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Giuseppe Grieco, Guido Masiello, Carmine Serio, "Operational Monitoring of Trace Gases over the Mediterranean Sea", Advances in Meteorology, vol. 2015, Article ID 318608, 9 pages, 2015. https://doi.org/10.1155/2015/318608
Operational Monitoring of Trace Gases over the Mediterranean Sea
This paper describes the operational implementation of the processor -IASI over the Mediterranean sea. The -IASI model implements two physically based inversion algorithms for the sequential retrieval of (a) the thermodynamic state of the atmosphere and (b) the tropospheric content of CO, CO2, CH4, and N2O from hyperspectral radiance observations of the Infrared Atmospheric Sounding Interferometer (IASI). The retrieval algorithm for trace gases exploits the concept of partially scanned interferogram technique, which is a tool mostly suited for Fourier transform spectrometers in the infrared. Minor and trace gases retrievals for July 2010 are presented and compared to in situ observations from five Mediterranean, permanent, stations of the Global Atmospheric Watch (GAW) network. The comparison evidences a good general consistency between satellite and in situ observations. IASI retrievals show a marked southeastern gradient, which is shown to be consistent with the general tropospheric circulation over the Mediterranean basin. These patterns are barely seen from in situ observations, a fact which stresses the importance of satellite (trace gases) data assimilation to improve the performance and quality of trace gases transport models.
The Infrared Atmospheric Sounding Interferometer (IASI) is a Michelson interferometer developed by the European Agency for the Exploitation of Meteorological Satellites (EUMETSAT). It has been flying onboard the polar Metop A/B orbiting platforms since October 2006 . IASI sounds the atmosphere in the infrared spectral band between 645 cm−1 (15.5 m) and 2760 cm−1 (3.6 m) with a spectral sampling of 0.25 cm−1 with the aim of retrieving the thermodynamic state of the atmosphere and its chemical composition for both weather and climate applications. The high quality hyperspectral radiances acquired by IASI  allows us to retrieve the thermodynamic structure of the atmosphere with a vertical resolution of 1-2 Km and an accuracy of 1 K for the atmospheric temperature, an accuracy of 0.5 K for the skin temperature, and an accuracy of 10–20% for what concerns the vertical structure of water vapor. These retrieval accuracies meet the World Meteorological Organization (WMO) requirements and, generally, they can be achieved by applying physically based retrieval algorithms .
In this paper, we present an operational implementation of the physically based forward/inverse model, called -IASI [3, 4], for the Mediterranean Sea. The -IASI model is a physically based retrieval package for the estimation of the thermodynamic structure of the atmosphere (surface temperature (), temperature (), water vapour mixing ratio (), and ozone mixing ratio (O3) profiles) and the tropospheric columnar content of minor and trace gases, namely, CO, CO2, CH4, and N2O, from clear sky radiance measurements acquired by IASI.
The limb-sounding of upper and lower stratosphere trace species is amongst the main goals of many satellite missions, for example, Atmospheric Chemistry Experiment (see, e.g., http://www.ace.uwaterloo.ca/) and MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) of the European Space Agency (see, e.g., https://earth.esa.int/web/guest/missions/esa-operational-eo-missions/envisat/instruments/mipas). However, our study focuses on the retrieval of trace gases from IASI, which is a nadir-looking instrument.
The subject of remote sensing of atmospheric minor and trace gases from nadir-looking instruments on board polar satellites is not a new subject. Instruments used for this objective include the Japanese IMG (Interferometric Monitor for Greenhouse Gases) , the American AIRS (Atmospheric Infrared Radiometer Sounder) [6–8], the European IASI [9–17], and the Japanese GOSAT (Greenhouse Gases Observing Satellite) .
In this study we offer a different perspective focusing on the use of the partially scanned interferogram (PSI) methodology, first introduced by , and demonstrating its capability of achieving columnar contents of trace gases with an unprecedented precision . IASI retrievals for July 2010 over the Mediterranean basin will be compared with in situ observations of the GAW (Global Atmospheric Watch) network. The retrieval exercise will also deserve to get better insight into understanding whether satellite observations of heavy molecules, such as CO2 and N2O, can track synoptic-scale weather patterns as claimed by Chahine et al. .
