Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers
The six supramolecular assemblies in which the cluster [Nb6Cl12(CN)6] is linked to one, two, three, four, and six [Mn(III)(ACEN)]. [Nb6] refers to the cluster [Nb6Cl12(CN)6]4- and [Ta6] refers to the cluster [Ta6Cl12(CN)6]3-; Mn = [Mn(III)(ACEN)]+. (ACEN = bis(acetylacetonato)ethylenediamine).
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