Advances in Materials Science and Engineering

Advances in Materials Science and Engineering / 2017 / Article

Research Article | Open Access

Volume 2017 |Article ID 1953087 | https://doi.org/10.1155/2017/1953087

E. Tiaya Mbou, E. Njeugna, A. Kemajou, N. R. Tagne Sikame, D. Ndapeu, "Modelling of the Water Absorption Kinetics and Determination of the Water Diffusion Coefficient in the Pith of Raffia vinifera of Bandjoun, Cameroon", Advances in Materials Science and Engineering, vol. 2017, Article ID 1953087, 12 pages, 2017. https://doi.org/10.1155/2017/1953087

Modelling of the Water Absorption Kinetics and Determination of the Water Diffusion Coefficient in the Pith of Raffia vinifera of Bandjoun, Cameroon

Academic Editor: Belal F. Yousif
Received02 Aug 2016
Accepted14 Dec 2016
Published13 Feb 2017

Abstract

The present work focuses on the study of the water absorption phenomenon through the pith of Raffia vinifera along the stem. The water absorption kinetics was studied experimentally by the gravimetric method with the discontinuous control of the sampling mass at temperature of 30°C. The samples of 70 mm × 8 mm × 4 mm were taken from twelve sampling zones of the stem of Raffia vinifera. The result shows that the percentage of water absorption of the pith of Raffia vinifera increases from the periphery to the center in the radial position and from the base to the leaves in the longitudinal position. Fick’s second law was adopted for the study of the water diffusion. Eleven models were tested for the modelling of the water absorption kinetics and the model of Sikame Tagne (2014) is the optimal model. The diffusion coefficients of two stages were determined by the solution of the Fick equation in the twelve sampling zones described by Sikame Tagne et al. (2014). The diffusion coefficients decreased from the center to the periphery in the radial position and from the base to the leaves in the longitudinal position.

1. Introduction

The raffia is a plant which is found in the tropical zones particularly in Madagascar and which is generally grown in the swampy zone [1, 2]. In the world, there are about twenty (20) species among which the Raffia vinifera is found in the West, the Northwest, the South, the Center and the East Regions of Cameroon. This raffia is constituted with a feather grass bearing stick with stout rachis and large petiole [2, 3].

Raffia is generally used in the realization of arts, crafts, decoration, braces, clothes, baskets, hats, beds, and food (sap/wine) [1, 4]. Raffia is also used in the West Region of Cameroon as a building material specially as ceiling material, but this use is still local. Our main objective is to extend the use of raffia as ceiling material over the world particularly in our country. The pith of raffia will be combined with another material, such as polymer and other vegetal material, to produce a new composite building material suitable for ceiling applications. The physical behavior of our pith of Raffia vinifera has to be known because the realization of the composite material will use the matrix, which is liquid and will be absorbed by our pith of raffia. It is important in our study to know the water diffusion coefficient and the percentage of the water absorption that will help us to predict the behavior of the composite material.

Several works have been carried out on the raffia such as the study of the thermal properties on trunk of Raffia hookeri which is used as ceiling material [5]. Some studies are also carried out on the study and the use of raffia and other vegetal products as insulation material in Cameroon [6]. Other works include the use of raffia in the reinforcement of concrete [7]. The use of raffia in the textile industry is equally growing. Studies are also carried out on the study of the microstructure and the physical properties of fibers coming from the leaves of raffia; the drying kinetics of these fibers is carried in view of its use as roofing elements [8, 9]. Mechanical studies have been carried out on the long-term creep behavior of the Raffia vinifera stem in compression and flexion tests [1013]. A study on the long-term mechanical behavior and the mechanical properties of fibers from the Raffia vinifera has been done [4]. Studies have been equally done on the traction and compression of composite cement matrix reinforcement by the raffia fiber [14].

In the same vein and in the view of improving the scientific knowledge so as to optimize the use of Raffia vinifera, this study focuses on the study of the water absorption phenomenon in the Raffia vinifera pith. The main objective of this work is to evaluate the percentage of the water absorbed, do the modelling of the water absorption kinetics, and evaluate the diffusion coefficient of water through the pith of Raffia vinifera.

In this article, we analyzed the distribution of water absorption rate of our material through the stem of raffia respectively on the sampling zones described by Sikame Tagne et al. [4]. The modelling of the water absorption kinetics is also taken in place. The diffusion coefficient of water through the material was evaluated in the sampling zones and followed by the conclusion.

