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Advances in Materials Science and Engineering
Volume 2014, Article ID 819057, 7 pages
http://dx.doi.org/10.1155/2014/819057
Research Article

Rare Earth Doped Lanthanum Calcium Borate Polycrystalline Red Phosphors

1School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China
2School of Information Science and Engineering, Dalian Polytechnic University, Dalian 116034, China

Received 19 March 2014; Accepted 15 July 2014; Published 5 August 2014

Academic Editor: Somchai Thongtem

Copyright © 2014 H. H. Xiong et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. F. Yang, Z. P. Yang, Q. M. Yu, Y. F. Liu, X. Li, and F. C. Lu, “Sm3+-doped Ba3Bi(PO4)3 orange reddish emitting phosphor,” Spectrochimica Acta A: Molecular and Biomolecular Spectroscopy, vol. 105, pp. 626–631, 2013. View at Publisher · View at Google Scholar
  2. D. Kang, H. S. Yoo, S. H. Jung, H. Kim, and D. Y. Jeon, “Synthesis and photoluminescence properties of a novel red-emitting Na2Y2Ti3O10:Eu3+,Sm3+ phosphor for white-light-emitting diodes,” Journal of Physical Chemistry C, vol. 115, no. 49, pp. 24334–24340, 2011. View at Publisher · View at Google Scholar · View at Scopus
  3. Y. H. Won, H. S. Jang, K. W. Cho, Y. S. Song, D. Y. Jeon, and H. K. Kwon, “Effect of phosphor geometry on the luminous efficiency of high-power white light-emitting diodes with excellent color rendering property,” Optics Letters, vol. 34, no. 1, pp. 1–3, 2009. View at Publisher · View at Google Scholar
  4. Z. Cui, R. Ye, D. Deng et al., “Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED,” Journal of Alloys and Compounds, vol. 509, no. 8, pp. 3553–3558, 2011. View at Publisher · View at Google Scholar · View at Scopus
  5. Y. H. Song, G. Jia, M. Yang, Y. J. Huang, H. P. You, and H. J. Zhang, “Sr3Al2O5Cl2:Ce3+,Eu2+: a potential tunable yellow-to-white-emitting phosphor for ultraviolet light emitting diodes,” Applied Physics Letters, vol. 49, Article ID 091902, 2009. View at Google Scholar
  6. H. Yamamoto, “White LED phosphors: the next step,” in Optical Components and Materials VII, Proceedings of SPIE, 2010. View at Publisher · View at Google Scholar
  7. M. K. Jung, W. J. Park, and D. H. Yoon, “Photoluminescence characteristics of red phosphor Eu3+, Sm3+ co-doped Y2O3 for white light emitting diodes,” Sensors and Actuators B: Chemical, vol. 126, no. 1, pp. 328–331, 2007. View at Publisher · View at Google Scholar · View at Scopus
  8. S. Nakamura, M. Senoh, N. Iwasa, and S. Nagahama, “High-power InGaN single-quantum-well-structure blue and violet light-emitting diodes,” Applied Physics Letters, vol. 67, p. 1868, 1995. View at Publisher · View at Google Scholar · View at Scopus
  9. H. J. Qian, J. Y. Zhang, and L. Q. Yin, “Crystal structure and optical properties of white light-emitting Y2WO6:Sm3+ phosphor with excellent color rendering,” RSC Advances, vol. 3, no. 23, pp. 9029–9034, 2013. View at Publisher · View at Google Scholar
  10. M. M. Haque, H. I. Lee, and D. K. Kim, “Luminescent properties of Eu3+-activated molybdate-based novel red-emitting phosphors for LEDs,” Journal of Alloys and Compounds, vol. 481, pp. 792–796, 2009. View at Google Scholar