The paper is organized as follows. Section 2 gives a description of the modules of the -IASI package. Section 3 describes and discusses the results of a retrieval exercise for July 2010; the same section also deals with an analysis of the computing performance of the code. Conclusions are drawn in Section 4.
2. The -IASI Forward/Inverse Software Package
In this section we summarize the main methodological aspects regarding the algorithms implemented in -IASI. An in-depth description of -IASI and its accuracy and validation has been presented in many papers [2–4, 21], which the interested reader is referred to for further details.
The model -IASI is a MATLAB written software package which consists of seven modules which sequentially process the clear sky spectral radiance observations acquired by IASI. These include a scene analysis module to select only clear sky measurements; an Empirical Orthogonal Functions (EOF) statistical regression scheme to provide the first guess for the next module, which implements an iterative optimal estimation algorithm that we call -IASI . The inverse module -IASI uses a physical radiative transfer model, which is provided by the module -IASI . The two modules -IASI and -IASI are the core of the -IASI model. Once -IASI has provided the thermodynamic state of the atmosphere (, , H2O, O3); this state forms the input for each of the modules dedicated to the computation of the total columnar content of minor and trace gases, that is, CO, CO2, CH4, and N2O. The flow chart of -IASI is shown in Figure 1. Further details about the individual modules are given below.
2.1. The Scene Analysis Module
The high spectral resolution of new advanced infrared sensors has resulted in better coverage and significantly improved temperature and moisture soundings capabilities compared with the current situation. Infrared data from nadir-looking instruments, however, are frequently affected by clouds. Thus, observations must be processed for operational data assimilation and inversion for geophysical parameters by screening to remove cloud-contaminated soundings. This operation is performed with a Scene Analysis module, which is normally based on thresholding of a suitable radiance channels. The scene analysis module embedded in -IASI has been variously described in many papers. The most up-to-date version of the module can be found in .
2.2. The -IASI Code
The forward model embedded in -IASI is called -IASI . This is a monochromatic forward module using a look-up table for the optical depth. The look-up table is derived from LBLRTM (Line-by-Line Radiative Transfer Model) model . For the work here shown we have used LBLRTM version 12.2. The forward module is based on 60 pressure layers, spanning the atmosphere from the ground level to the top assumed to be at 0.005 hPa. The model computes spectral radiances and analytical Jacobian derivatives of any surface and/or atmospheric parameter. IASI radiances are obtained through convolution with the IASI Instrumental Spectral Response Function (ISRF).
2.3. The EOF Module
The EOF module is a statistically based algorithm for the retrieval of the thermodynamic state of the atmosphere (, , H2O, and O3). The general analytic formulation of the problem is described in the work of Serio et al. , which the interested reader is referred to for more details. Basically, the module is based on a linear regression among atmospheric parameters and radiances, represented through a truncated expansion of EOF scores. In fact, the radiances are first transformed to EOF scores and a truncated expansion is used to reduce the dimensionality of the data space. The regression coefficients are computed on the basis of a suitable training data set. For the current implementation we use a set of (, , H2O, O3) state vectors derived from the ECMWF (European Centre for Medium-Range Weather Forecasts) analysis for July 2010. A total of 1147 state vectors were used, which uniformly cover the Mediterranean basin.
2.4. The -IASI Module
The -IASI module  implements an iterative algorithm for the optimal estimation of the thermodynamic state of the atmosphere. The algorithms simultaneously retrieves the state vector which, for sea surface, is made up of (, , H2O, O3). For sea surface emissivity we use the Masuda model .
The retrieval algorithm follows Rodgers optimal estimation  and uses an additional regularization parameter which improves the retrieval accuracy and convergence rate of the inverse scheme [15, 21]. The optimal estimator we use to get an estimate of the state vector from spectral radiances has been first derived by Carissimo et al.  and discussed at length by Grieco et al.  and Masiello et al. .
The -IASI estimator readswhere the superscript indicates the transpose operation. Without any loss of generality, we assume that we are in a region around the first guess in which problem (1) is linear. If not, the scheme has to be further iterated according to the usual Gauss-Newton scheme . With this in mind, in (1), we havewhere , , and are the parameters’ state vector (estimated), the priori or background vector, and the first guess state vector (the size of these vectors will be denoted by ). Furthermore, in (1) is the observational covariance matrix and indicates a suitable smoothing operator, normally fixed to the covariance matrix of (e.g., ). is the vector (size ) of observed radiances, , with being the forward model. Furthermore, the × derivative matrix or Jacobian derivative, , is computed as If we definethen (e.g., ) (1) can be written in the equivalent formwhich says that scaling the background covariance by has the same effect as scaling the observational covariance matrix by .