2. Methods

2.1. Materials

The samples used in this work come from the stem of Raffia vinifera originating from Bandjoun in the West Region of Cameroon particularly the Koung-Khi division. In the stem, prismatic samples are cut particularly on the parallelepiped shape with 70 mm × 8 mm × 4 mm . The largest dimension of the sample is along the length of the stem. The samples were taken from the twelve sampling zones described by Sikame Tagne et al. [4] and presented in Figure 1. In the stem, we distinguished four parts (Figure 1(a)) from the bottom to the top named P1/4 (near the root), P2/4, P3/4, and P4/4 (near the leaves). In the radial position, we distinguished three zones (Figure 1(b)) called center, half-radius, and periphery (near the bark) zones.

A microwave of Bosch mark was used as oven for the drying of the sample at a constant temperature until the mass is stabilized. Digital scales of ADAM mark with a maximum weight of 750 g and to the milligram accuracy level are used for the various weighing. A numerical slide caliper with the hundredth of the millimeter accuracy is used for the measurement of the sample dimensions. The distilled water at the ambient temperature of is used for the immersion of the samples as in the case of the absorption of other types of wood such as Afra, Ojamlesh, and Roosi [1, 16, 17, 28].

2.2. Methods

The section of the stem of raffia has an elliptic form. The large diameter of the raffia stem is about 62 mm on the base, 40 mm on the middle, and 34 mm on the top. The small diameter of the raffia stem is about 51 mm on the base, 36 mm on the middle, and 29 mm on the top. After subdivision of the stem in four parts named P1/4, P2/4, P3/4, and P4/4, we removed the bark of each part. According to each longitudinal position, the remaining diameter was divided into three parts to obtain primary samples following radial position (center, half-radius, and periphery zones). On this primary samples, we extracted the final samples which have a parallelepiped shape with the following dimensions 70 mm × 8 mm × 4 mm. The samples were extracted in the twelve sampling zones on the stem.

The obtained samples are now conditioned in the microwave used as the oven at the constant temperature of 90°C until stabilization of the mass. This gravimetric analysis method is done in order to eliminate residual water found in the samples. The samples were then introduced in plastic bags to avoid reabsorption of moisture from the air during the samples cooling period. Conditioned samples are weighed and labeled before being introduced into the distilled water. After the drying phase, we introduced our samples in the distilled water at the laboratory room temperature estimated at . The samples are maintained under water by nuts made of rustproof steel. During the regular time intervals, samples were removed from the water; surface water of the sample was then eliminated with a dry fabric base on cotton and the samples were weighted and reintroduced into the distilled water. This operation was done in very short time so as to enable us to neglect the time that was spent out of the distilled water. At the beginning of the test, immersion time is taken at five minutes. After one hour of test, we changed it to ten minutes. We prolonged the weight time until we arrive at weight one time per day, one time after two days, three days, and eventually one time per week. The process of weighting is repeated until the constant mass, that is, until samples reach water saturation level [16, 2932].

In each sampling zone, twenty (20) samples were tested for a total of two hundred and forty (240) samples of Raffia vinifera along the stem. These samples were extracted from two dry mature stems of Raffia vinifera for each zone. These samples were mixed and tested in the group. The test was stopped when the mass no longer varies.

The statistical analysis of experimental data was done in the Matlab 2009b software environment which enabled drawing experimental curves and doing the modelling with different models as found in Table 4. The best model was the one which has an average correlation coefficient near to the unit, the square root of mean error average near zero, and the sum of square error average near zero. These two last statistical parameters are defined by the following [1, 26]: where , , and are the theoretical mass, the predicted mass, and the number of observation, respectively.

2.2.1. Mass Diffusion Theory through Solid

The mass transfer equation of solid result from the second Fick law given bywhere is the molar concentration , is the diffusion coefficient , and is the time .

To simplify the resolution of (2), it is supposed that the diffusion coefficient is independent of the space direction [33, 34]. This hypothesis enables us to write (2) in the following form:

It is assumed that the sample is the plane shape and it is assumed to have a single long direction, the direction in Figure 2(b), so that the diffusion equation can be solved in one dimension across the shortest dimension of the sample. In our case, the direction is the one on which diffusion has taken place. Figure 2 presents the samples obtained for the test (Figure 2(a)) and the plan which presents the dimensions of the sample (Figures 2(b) and 2(c)). These hypotheses enabled the reduction of (3) which then gives [29, 33, 34]

By taking into account the boundary’s conditions, we havewhere is the thickness of the sample.

