Localised Tuneable Composition Single Crystal Silicon-Germanium-on-Insulator for Low Cost Devices

Littlejohns, Callum G.; Dominguez Bucio, Thalia; Nedeljkovic, Milos; Wang, Hong; Mashanovich, Goran Z.; Reed, Graham T.; Gardes, Frederic Y.

doi:https://doi.org/10.1155/2016/4154256

Advances in Materials Science and Engineering

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Abstract Introduction Materials and Methods Results and Discussion Conclusion Acknowledgments References Copyright Related Articles

Research Article | Open Access

Volume 2016 | Article ID 4154256 | https://doi.org/10.1155/2016/4154256

Localised Tuneable Composition Single Crystal Silicon-Germanium-on-Insulator for Low Cost Devices

Callum G. Littlejohns,^1,2Thalia Dominguez Bucio,²Milos Nedeljkovic,²Hong Wang,¹Goran Z. Mashanovich,²Graham T. Reed,²and Frederic Y. Gardes²

Academic Editor: Achim Trampert

Received11 Feb 2016

Revised10 May 2016

Accepted18 May 2016

Published08 Jun 2016

Abstract

The realisation of high quality silicon-germanium-on-insulator (SGOI) is a major goal for the field of silicon photonics because it has the potential to enable extremely low power active devices functioning at the communication wavelengths of 1.3 μm and 1.55 μm. In addition, SGOI has the potential to form faster electronic devices such as BiCMOS transistors and could also form the backbone of a new silicon photonics platform that extends into the mid-IR wavelengths for applications in, amongst others, sensing and telecoms. In this paper, we present a novel method of forming single crystal, defect-free SGOI using a rapid melt growth technique. We use tailored structures to form localised uniform composition SGOI strips, which are suitable for the state-of-the-art device fabrication. This technique could pave the way for the seamless integration of electronic and photonic devices using only a single, low cost Ge deposition step.

1. Introduction

Silicon-germanium () is a well-established material in the photonics and electronics industries. It is fully miscible across its entire composition range, therefore enabling the tuning of properties such as the lattice constant [1] and band gap [2], between those of bulk Ge and bulk Si. SiGe alloys can therefore be either optically transparent or optically absorbing at telecoms wavelengths (1.3 μm and 1.55 μm), depending on its composition. This results in the potential for the fabrication of active optical devices for both modulation [3, 4] and detection [5–7]. Additionally, SiGe also has a higher electron mobility and higher hole mobility relative to Si [8], potentially leading to faster electronic devices such as bipolar complementary metal-oxide semiconductor (BiCMOS) transistors [9, 10]. Tuning of the SiGe lattice constant also enables lattice matching for epitaxial III–V growth [11–13].

Conventional methods of growing SiGe directly on Si include reduced pressure chemical vapour deposition (RPCVD) [14], low energy plasma enhanced chemical vapour deposition (LEPECVD) [15], and molecular beam epitaxy (MBE) [16]. However, due to the 4.2% lattice mismatch between Si and Ge, these methods inevitably introduce high defect densities at the growth interface.

An alternative method of growing SiGe, this time on a localised insulator, is rapid melt growth (RMG). This technique was invented in the 1960s [17] and further developed in the 1970s for the fabrication of LEDs [18], detectors [19], and laser diodes [20]. Originally used for III–V crystal growth, RMG was pioneered by Liu et al. [21] for localised germanium-on-insulator (GOI) growth in 2004. Since then, it has been studied by various groups [22–27] and adapted for silicon-germanium-on-insulator (SGOI) growth [28–37].

A localised SGOI platform paves the way for the monolithic integration of electronic devices with photonic devices on Si substrates, providing a complementary solution to the silicon-on-insulator (SOI) substrates generally used for photonic devices [38]. Process flexibility, CMOS compatibility, and cost are all reasons why the migration of silicon photonic devices to Si substrates is of major interest. The use of dielectric optical waveguides [39], with localised buried SiO₂ layers for optical confinement, can enable such a platform. Alternative techniques for fabricating localised SGOI include Ge condensation [40] and layer transfer using a donor wafer [41].