The meaning and use of the parameter have been discussed at length by Carissimo et al.  and Grieco et al. . Basically, can improve the regularization of the inverse problem (1) and its tuning may allow us to trade off between accuracy and stability of the solution, .
In fact, introducing the operator the -IASI estimator can be put in the dimensionless formwhose solution, , is given bywith Equation (7) describes a Tikhonov-type or ridge regression regularization problem. According to Tikhonov and Arsenin (see, e.g., ) the operator describes a regularization scheme with the norm of given byWithin the context of Tikhonov theory , the regularization of the problem (7) (hence (1)) improves for . From (10) it is also seen that the amount of smoothing (regularization) is independent of the details of and , provided that they have inverse (so that we can define the operator ). This is an important aspect of the inverse problem (1) because normally both and are model approximations of the truth. Of course, the accuracy with which both and are known affects the final estimate and its error analysis.
Finally, we stress that (7) also provides a fast and effective scheme for the computation of the estimate . Based on the operator and (7) an algorithm can be developed [4, 21], which does not require the inversion of and, in case is diagonal, is fast and accurate because it just requires the singular value decomposition of the kernel .
2.5. The Minor and Trace Gases Modules: The FTS-PSI Based Retrieval Technique
The PSI based retrieval technique consists in transforming the radiance spectrum into the interferogram domain where we identify a region which is particularly sensitive to the geophysical parameter we want to retrieve. Once the resonant peak in the interferogram domain has been identified, the given gas is simultaneously retrieved with the most important interfering parameters, normally (, , H2O).
The PSI technique has been applied in several contexts and is particularly efficient when information content related to the given geophysical parameter is confined to a small portion of the interferogram radiance. This is the case, for example, of linear molecules, such as CO and CO2. In fact, the regularly spaced CO2 absorption lines around 15 m and of CO around 4.65 m yield a resonant peak in the interferogram domain. To exemplify let us consider the case of CO. For CO the radiance spectrum shows a regular line spacing of ≈3.6 cm−1; therefore, if we Fourier-transform the spectrum to the interferogram domain, we expect a resonant peak at an optical path difference (opd) of about the inverse of this value, that is, 0.28 cm. In order to better clarify this aspect, Figure 2 shows the interferogram around the expected resonance peak of CO for the US standard atmospheric profile  and for the same profile with a null concentration of CO. It can be seen that in the optical path difference interval between 0.2 and 0.3 the two interferograms are sensibly different, while they are quite similar outside this interval. This is an extreme example which gives an idea of the sensitivity of the interferogram radiance to the CO concentration near to the expected resonance peak.
The most important advantage of this technique is the improvement of the signal to noise ratio and the reduction of the influence of the interfering parameters in the final retrieval. The basics of the technique may be found in the work of Grieco et al.  and are here briefly summarized for the benefit of the reader.
For the purpose of the retrieval problem, the retrieved atmospheric parameters (these include the given gas and the set of the most important interfering factors, i.e., , , and H2O) are represented through a parametric form of the profile:where is the number of parameters to be retrieved, is the vertical profile, is the atmospheric pressure, is a suitable first guess profile, and is the parameter to be retrieved. For the case of surface temperature, (11) just reduces to the scalar formConsidering the first-order Taylor expansion of the interferogram radiance around first guess values, we havewhere, as for the radiance case, is the observed interferogram, is the interferogram computed with the forward model at the first geuss state vector, and is the Jacobian derivative of the interferogram radiance.
The vector is retrieved by means of an unconstrained least square algorithm, and an estimation of the total columnar content is carried out according towhere is the estimate of and is the surface pressure.
The usual least square a posteriori error analysis allows assessing the accuracy of the retrieval and the relative weight of the interfering parameters. Based on the a posteriori retrieval accuracy analysis, we have that the retrieved columnar content of the trace and minor gases has the error bars shown in Table 1. The details about the assessment of these values can be found in the work of Grieco et al. .
