Compositional Changes for Reduction of Polymerisation-Induced Shrinkage in Holographic Photopolymers

<div>Schematic diagram showing reorientation of fringes in a transmission grating as a result of shrinkage.<svg height="11.927pt" id="M11" style="vertical-align:-3.291101pt" version="1.1" viewbox="-0.0498162 -8.6359 15.6677 11.927" width="15.6677pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,4.358,0)"><path d="M411 648L381 663L349 596C321 620 285 635 241 635C89 635 35 457 35 312C35 217 55 118 102 56L63 -24L92 -43L128 29C157 3 194 -12 240 -12C390 -12 443 166 443 312C443 406 424 507 374 569L411 648ZM141 132C126 185 119 247 119 312C119 465 149 601 239 601C278 601 305 577 321 542L141 132ZM338 497C355 434 360 373 360 312C360 159 329 21 240 21C202 21 174 47 157 85L338 497Z" id="g113-25"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="480" vert-adv-y="480"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,10.598,3.132)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="487" vert-adv-y="487"></glyph.data></g></svg> and <svg height="11.8174pt" id="M12" style="vertical-align:-3.1815pt" version="1.1" viewbox="-0.0498162 -8.6359 15.6677 11.8174" width="15.6677pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M411 648L381 663L349 596C321 620 285 635 241 635C89 635 35 457 35 312C35 217 55 118 102 56L63 -24L92 -43L128 29C157 3 194 -12 240 -12C390 -12 443 166 443 312C443 406 424 507 374 569L411 648ZM141 132C126 185 119 247 119 312C119 465 149 601 239 601C278 601 305 577 321 542L141 132ZM338 497C355 434 360 373 360 312C360 159 329 21 240 21C202 21 174 47 157 85L338 497Z" id="g113-25"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="480" vert-adv-y="480"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,6.24,3.132)"><path d="M389 0V32C297 38 291 46 291 118V635C234 613 175 595 109 583V556L161 554C203 552 207 547 207 497V118C207 46 201 38 110 32V0H389Z" id="g50-50"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="487" vert-adv-y="487"></glyph.data></g></svg>are the initial and final slant angles.</div>

Advances in Materials Science and Engineering

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Figure 1

Figure 1: Compositional Changes for Reduction of Polymerisation-Induced Shrinkage in Holographic Photopolymers 