The RMG technique relies on the fact that Si has a higher melting point than Ge (1414°C and 938°C, resp. [42]). This means that, at temperatures greater than 938°C, the Ge is melted whilst the Si remains solid, maintaining its crystal structure, so that it can act as a template for the recrystallisation of the liquid Ge. Due to the nature of the lateral regrowth upon an insulator, extremely low threading dislocation densities (TDD) can be achieved, potentially leading to improved device characteristics. Additionally, during the melting phase, Si diffuses from the seed into the Ge layer, leading to the formation of SiGe layers from an initial Ge deposition. This deposition is noncritical since it will subsequently be melted to initiate regrowth. Therefore, fabrication complexity is significantly reduced, since the initial Ge deposition does not need to be modified to achieve a different SiGe composition and can be performed using any low cost technique.

However, until now, this RMG technique has resulted in graded SiGe composition profiles or only very high Ge composition uniform areas. In this paper, we firstly describe the RMG fabrication process and subsequently present a novel method for realising uniform composition, tuneable localised SGOI layers, demonstrating a large range of SiGe compositions.

2. Materials and Methods

Fabrication was carried out on 6-inch (100) Si wafers. Firstly, a 50 nm insulating layer is deposited using plasma enhanced chemical vapour deposition (PECVD), upon which the lateral regrowth occurs. Alternatively, a layer can be used. The layer thickness can also be varied to satisfy the design requirements. This layer was subsequently densified in a rapid thermal annealer (RTA) to reduce the amount of trapped hydrogen in the film. This prevents outgassing during subsequent annealing steps, which could lead to void formation in the SiGe as it recrystallises. Seed areas are then formed into this insulating layer using a dilute (20 : 1) HF wet etch in order to expose the underlying Si, which acts as a template for the SiGe recrystallisation process. Next, nonselective 400 nm Ge growth was performed by PECVD using GeH₄ (10%) diluted in (2.5 sccm) and (100 sccm), at a temperature of 250°C. More details of this Ge growth can be found in [36]. Prior to Ge growth, an HF dip was performed to remove the native layer formed on the Si surface and also to terminate the dangling bonds at the Si surface with H, preventing the formation of a native during transfer to the Ge growth chamber. This HF last approach eliminates the need for a high temperature prebake (to remove the native ) prior to epitaxial Ge growth [45]. Figure 1 shows a cross section scanning electron microscope (SEM) image at the seed edge after the Ge growth, confirming nonselective growth.

The Ge was then inductively coupled plasma (ICP) etched into the desired structures, ensuring that one end of the Ge pattern overlapped with the Si seed area. A 1 μm layer was then deposited by PECVD to encapsulate the Ge structures to contain the liquid Ge during subsequent melting in an RTA. In this melting step, the temperature of the RTA was stabilised at approximately 500°C, before ramping up to the peak temperature at a rate of approximately 100°C/s. The temperature was held at its peak for 1 second, before cooling naturally (i.e., switching off the RTA lamps).

2.1. Regrowth Mechanism

When the temperature is raised above the melting point of Ge, Si diffusion from the seed is greatly enhanced [46], leading to the formation of a SiGe liquid. Upon cooling, regrowth is then initiated at the Si seed, firstly because the substrate acts as a heat sink and secondly because the slightly higher Si composition in the seed area results in solidification at a slightly higher temperature, as defined by the SiGe phase diagram shown in Figure 2. Epitaxial regrowth then propagates laterally along the SiGe structure. It has been shown that all threading dislocations are confined to the seed area by a defect necking mechanism, as shown in [36].

2.2. Material Characterisation

The SiGe material has been characterised using 532 nm Raman spectroscopy to determine its composition. Raman spectroscopy is a nondestructive, microscale technique, which does not require any sample preparation, and is commonly used for this type of analysis [23, 47–49]. A 50x objective lens was used, resulting in a laser spot size of approximately 0.5 μm. The data gathered by this technique relates to the near-surface information only because a laser of this wavelength has a penetration depth of several tens of nanometers in high Ge percentage SiGe (depending on the composition [50]). It is therefore possible that there is a nonuniform vertical distribution of Ge. However, this is predicted to be negligible [33], especially in areas away from the seed, since the epitaxial regrowth front propagates laterally.