Figure 3 exemplifies the Jacobian derivative for CO mixing ratio, in the region around the interferogram resonant peak. The Jacobian derivative does not show any sharp peak all over the absorption spectral interval and most of the contribution comes from the pressure interval between 800 and 200 mb, which corresponds approximately to the region of the free troposphere. Similar results hold for the other gases considered in this study and are not shown for the sake of brevity.
3. Application to the Mediterranean Basin
The -IASI package has been applied to a dataset of ≈35000 IASI radiance spectra acquired over the Mediterranean basin for July 2010. This month has been selected because of the weather pattern over the Mediterranean region, which has been characterized by above normal surface temperatures associated with a relatively high frequency of blocking days. Likewise, a particularly long blocking event has been experienced over Western Russia that has led to the occurrence of anomalously high temperatures over this region [30, 31]. Apart from the high temperatures, July 2010 showed the typical synoptic conditions [32, 33] of the Mediterranean summer (June to September), with high pressure over the Mediterranean Europe and a low-pressure through extending from the Persian Gulf through Iraq to the southeastern Mediterranean (see Figure 4).
It is now very well understood (e.g., Karnieli et al.  and the references therein) that this kind of weather pattern yields persistent northwesterly winds which causes long-range transport of air masses from southeastern and southwestern Europe into the eastern Mediterranean basin.
Arguing that atmospheric heavy molecules, such as CO2 and NO2, follow the dominant atmospheric circulation, Chahine et al.  demonstrated that satellite derived CO2 data track weather patterns and can also be used to study the vertical and horizontal transports in the Earth atmosphere. Thus, according to Chahine et al. , because of the aforementioned summer weather pattern over the Mediterranean basin, we expect that CO2 and N2O should show a northwestern to southeastern pattern over the Mediterranean region. To study this effect, in this section, we will show and analyze trace gases retrievals form IASI data for July 2010.
To begin with, we briefly show and discuss patterns associated with retrievals of surface () and atmospheric parameters ( and O3) derived with -IASI. Figures 5 and 6 show the maps of the retrieved atmospheric 500 hPa temperature and the total columnar ozone, averaged over the whole July period. These maps and all the following ones have been smoothed with a median filter and rendered on a regular grid of 0.5° × 0.5°. The value of each image pixel is the median value of the whole month distribution of all the values in the 2 × 2 neighborhood pixels around the corresponding pixel in the input image. The maps clearly show the transition from the European midlatitude air mass type to tropical one which characterizes the southeastern region of the Mediterranean basin. This transition is very well evidenced in the temperature and ozone maps and also testifies the quality of the retrieval. In addition, Figure 7 shows the sea surface temperature, with the expected northwestern southeastern gradient. This map evidences the relatively high sea surface temperature, which in most part of the Mediterranean basin exceeds 26°C (299 K).
Figure 8 shows the retrieved tropospheric CO2 content averaged over the whole period of July 2010. The most striking feature in this map is the marked northwestern-southeastern gradient, which is consistent with the large scale synoptic weather pattern for July 2010. Thus, Figure 8 supports Chahine et al.’s  finding that the retrieved CO2 is capable of tracking the dominant atmospheric circulation. Similar results have been also found for N2O (see Figure 9) and for methane (see Figure 10).
Finally, we show and discuss the comparison with in situ observations from the GAW stations of Begur (Spain), Lampedusa (Italy), Finokalia (Greece), Cairo (Egypt), and Sde Boker (Israel). It is important to remark that this comparison is not aimed at validating the retrievals. This matter has been addressed by Grieco et al. [20, 35], and the references therein. The present comparison is aimed at getting insight into understanding whether patterns and structures seen from satellite data are also shown by in situ observations.
As already mentioned, these stations belong to the Global Atmosphere Watch (GAW) network and the data have been downloaded from the website of the World Data Centre for Greenhouse Gases. Figure 11 shows the geographical positions of the GAW stations. As it can be seen, they span all the Mediterranean basin. Three of them are seaside while Sde Boker and Cairo are about 100 Km far from the coast.
Table 2 compares the monthly average of in situ and IASI retrievals. The comparison is limited to CO2 and CH4 because these two gases have the largest density of monitoring (4 out of 5 GAW stations). There is a general consistency between in situ and satellite observations. However, systematic differences appear, which nevertheless are still consistent with the diverse atmospheric column sensed with in situ and satellite instruments. In fact, from Figure 3, we see that, conversely to in situ observations, IASI retrieval for atmospheric gases is sensitive to the free troposphere and cannot see the planetary boundary layer.
