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Advances in Materials Science and Engineering
Volume 2014 (2014), Article ID 129540, 4 pages
Research Article

Preparation of N-Doped TiO2-ZrO2 Composite Films under Electric Field and Heat Treatment and Assessment of Their Removal of Methylene Blue from Solution

School of Material Sciences and Technology, China University of Geosciences, Beijing 100083, China

Received 23 July 2014; Revised 21 August 2014; Accepted 22 August 2014; Published 28 August 2014

Academic Editor: Zhaohui Li

Copyright © 2014 Lefu Mei et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


TiO2-ZrO2 composite film with the grain size of 50 nm was synthesized by electric field and heat (EF&H) treatments. Portions of O atoms in the TiO2 network structure were replaced by N atoms as revealed by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) analyses, suggesting formation of a nonstoichiometric compound on the composite film. The UV-Vis spectra of the film suggested that the visible light with wavelength of 550 nm could be absorbed for the N-doped composite film after EF&H treatment in comparison to a cutoff wavelength of 400 nm for the composite film without EF treatment. Photocatalytic experiments showed that the degradation rate of methylene blue by N-doped composite films increased significantly under visible light irradiation. The partial replacement of O by doped N played a very important role in narrowing the band gap and improving the visible light photocatalytic reactivity.