Synchrotron-Radiation X-Ray Investigation of Li⁺/Na⁺ Intercalation into Prussian Blue Analogues

Table 1

Electrolyte compositions in the electrochemical deposition of the respective PBA films. NMF83, NMF87, NMF93, NCF90, NCF71, NNF68, and NCdF96 represent Na_1.24Mn[Fe(CN)₆]_0.813.0H₂O, Na_1.48Mn[Fe(CN)₆]_0.872.5H₂O, Na_1.72Mn[Fe(CN)₆]_0.932.3H₂O, Na_1.60Co[Fe(CN)₆]_0.902.9H₂O, Na_0.84Co[Fe(CN)₆]_0.713.8H₂O, Na_0.72Ni[Fe(CN)₆]_0.685.1H₂O, and Na_1.84Cd[Fe(CN)₆]_0.964.8H₂O, respectively.

Film	Electrolytes
NMF83	1.0 mmol/L K3[Fe(CN)6]	1.5 mmol MnCl2	1 mol/L NaCl
NMF87	1.0 mmol/L K3[Fe(CN)6]	1.5 mmol MnCl2	3 mol/L NaCl
NMF93	1.0 mmol/L K3[Fe(CN)6]	1.5 mmol MnCl2	5 mol/L NaCl
NCF90	0.8 mmol/L K3[Fe(CN)6]	0.5 mmol Co(NO3)2	5 mol/L NaNO3
NCF71	0.5 mmol/L K3[Fe(CN)6]	1.25 mmol Co(NO3)2	1 mol/L NaNO3
NNF68	0.5 mmol/L K3[Fe(CN)6]	0.5 mmol Ni(NO3)2	1 mol/L NaNO3
NCdF96	1.0 mmol/L K3[Fe(CN)6]	1.5 mmol MnCl2	1 mol/L NaCl