  11. I. Pekgozlu, S. Cakar, and J. Lumin, “Photoluminescence properties of Li6CaB3O8.5: M3+ (M3+: Dy and Sm),” Journal of Luminescence, vol. 132, no. 9, pp. 2312–2317, 2012. View at Google Scholar
  12. H. Yu, D. Deng, D. Zhou et al., “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” Journal of Materials Chemistry C, vol. 1, no. 35, pp. 5577–5582, 2013. View at Publisher · View at Google Scholar · View at Scopus
  13. S. Neeraj, N. Kijima, and A. K. Cheetham, “Novel red phosphors for solid-state lighting: the system NaM(WO4)2−x(MoO4)x:Eu3+ (M, Gd, Y, Bi),” Chemical Physics Letters, vol. 387, pp. 2–6, 2004. View at Publisher · View at Google Scholar
  14. G. R. Dillip, S. J. Dhoble, L. Manoj, C. Madhukar Reddy, and B. Deva Prasad Raju, “A potential red emitting K4Ca(PO4)2: Eu3+ phosphor for white light emitting diodes,” Journal of Luminescence, vol. 132, no. 11, pp. 3072–3076, 2012. View at Publisher · View at Google Scholar · View at Scopus
  15. C. B. Azevedo, É. A. De Souza, E. H. De Faria et al., “Optical properties of Eu-doped hybrid materials prepared from dimethyl and methyl alkoxides precursors,” Journal of Luminescence, vol. 134, pp. 551–557, 2013. View at Publisher · View at Google Scholar · View at Scopus
  16. Y. G. Su, L. P. Li, and G. S. Li, “Synthesis and optimum luminescence of CaWO4-based red phosphors with codoping of Eu3+ and Na+,” Chemistry of Materials, vol. 20, no. 19, pp. 6060–6067, 2008. View at Publisher · View at Google Scholar
  17. R. J. Wiglusz, T. Grzyb, A. Lukowiak, A. Bednarkiewicz, S. Lis, and W. Strek, “Tuning luminescence properties of Eu3+ doped CaAl2O4 nanophosphores with Na+ co-doping,” Journal of Luminescence, vol. 133, pp. 102–109, 2013. View at Publisher · View at Google Scholar · View at Scopus
  18. N. S. Hussain, G. Hungerford, R. El-Mallawany et al., “Absorption and emission analysis of RE3+(Sm3+ and Dy3+): Lithium boro tellurite glasses,” Journal of Nanoscience and Nanotechnology, vol. 9, no. 6, pp. 3672–3677, 2009. View at Publisher · View at Google Scholar · View at Scopus
  19. M. D. Que, Z. P. Ci, Y. H. Wang, G. Zhu, Y. R. Shi, and S. Y. Xin, “Synthesis and luminescent properties of Ca2La8(GeO4)6O2:RE3+ (RE3+=Eu3+, Tb3+, Dy3+, Sm3+, Tm3+) phosphors,” Journal of Luminescence, vol. 144, pp. 64–68, 2013. View at Google Scholar
  20. A. Tang, D. F. Zhang, and L. Yang, “Photoluminescence characterization of a novel red-emitting phosphor In2(MoO4)3:Eu3+ for white light emitting diodes,” Journal of Luminescence, vol. 132, no. 6, pp. 1489–1492, 2012. View at Google Scholar
  21. S. A. Naidu, S. Boudin, U. V. Varadaraju, and B. Raveau, “Eu3+ and Tb3+ emission in molybdenophosphate Na2Y(MoO4)(PO4),” Journal of the Electrochemical Society, vol. 159, no. 4, pp. J122–J126, 2012. View at Publisher · View at Google Scholar · View at Scopus
  22. X. L. Dong, J. H. Zhang, X. Zhang, Z. D. Hao, and S. Z. Lv, “Synthesis and photoluminescence properties of Eu2+ doped Sr9Sc(PO4)7 phosphors for white light-emitting diodes,” Ceramics International, vol. 40, no. 4, pp. 5421–5423, 2014. View at Publisher · View at Google Scholar
  23. P. Abdul Azeem, M. Kalidasan, R. R. Reddy, and K. Ramagopal, “Spectroscopic investigations on Tb3 doped lead fluoroborate glasses,” Optics Communications, vol. 285, no. 18, pp. 3787–3791, 2012. View at Publisher · View at Google Scholar · View at Scopus