From the comparison of in situ observations and colocated satellite retrievals it can be seen that CO2 and CH4 concentrations tend to agree in showing a southeastward gradient, although it is fair to say that the gradient is much more marked for the satellite retrieval than in situ observations.
3.1. Performance of the Code
The performance of the code has been evaluated on a multiprocessor machine equipped with 6 physical and 6 virtual Intel i7 CPUs with a CPU clock rate equal to 3.33 GHz and a RAM memory which amounts to 24 GB. The time to invert a single IASI spectrum varies from about 8 seconds to 14 seconds, depending on the number of iterations the -IASI module performs. For the application discussed in this paper, the number of iterations ranges from 1 to 3 with an average number which is around 1.5. Obviously, the number of iterations depends on the quality of the first guess of the thermodynamic state of the atmosphere and this aspect is crucial for both the quality and the speed of the retrieval. For the application under examination, we can consider that the average time spent for the retrieval of a single IASI spectrum is about 10 seconds. Considering that the total number of IASI spectra over the Mediterranean basin for the whole month of July is about 35000 and that only about the 25% of the spectra have been classified as clear-sky and therefore processed by the physical inversion scheme, the computational time spent for the retrieval amounts to a little bit more than 24 hours. The availability of 6 physical CPUs reduced this time to few hours. Considering the implementation of the code for the whole globe, a number of 50 to 100 CPUs of the type described above should be enough to guarantee operability.
The hardware equipment used for the evaluation of the performance of the code is available at the moment for few thousand Euros, which means that the computer technology is now mature enough and contextually cheap to allow the full exploitation of information content of hyperspectral satellite infrared sounders such as a IASI.
The operational implementation of the -IASI software package over the Mediterranean basin for the retrieval of the thermodynamic state of the atmosphere and of the free tropospheric columnar content of CO2, CO, CH4, and N2O from the hyperspectral radiance measurements acquired by the Infrared Atmospheric Sounding Interferometer has been presented.
We have shown that -IASI can operationally retrieve skin temperature, atmospheric parameters (, H2O, and O3), and minor and trace gases, namely, CO, CO2, N2O, and CH4, at the scale of the Mediterranean basin.
The retrieval scheme has been exemplified through its application to IASI spectra recorded on July 2010. The retrieval results have been also compared to in situ observations from five GAW permanent stations. Considering that nadir-looking IASI retrievals are sensitive to the free troposphere, whereas in situ measurements sense the boundary layer, the comparison has shown a fair agreement of in situ observations with IASI observations. IASI retrieval for heavy molecules, noticeably CO2 and N2O, shows marked northwestern to southeastern gradients with a relatively higher concentration over the eastern part of the Mediterranean basin. This behaviour is both consistent with biogenic activity of the Mediterranean sea  and the large scale synoptic weather circulation in July 2010 which transports air masses from southeastern and southwestern Europe into the eastern Mediterranean basin.
Our findings support previous results for CO2 geospatial distribution  and also exemplify how satellite retrievals are complementary to in situ observations to study the vertical and horizontal transports in the Earth’s atmosphere of gases such as CO2, N2O, and CH4 which are of paramount interest in view of their crucial role within the anthropogenic greenhouse effect and hence global warming of the planet.
Conflict of Interests
The authors declare that there is no conflict of interests regarding the publication of this paper.
The measurements in Lampedusa and Sde Boker have been downloaded from the web page http://www.esrl.noaa.gov/gmd/dv/iadv/ owned by NOAA/ESRL. The measurements in Begur and Finokalia have been supplied by the Laboratoire des Sciences du Climat et de l’Environnement (http://www.lsce.ipsl.fr/). The measurements in Cairo have been supplied by the Egyptian Meteorological Authority (http://ema.gov.eg/). This work has been partly supported by The RITMARE Flagship Project (CNR-MIUR). IASI has been developed and built under the responsibility of the Centre National d’Etudes Spatiales (CNES, France). It is flown onboard the Metop satellites as part of the EUMETSAT Polar System. The IASI L1 data are received through the EUMETCast near real time data distribution service.
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