Lateral scans were performed along each structure, resulting in a series of Raman spectra, each of which can be analysed to determine the SiGe composition at that point. Two characteristic peaks can be seen in each spectrum: the first at a wavenumber between 280 cm⁻¹ and 300 cm⁻¹, corresponding to the GeGe mode vibrations, and the second at a wavenumber between 390 cm⁻¹ and 410 cm⁻¹, corresponding to the SiGe mode vibrations. The wavenumber of each mode depends on the composition of the measured material, which therefore enables the composition to be determined using the peak location [48, 51]. Shin et al. [51] showed that the unstrained GeGe Raman peak location, , can be calculated by where is the Ge concentration. However, this type of measurement is complicated by the fact that the peak location also depends on strain [52–54]. In fact, an in-plane strain of 1% will induce a peak shift of approximately 3.85 cm⁻¹ [52]. Nevertheless, as proposed by Mooney et al. [47] (2), the composition can be determined using the relative intensities of the SiGe and GeGe peaks, independently of the strain:where and are the integrated intensities of the SiGe and GeGe modes, respectively, is the Ge concentration, and , which is dependent on the excitation wavelength, is an experimental setup specific constant that can be determined from samples of known composition. Using this particular setup, was determined to be 1.2.

3. Results and Discussion

3.1. Composition Profiles of Straight Strips

After RMG was performed, the encapsulating was removed in 20 : 1 HF acid to enable SEM viewing of the SiGe structures. Figure 3 shows an array of strip widths, each with a length of 200 μm.

From this image, it is evident that there is a maximum strip width, above which RMG becomes unstable. Closer inspection reveals the maximum width to be approximately 5 μm, using the fabrication process described above. The liquid SiGe agglomerates at widths greater than 5 μm, possibly due to the high interface energy between SiO₂ and SiGe [25], resulting in dewetting of the SiO₂ surface when the SiGe is in the liquid phase. Agglomeration is suppressed at strip widths less than 5 μm, so only strips with a width of 5 μm or less are investigated in detail.

Figure 4(a) shows the composition profile as a function of distance from the Si seed for a variety of strip lengths. The annealing temperature of the SiGe has been estimated from the SiGe phase diagram to be 1008°C, based on the lowest observed Ge composition.

(a)

(b)

From Figure 4(a), it can be observed that the composition varies in the straight strips, from lower Ge composition at the seed to 100% Ge at the distal end of the strip. The composition profile is independent of length (for this range of lengths), which can be seen in Figure 4(b), where the strip length has been normalised by dividing each point by the total length of each respective strip. This graded composition profile is a result of the large separation between the solidus and liquidus curves of the SiGe phase diagram (Figure 2), which therefore results in preferential Si rich solid formation at the regrowth front, with rejection of Ge into the liquid. The complete mixing model [33], based on analysis originally carried out by Scheil [55], has been added to each curve and is described in the following.

3.2. Segregation Coefficient

The segregation coefficient, , of a SiGe alloy defines the degree of segregation between Ge and Si. It is defined as the ratio of the Ge solid composition, , to the Ge liquid composition, , at any particular temperature: can be calculated from the SiGe phase diagram, as shown in Figure 5(a). This is then plotted as a function of the solid Ge composition in Figure 5(b).

(a)

(b)

As the Ge composition approaches 100% Ge, the segregation coefficient approaches unity. On the contrary, as the Ge composition decreases, there is a higher degree of segregation. A simple linear fit has been applied between Ge compositions of 0.4 and 1.0, leading to (4) for the segregation coefficient as a function of the Ge solid composition, :In this paper, no Ge compositions lower than 0.4 have been measured, therefore deeming this approximation valid.

3.3. Scheil Equation

The simplest model of binary alloy solidification is possibly the Scheil equation [55]:where is the fraction of the strip that has solidified and is the average Ge composition in the liquid at the point when solidification commences. The Scheil equation makes 3 assumptions:(1)There is complete mixing of Ge and Si in the melt, resulting in a uniform composition.(2)There is no diffusion in the solid.(3) is constant. This is only valid if the phase diagram is simplified to become straight lines, which is approximately true for small composition ranges.

The segregation coefficient (3) determines the solid composition to commence at , since the liquid is at a uniform composition of . The fact that the Scheil equation assumes complete mixing in the melt means that it is only accurate when the regrowth front propagation speed is slow, therefore providing enough time for the rejected Ge at the regrowth front to fully diffuse into the melt.