  24. E. Cavalli, P. Boutinaud, R. Mahiou, M. Bettinelli, and P. Dorenbos, “Luminescence dynamics in Tb3+-doped CaWO4 and CaMoO4 crystals,” Inorganic Chemistry, vol. 49, no. 11, pp. 4916–4921, 2010. View at Publisher · View at Google Scholar · View at Scopus
  25. A. Boukhris, M. Hidouri, B. Glorieux, and M. Ben Amara, “Correlation between structure and photoluminescence of the europium doped glaserite-type phosphate Na2SrMg(PO4)2,” Materials Chemistry and Physics, vol. 137, no. 1, pp. 26–33, 2012. View at Publisher · View at Google Scholar · View at Scopus
  26. Y. Zhang, C. H. Lu, L. Y. Sun, Z. Z. Xu, and Y. R. Ni, “Influence of Sm2O3 on the crystallization and luminescence properties of boroaluminosilicate glasses,” Materials Research Bulletin, vol. 44, pp. 179–183, 2009. View at Publisher · View at Google Scholar
  27. M. Sobczyk, P. Starynowicz, R. Lisiecki, and W. Ryba-Romanowski, “Synthesis, optical spectra and radiative properties of Sm2O3:PbO:P2O5 glass materials,” Optical Materials, vol. 30, no. 10, pp. 1571–1575, 2008. View at Publisher · View at Google Scholar · View at Scopus
  28. V. Venkatramu, P. Babu, C. K. Jayasankar, T. Tröster, W. Sievers, and G. Wortmann, “Optical spectroscopy of Sm3+ ions in phosphate and fluorophosphate glasses,” Optical Materials, vol. 29, no. 11, pp. 1429–1439, 2007. View at Publisher · View at Google Scholar · View at Scopus
  29. S. Nishiura, S. Tanabe, K. Fujioka, and Y. Fujimoto, “Properties of transparent Ce:YAG ceramic phosphors for white LED,” Optical Materials, vol. 33, no. 5, pp. 688–691, 2011. View at Publisher · View at Google Scholar · View at Scopus
  30. X. M. Zhang and H. J. Seo, “Luminescence properties of novel Sm3+, Dy3+ doped LaMoBO6 phosphors,” Journal of Alloys and Compounds, vol. 509, pp. 2007–2010, 2011. View at Publisher · View at Google Scholar
  31. A. M. Pires, M. F. Santos, M. R. Davolos, and E. B. Stucchi, “The effect of Eu3+ ion doping concentration in Gd2O3 fine spherical particles,” Journal of Alloys and Compounds, vol. 344, no. 1-2, pp. 276–279, 2002. View at Publisher · View at Google Scholar · View at Scopus
  32. K. Driesen, V. K. Tikhomirov, and C. Gorller-Walrand, “Eu3+ as a probe for rare-earth dopant site structure in nano-glass-ceramics,” Journal of Applied Physics, vol. 102, Article ID 024312, 2007. View at Publisher · View at Google Scholar
  33. C. H. Yan, L. D. Sun, C. S. Liao et al., “Eu3+ ion as fluorescent probe for detecting the surface effect in nanocrystals,” Applied Physics Letters, vol. 82, no. 20, pp. 3511–3513, 2003. View at Publisher · View at Google Scholar
  34. R. Stefani, A. D. Maia, E. E. S. Teotonio, M. A. F. Monteiro, M. C. F. C. Felinto, and H. F. Brito, “Photoluminescent behavior of SrB4O7:RE2+ (RE=Sm and Eu) prepared by Pechini, combustion and ceramic methods,” Journal of Solid State Chemistry, vol. 179, no. 4, pp. 1086–1092, 2006. View at Publisher · View at Google Scholar · View at Scopus
  35. Y. Won, H. Jang, W. Im, D. Jeon, and J. Lee, “Red-emitting LiLa2O2BO3: Sm3+, Eu3+ phosphor for near-ultraviolet light-emitting diodes-based solid-state lighting,” Journal of The Electrochemical Society, vol. 155, no. 9, pp. J226–J229, 2008. View at Publisher · View at Google Scholar
