Debye’s conventional low-temperature expansion , (see (A.4)), it became possible to perform high-accuracy calculations of values (up to at least 10 significant figures; cf. Table 7) without involving any numerical integration procedure. The subsequent adoption of respective and formulas to the Debye-like component, (see (10)), of the long-wave TA phonon contribution to the cryogenic heat capacity, including the derivation of analogous formulas for the associated non-Debye component, (see (10)), enabled us to display (in Section 3.2) an integral-free version of the multioscillator hybrid model [14, 21, 50]. This has been used here (in Section 4) for numerical fittings of the data sets under study.
The high-accuracy results obtained in Appendix A for the dependence provided us, among other things, with the numerical basis for the solution of another and practically even more important mathematical problem, namely, the construction of appropriate integral-free formulas for the inverse Debye function dependence, that is, the function (see Figure 9 and Table 9), which describes the functional dependence of the characteristic Debye versus lattice temperature ratios, , on the ratios, , of given heat capacities versus Dulong-Petit classical heat capacity limit.
We have derived (in Appendix B) a series of more or less elaborate formulas for low- and high-capacity curve sections of the curve (solid curve in Figure 9). The simplest one of these approximate expressions is given in form of a junction formula, (see (B.4a)/(B.4b)), the actual use of which, however, is still connected with deviations from the exact dependence up to 0.6% (cf. the upper inset of Figure 9). Reductions of residual deviations to ±0.13%, or even to ±0.0153%, could be achieved (in Sections B.1 and B.2) via least-mean-square fittings of the exact dependence, adopting either the still relatively simple (2-parameter) formula, (see (B.5a) and (B.5b)), or the refined (9-parameter) formula,