3.4. Complete Mixing Model

A more complete version of the Scheil equation is the complete mixing model [33]. This model does not assume a constant value of . Assumptions (1) and (2) (listed above) still remain valid. In this paper, the simplified linear equation for the segregation coefficient (4) has been used.

To derive the complete mixing model, we must consider a small progression of the regrowth front, as shown in Figure 6.

Here, the solid line shows the composition profile at any given point in time, with the solid composition on the left-hand side and the liquid composition on the right-hand side. The dashed line shows the composition profile after a small progression of the regrowth front, . Ge is rejected from the solid into the liquid at the regrowth front. Therefore, conservation of mass enables equating the amount of Ge in the two hashed areas:The segregation coefficient, , can then be used to replace . Rearranging (4) givesSubstituting (7) into (6) and integrating both sides result in where is the solid composition at the edge of the seed. This is the complete mixing model, valid for Ge compositions between 0.4 and 1.0. The full derivation of the complete mixing model can be found in Appendix D of [56]. This equation is also only valid when the regrowth front propagation speed is low because of the assumption that the melt has a uniform composition (i.e., complete mixing of the rejected Ge into the melt). In addition, this equation is also valid when the distance left to solidify is low (i.e., a few microns), since complete mixing can still occur.

Figure 4 shows that the complete mixing model is a close match to the measured data, suggesting that, for straight strips of these lengths (<100 μm), the regrowth front propagation speed is slow enough to enable complete mixing of the rejected Ge into the melt.

However, for the fabrication of the state-of-the-art devices using this material, it is essential to form uniform composition areas of SGOI. This can be achieved by steady-state solidification, whereby Ge diffusion into the melt is dramatically reduced by increasing the regrowth front propagation speed.

3.5. Steady-State Solidification

In steady-state solidification, there is limited Ge diffusion into the melt. When the regrowth front propagation speed is nonnegligible, this is a more accurate model than both the Scheil equation and the complete mixing model. Here, diffusion of the rejected Ge at the regrowth front is balanced by the propagation of the regrowth front, therefore resulting in a uniform composition profile. Diffusion of Ge is given by Fick’s second law:Also,where is the regrowth front propagation speed, is the diffusivity of Ge in liquid SiGe, and is the length in the liquid with a nonuniform composition. This equation assumes a constant regrowth propagation speed. These equations combine to give This is a second-order differential equation. Therefore, the solution is of the following form:The first- and second-order differentials of this equation areSubstituting these two equations into (11) gives (note the change in sign since Ge diffusion and regrowth are in the same direction)which simplifies toSubstituting this into the general solution of a second-order differential equation results in The boundary conditions for this equation are when and when . Substituting the boundary conditions into (16) results inAnd, therefore,Substituting these back into (16),which becomesThis is the steady-state equation for alloy solidification, which is detailed in Figure 7.

In steady-state solidification, the regrowth front propagation speed is faster than that in the complete mixing model. Therefore, as the Ge is rejected from the solid at the regrowth front, there is insufficient time for it to fully diffuse into the bulk melt. This results in an initial build-up of a Ge “bow” (Figure 7(a)) at the regrowth front as solidification commences, followed by a steady-state period once the solid Ge composition reaches (Figure 7(b)). At this point, the propagating regrowth front effectively sees the same Ge composition in the melt directly ahead of it, independent of the distance from the seed, and therefore a uniform composition is achieved. However, at the distal end of the structure, when becomes small, completed diffusion is realised and the composition profile follows the complete mixing model.

Steady-state solidification composition profiles can be predicted using the University of Cambridge website “Dissemination of IT for the Promotion of Materials Science” [44] simulation software. Figure 8 shows the predicted composition profile as the regrowth front propagation speed is increased from Figures 8(a)–8(c).

These simulations demonstrate that increasing the regrowth front propagation speed results in a flatter composition profile because the diffusion of the rejected Ge into the melt at the regrowth front is balanced by the propagation of the regrowth front itself.

It is therefore necessary to maximise the regrowth front propagation speed to achieve a uniform composition profile. This can be realised by maximising the cooling rate of the SiGe structures after melting [57]. This cannot be accomplished by altering the RTA cooling process since the lamps are already switched off immediately after heating. Therefore, it is necessary to increase the cooling rate by other means.