  36. M. Ayvacıklı, A. Ege, and N. Can, “Radioluminescence of SrAl2O 4:Ln3+ (Ln = Eu, Sm, Dy) phosphor ceramic,” Optical Materials, vol. 34, no. 1, pp. 138–142, 2011. View at Google Scholar
  37. Y. M. Yang, Z. Y. Ren, Y. C. Tao, Y. M. Cui, and H. Yang, “Eu3+ emission in SrAl2B2O7 based phosphors,” Current Applied Physics, vol. 9, pp. 618–621, 2009. View at Publisher · View at Google Scholar
  38. D. Tu, Y. J. Liang, R. Liu, Z. Cheng, F. Yang, and W. L. Yang, “Photoluminescent properties of LiSrxBa1−xPO4:RE3+ (RE = Sm3+, Eu3+) f–f transition phosphors,” Journal of Alloys and Compounds, vol. 509, no. 18, pp. 5596–5599, 2011. View at Publisher · View at Google Scholar
  39. J. H. Hao, J. Gao, and M. Cocivera, “Tuning of the blue emission from europium-doped alkaline earth chloroborate thin films activated in air,” Applied Physics Letters, vol. 82, no. 17, pp. 2778–2780, 2003. View at Publisher · View at Google Scholar · View at Scopus
  40. A. E. Henkes and R. E. Schaak, “Synthesis of nanocrystalline REBO3 (RE=Y, Nd, Sm, Eu, Gd, Ho) and YBO3:Eu using a borohydride-based solution precursor route,” Journal of Solid State Chemistry, vol. 181, no. 12, pp. 3264–3268, 2008. View at Publisher · View at Google Scholar · View at Scopus
  41. G. F. Ju, Y. H. Hu, H. Y. Wu et al., “A red-emitting heavy doped phosphor Li6Y(BO3)3:Eu3+ for white light-emitting diodes,” Optical Materials, vol. 33, pp. 1297–1301, 2011. View at Publisher · View at Google Scholar
  42. J. Yang, C. M. Zhang, C. X. Li, Y. G. Yu, and J. Lin, “Energy transfer and tunable luminescence properties of Eu3+ in TbBO3 microspheres via a facile hydrothermal process,” Inorganic Chemistry, vol. 47, no. 16, pp. 7262–7270, 2008. View at Google Scholar
  43. Y. C. Wu, J. G. Liu, P. Z. Fu et al., “A new lanthanum and calcium borate La2CaB10O19,” Chemistry of Materials, vol. 13, no. 3, pp. 753–755, 2001. View at Publisher · View at Google Scholar
  44. H. Lin, D. Hou, L. Li, Y. Tao, and H. Liang, “Luminescence and site occupancies of Eu3+ in La2CaB10O19,” Dalton Transactions, vol. 42, no. 36, pp. 12891–12897, 2013. View at Publisher · View at Google Scholar · View at Scopus
  45. Y. Chen, J. Wang, C. M. Liu, X. J. Kuang, and Q. Su, “A host sensitized reddish-orange Gd2MoO6:Sm3+ phosphor for light emitting diodes,” Applied Physics Letters, vol. 98, Article ID 081917, 2011. View at Publisher · View at Google Scholar
  46. V. Kumar, A. K. Bedyal, S. S. Pitale, O. M. Ntwaeaborwa, and H. C. Swart, “Synthesis, spectral and surface investigation of NaSrBO3: Sm3+ phosphor for full color down conversion in LEDs,” Journal of Alloys and Compounds, vol. 554, pp. 214–220, 2013. View at Publisher · View at Google Scholar · View at Scopus
  47. Y. Zhou and B. Yan, “RE2(MO4)3:Ln3+ (RE = Y, La, Gd, Lu; M = W, Mo; Ln = Eu, Sm, Dy) microcrystals: controlled synthesis, microstructure and tunable luminescence,” CrystEngComm, vol. 15, no. 28, pp. 5694–5702, 2013. View at Publisher · View at Google Scholar · View at Scopus
  48. S. A. Yan, J. W. Wang, Y. S. Chang, W. S. Hwang, and Y. H. Chang, “Synthesis and luminescence properties of Ln3+ (Ln3+ = Er3+, Sm3+)-doped barium lanthanum tungstate BaLa2WO7 phosphors,” Optical Materials, vol. 34, no. 1, pp. 147–151, 2011. View at Publisher · View at Google Scholar