The solution of (4) can be given in the following form:

If we call the total mass of water which diffuses in the material at instant and , the same quantity at the infinite time, that is to say, when the saturation of the material is reached, then [23, 25, 29, 35] (6) can be written in the following form:

2.2.2. Percentage of Water Absorption

The percentage of water absorption of our sample (WA) is given by the following relation, which was also used for the determination of the water absorption by [15, 16, 36]where and are, respectively, the final and initial mass of the sample.

2.2.3. Study of the Absorption Kinetics

The ratio of the water absorption called is defined as follows:The similarity between (7) and (9) enables us to writewhere , , and are, respectively, the anhydrous mass (at the initial instant), at current moment and at the infinite time , that is, at saturation.

3. Results and Discussions

3.1. Determination of the Percentage of Water Absorption

The percentage of water absorption of our samples for the twelve sampling zones is done by (8). The synthesis result is presented in Table 1.


CenterHalf-radiusPeriphery

Part 1/4
Part 2/4
Part 3/4
Part 4/4

It is observed that the average percentage of water absorption stands between and during the immersion period estimated at 45 days.

A comparative study of the percentage of the water absorption of the Raffia vinifera pith and other vegetal products has been done, in Table 2. This study indicates that the Raffia vinifera pith absorbs more water than the fibers taken in the same position of the stem [4]. This is probably due to the fact that the samples of pith of Raffia vinifera are the natural composites materials comprising fibers and a spongy part that work as a natural binder between the fibers and which in addition absorbs water.


TypesPercentage of water absorbed (%)Absorption durationTemperature (°C)References

Afra wood10225 Days25 [16]
Ojamlesh Wood54
Roosi Wood120

Hemp6213 Days27–67 [17]
Okra64
Betel nut38

Fibers of Raffia vinifera303–66225 Days23[4]

Pith of the Raffia vinifera392–133145 Days30 ± 1Studied case

The average of the percentage of water absorption along the stem is presented on Figure 3. Globally the observation of Figure 3 enables us to see that the percentage of water absorption increases from the periphery to the center on the radial position and from the base to the leaves on the longitudinal position along the stem of Raffia vinifera.

3.2. Kinetics of Water Absorption

Equation (9) allows us to plot the curve of water absorption ratio according to the time and the obtained curve is presented by Figure 4. This curve presents the results of water absorption test of the pith of Raffia vinifera taken from the center of part 4/4.

The obtained curves on the twelve sampling zones have the same profile as that presented in Figure 4.

An observation of the curve presented in Figure 4 shows that, during the first 5000 minutes, approximately 50% of the sample masses reached saturation level.

The curve presented in Figure 4 is similar to the curve obtained by other authors who have studied water absorption kinetics in natural materials [4, 16, 26, 27, 34, 37]. It was noticed that the water absorption kinetics of the pith of Raffia vinifera takes place in two phases: the first phase rapidly takes place and enables reaching approximately 50% of the mass at saturation. This is done in the first 5000 minutes and the second phase that is relatively slow and is represented by the second part of the curve. This brings out two diffusion coefficients which indicate the velocity of the water diffusion in the pith of Raffia vinifera samples.

3.3. Modelling of the Water Absorption Kinetics

The water absorption kinetics in the pith of Raffia vinifera is done by using the mathematical models found in the literature. In this fact, we found eleven models which are in Table 3.


NumberModel’s nameModel’s equation References

1Pilosof[18]
2Mohsenin[16, 19]
3Singh[20]
4Peleg[21, 22]
5García-Pascual[23]
6Gowen[24]
7Czel and Czigany[25]
8Vega-Gálvez[26]
9Gornicki[27]
10Gornicki[27]
11Sikame Tagne[4]


Model’s nameRadial positionRMSESSE

PelegCenter
Half-radius
Periphery

PilosofCenter
Half-radius
Periphery

SinghCenter
Half-radius
Periphery

WitrowaCenter
Half-radius
Periphery

GowenCenter
Half-radius
Periphery

WesolowskiCenter
Half-radius1.465 × 104
Periphery1.827 × 104

MohseninCenter1.629 × 104
Half-radius2.429 × 1051.638 × 104
Periphery3.894 × 1063.505 × 104

WeibullCenter
Half-radius
Periphery

Czel and CziganyCenter
Half-radius
Periphery

Vega-GálvezCenter
Half-radius
Periphery

Sikame TagneCenter