3.6. SiGe Composition Profiles of Tailored Structures

In order to realise a uniform SiGe composition, a tailored tree-like structure was designed, as shown in Figure 9. Branches were added to the main central strip, which act as radiating elements with the purpose of increasing the cooling rate and therefore the regrowth front propagation speed of the structure.

The composition profile of the complete tree-like structure is shown in Figure 10.

(a)

(b)

Figure 10 shows that a uniform composition has been achieved in the central strip of a tree-like structure, when the central strip width is 3 μm. Only the uniform composition area (first 56 μm, corresponding to 7 out of 8 sets of branches) has been shown. After the first 56 μm (penultimate set of branches), the cooling effects of the branches are reduced, and the length of strip left to solidify becomes small, resulting in a nonuniform SiGe composition profile. Each branch exhibits a graded composition profile, suggesting that the central strip solidifies first and then subsequently acts as a seed for the regrowth of the branches.

Figure 11 compares the composition profile of the central strip of a tree-like structure with a straight strip with the same dimensions.

(a)

(b)

Figure 11

Comparison of SiGe composition profiles of the central strip of a tailored tree-like structure and a straight strip. (a) Graph and (b) schematic. The final set of branches have been omitted from the central strip of the tailored tree-like structure to display only the uniform composition region. The straight strip data has been normalised from Figure 4 to match the length of the tailored tree-like structure. The complete mixing model has been fitted to the straight strip data [33]. A linear fit has been added to the tailored tree-like structure data.

3.7. SiGe Composition Tuning by Annealing Temperature

It is desirable to be able to tune the SiGe composition in the central strip, without the need to alter the initial Ge growth conditions, so that this RMG technique can be used for a whole range of device designs. This can be achieved simply by modifying the annealing temperature, according to the phase diagram, as shown in Figure 12.

(a)

(b)

Figure 12

SiGe composition tuning by varying the RMG annealing temperature. (a) Composition profiles in the central strips of tailored tree-like structures annealed at a range of temperatures. A linear fit has been added to each data set and (b) average Ge composition along the central strip of a tailored tree-like structure as a function of annealing temperature. Only the uniform region up to 56 μm has been considered. The error bars show the maximum and minimum values observed along each strip. = 3 μm, = 65 μm, = 20 μm, = 5 μm, and = 3 μm.

Figure 12(a) shows that a uniform composition is realised for all the demonstrated annealing temperatures. A higher annealing temperature results in greater Si diffusion into the structure before solidification commences and therefore leads to a lower Ge composition upon solidification. This is demonstrated in Figure 12(b), where the average Ge composition in the central strip of the tree-like structures has been plotted as a function of annealing temperature.

3.8. Material Quality Analysis

Transmission electron microscopy (TEM) has been performed to image a cross section of the central strip of a SiGe tree-like structure. Figure 13 confirms single crystal, defect-free SGOI fabrication using this RMG method.

Electron backscatter diffraction (EBSD) measurements were also performed to measure the crystal orientation of the RMG SiGe. Figure 14 shows a pole figure of an area approximately 3 μm × 3 μm. The observed data confirms single crystal (001) orientated SiGe, matching the crystal orientation of the Si substrate, as expected.

A more detailed material quality analysis can be found in [36].

4. Conclusion

In conclusion, the rapid melt growth technique described here presents a fabrication process for producing localised single crystal SiGe layers of uniform composition, suitable for the state-of-the-art device fabrication. This method enables the simple tuning of the SiGe composition, without the need to alter the initial growth conditions, and uses low cost, readily available CMOS fabrication tools. It offers the potential for the migration of silicon photonics to bulk Si substrates, enabling the coexistence of SiGe photonic and electronic devices on the same chip.

Competing Interests

The authors declare that they have no competing interests.

Acknowledgments

The research leading to these results was funded by the UK Engineering and Physical Sciences Research Council (EPSRC) under the grant “HERMES” and is also supported by the National Research Foundation of Singapore (NRF-CRP12-2013-04). The fabrication was carried out at the Southampton Nano Centre, University of Southampton, UK. The data in this paper can be accessed at 10.5258/SOTON/393034.

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Copyright © 2016 Callum G. Littlejohns et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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