  49. Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” Journal of the American Ceramic Society, vol. 93, no. 5, pp. 1397–1401, 2010. View at Publisher · View at Google Scholar · View at Scopus
  50. F. He, P. Yang, D. Wang et al., “Hydrothermal synthesis, dimension evolution and luminescence properties of tetragonal LaVO4:Ln (Ln = Eu3+, Dy3+, Sm3+) nanocrystals,” Dalton Transactions, vol. 40, no. 41, pp. 11023–11030, 2011. View at Publisher · View at Google Scholar · View at Scopus
  51. G. S. R. Raju, J. Y. Park, H. C. Jung et al., “Excitation induced efficient luminescent properties of nanocrystalline Tb3+/Sm3+:Ca2Gd8Si6O26 phosphors,” Journal of Materials Chemistry, vol. 21, no. 17, pp. 6136–6139, 2011. View at Publisher · View at Google Scholar · View at Scopus
  52. X. Lin, X. S. Qiao, and X. P. Fan, “Synthesis and luminescence properties of a novel red SrMoO4:Sm3+,R+phosphor,” Solid State Sciences, vol. 13, no. 3, pp. 579–583, 2011. View at Publisher · View at Google Scholar · View at Scopus
  53. Z. Yang, Z. Zhao, M. Que, and Y. Wang, “Photoluminescence and thermal stability of β-SiAlON:Re (Re = Sm, Dy) phosphors,” Optical Materials, vol. 35, no. 7, pp. 1348–1351, 2013. View at Publisher · View at Google Scholar · View at Scopus
  54. M. Puchalska and E. Zych, “The effect of charge compensation by means of Na+ ions on the luminescence behavior of Sm3+-doped CaAl4O7 phosphor,” Journal of Luminescence, vol. 132, no. 3, pp. 826–831, 2012. View at Publisher · View at Google Scholar · View at Scopus
  55. G. Lakshminarayana, R. Yang, J. R. Qiu, M. G. Brik, G. A. Kumar, and I. V. Kityk, “White light emission from Sm3+/Tb3+ codoped oxyfluoride aluminosilicate glasses under UV light excitation,” Journal of Physics D: Applied Physics, vol. 42, no. 1, Article ID 015414, 2009. View at Publisher · View at Google Scholar
  56. P. L. Li, Z. J. Wang, Z. P. Yang, Q. L. Guo, and X. Li, “Emission features of LiBaBO3:Sm3+ red phosphor for white LED,” Materials Letters, vol. 63, no. 9-10, pp. 751–753, 2009. View at Publisher · View at Google Scholar
  57. M. N. Huang, Y. Y. Ma, X. Y. Huang, S. Ye, and Q. Y. Zhang, “The luminescence properties of Bi3+ sensitized Gd2MoO6:RE3+ (RE = Eu or Sm) phosphors for solar spectral conversion,” Spectrochimica Acta A, vol. 115, pp. 767–771, 2013. View at Publisher · View at Google Scholar
  58. S. Tang, M. Huang, J. Wang, F. Yu, G. Shang, and J. Wu, “Hydrothermal synthesis and luminescence properties of GdVO 4:Ln3+ (Ln = Eu, Sm, Dy) phosphors,” Journal of Alloys and Compounds, vol. 513, pp. 474–480, 2012. View at Publisher · View at Google Scholar · View at Scopus
  59. N. Zhang, C. Guo, and H. Jing, “Photoluminescence and cathode-luminescence of Eu3+-doped NaLnTiO4 (Ln = Gd and Y) phosphors,” RSC Advances, vol. 3, no. 20, pp. 7495–7502, 2013. View at Publisher · View at Google Scholar · View at Scopus
  60. L. Q. An, J. Zhang, M. Liu, S. Chen, and S. W. Wang, “Preparation and photoluminescence of Sm3+ and Eu3+ doped Lu2O3 phosphor,” Optical Materials, vol. 30, no. 6, pp. 957–960, 2008. View at Publisher · View at Google Scholar
  61. S. C. Prashantha, B. N. Lakshminarasappa, and B. M. Nagabhushana, “Photoluminescence and thermoluminescence studies of Mg2SiO4:Eu3+ nano phosphor,” Journal of Alloys and Compounds, vol. 509, no. 42, pp. 10185–10189, 2011. View at Publisher · View at Google Scholar · View at Scopus
  62. L. Chen, G. T. Yang, J. Q. Liu, X. Shu, G. B. Zhang, and Y. Jiang, “Photoluminescence properties of and in host under vacuum ultraviolet/ultraviolet excitation,” Journal of Applied Physics, vol. 105, no. 1, Article ID 013513, 2009. View at Publisher · View at Google Scholar
  63. A. Dhahri, K. Horchani-Naifer, A. Benedetti, F. Enrichi, and M. Ferid, “Combustion synthesis and photoluminescence of Eu3+ doped LaAlO3 nanophosphors,” Optical Materials, vol. 34, no. 11, pp. 1742–1746, 2012. View at Publisher · View at Google Scholar
  64. S. Mishra, R. Rajeswari, N. Vijayan et al., “Probing the structure, morphology and multifold blue absorption of a new red-emitting nanophosphor for LEDs,” Journal of Materials Chemistry C, vol. 1, no. 37, pp. 5849–5855, 2013. View at Publisher · View at Google Scholar · View at Scopus
  65. W. A. Pisarski, J. Pisarska, G. Dominiak-Dzik, and W. Ryba-Romanowski, “Transition metal (Cr3+) and rare earth (Eu3+, Dy3+) ions used as a spectroscopic probe in compositional-dependent lead borate glasses,” Journal of Alloys and Compounds, vol. 484, no. 1-2, pp. 45–49, 2009. View at Publisher · View at Google Scholar · View at Scopus
  66. L. A. Bueno, A. S. Gouveia-Neto, E. B. da Costa, Y. Messaddeq, and S. J. L. Ribeiro, “Structural and spectroscopic study of oxyfluoride glasses and glass-ceramics using europium ion as a structural probe,” Journal of Physics Condensed Matter, vol. 20, no. 14, Article ID 145201, 2008. View at Publisher · View at Google Scholar · View at Scopus
  67. A. Ellens, F. Zwaschka, F. Kummer, A. Meijerink, M. Raukas, and K. Mishra, “Sm2+ in BAM: fluorescent probe for the number of luminescing sites of Eu2+ in BAM,” Journal of Luminescence, vol. 93, no. 2, pp. 147–153, 2001. View at Publisher · View at Google Scholar · View at Scopus
  68. J. Huang, J. Loriers, and P. Porcher, “Spectroscopic properties of some Eu3+ doped scheelite-related rare earth sesquimolybdates and sesquitungstates,” Journal of Solid State Chemistry, vol. 48, no. 3, pp. 333–345, 1983. View at Google Scholar
  69. M. Karbowiak, A. Mech, A. Bednarkiewicz, and W. Stręk, “Synthesis and properties of solution-processed Eu3+:BaY2F8,” Journal of Luminescence, vol. 114, no. 1, pp. 1–8, 2005. View at Publisher · View at Google Scholar
  70. Y. Tian, B. J. Chen, R. N. Hua et al., “Optical transition, electron-phonon coupling and fluorescent quenching of La2(MoO4)3:Eu3+ phosphor,” Journal of Applied Physics, vol. 109, Article ID 053511, 2011. View at Publisher · View at Google Scholar
  71. M. Dejneka, E. Snitzer, and R. E. Riman, “Blue, green and red fluorescence and energy transfer of Eu3+ in fluoride glasses,” Journal of Luminescence, vol. 65, no. 5, pp. 227–245, 1995. View at Google Scholar · View at Scopus
  72. R. Guo, Y. C. Wu, P. Z. Fu, and F. L. Jing, “Optical transition probabilities of Er3+ ions in La2CaB10O19 crystal,” Chemical Physics Letters, vol. 416, no. 1–3, pp. 133–136, 2005. View at Publisher · View at Google Scholar