Multilayers Polyethylene Film for Crop Protection in Harsh Climatic Conditions

Dehbi, A.; Youssef, B.; Chappey, C.; Mourad, A.-H. I.; Picuno, P.; Statuto, D.

doi:https://doi.org/10.1155/2017/4205862

Advances in Materials Science and Engineering

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Research Article | Open Access

Volume 2017 | Article ID 4205862 | https://doi.org/10.1155/2017/4205862

Multilayers Polyethylene Film for Crop Protection in Harsh Climatic Conditions

A. Dehbi,¹B. Youssef,²C. Chappey,²A.-H. I. Mourad,³P. Picuno,⁴and D. Statuto⁴

Academic Editor: Gianluca Cicala

Received07 Dec 2016

Accepted10 Jan 2017

Published30 Jan 2017

Abstract

In this work the performance and durability of a new generation of greenhouse covers, in which the cover is composed of five layers, are investigated. A sand wind ageing was performed under different exposure conditions. Surface morphology and chemical, physical, and thermal characteristics were investigated by using optical microscopy, FTIR, and tensile test techniques. In addition, the mechanical integrity of the five-layer film was assessed. The analysis indicated that the sand wind treatments have a significant influence only on the performance of the film. An attempt has been done to compare the properties of the five-layer film with the monolayer and trilayer films with or without air bubble under similar conditions. The results revealed that the five-layer film proved to be a promising greenhouse covering film.

1. Introduction

The growing use of plastics in agriculture results in increased yield, earlier or delayed harvest, less reliance on herbicides and pesticides, better protection of food products, and more efficient water conservation [1–3]. According to most recent estimation [4–6], the annual consumption in the world of plastic material in the agricultural sector is approximately 5 million tons (about 2% of the total plastic production), and it seems to be steadily growing.

The protection of crops from hail, wind, snow, or strong rainfall in horticulture, together with the realization of a confined space with controlled microclimatic conditions, is the most common case. Plastic films are widely diffused for covering greenhouses, low and medium tunnels, and soil mulching (Figure 1). In greenhouse, the plastic cover is used to maintain favourable conditions of temperature, solar radiation, gas composition (O₂, CO₂, and N₂), and humidity in order to allow optimal photosynthesis, respiration, and growth of the plants.

Low-density polyethylene (LDPE) is one of the plastic materials most widely used as greenhouse cover [7–12]. In spite of the low cost of these polymeric materials, the economic advantages of plasticulture can be seriously damaged by extreme climatic factors, which decrease the lifetime of the plastic cover [13–18]. Despite the continuous efforts made by plastic producers [19, 20], this important characteristic is actually limited from four to five seasons in Europe and in US and from two to three seasons in Saharan environment [21, 22]. The specific working conditions, that is, climatic parameters (air temperature, solar radiation, humidity, temperature of the contacting metallic frame, etc.) as well as other local actions (e.g., mechanical constraints, sand wind, contact with agrochemicals and pesticides, etc.), could indeed considerably modify some important technical properties like mechanical strength, radiometric properties, and gas permeability of the exposed plastic films [23–25]. Moreover, these effects promote the degradation of the polymeric film in its environment, resulting in an important residual pollution [18, 26, 27].

Various researchers were interested in the long-term behaviour of these plastic covers. Guenachi et al. [28, 29] studied the effect of a sand wind simulation on a LDPE monolayer film, keeping it for 4 hours at 40°C. They showed that this creates on the exposed surface a very thin layer of material inlaid with particles of sand. Dehbi et al. [21] reported that the durability of the material depends on its capacity to resist the erosion. Recently, Djakhdane et al. [30] have studied the impact of sand wind, temperature, and exposure time on trilayer polyethylene film. They have illustrated that the exposure to temperature and sand wind have severe degradable effects on the mechanical and radiometric characteristics of the film. The solar transmission of the film and its mechanical properties have reduced significantly due to exposure to sand wind and temperature.

The greenhouse covers are generally made up of monolayer films of LDPE having 200 μm thickness. Due to the ageing and to the variation of their radiometric and mechanical properties, trilayer films [31–34] — typically with 220 μm thickness made of LDPE, and poly(vinyl acetate) (PVA) with air bubbles entrapped in the middle layer — were developed (PROSYN-POLYAN). Due to the air bubble in the middle layer, this film is more efficient in maintaining the temperature in the greenhouse. However, trilayer films based on LDPE, produced by Agrofilm SA (Algeria) without air bubbles, showed better mechanical properties when compared to the monolayer LDPE film [35].

Recently, an innovative five-layer film for greenhouse was produced by Ginegar Plastic Products Ltd. From the literature survey, the present study could appear to be the first one about the five-layer LDPE film as a greenhouse covering. On the other side, no research was carried out concerning the gas permeation of multilayer greenhouse films. These points motivated the present work, in which the surface morphology and gases (O₂and CO₂) permeability behaviour of a five-layer film subjected to Saharan environment simulated conditions was considered. The film was exposed to sand wind for 8 hours at a temperature of 40°C, as well as for 1000 hours at a temperature of 40°C, and to UVA radiation conditions too. Since O₂and CO₂play a significant role for the growth of the plants, it is very important to have a systematic study on the permeability nature of these films. The properties of the five-layer films were then finally compared with those of the monolayer and trilayer films (with or without air bubbles) used as greenhouse covering under similar environmental conditions.

2. Material and Methods

2.1. Materials

The greenhouse covering film used for this study was supplied by Ginegar Plastic Product Ltd. with the trade name Sun Selector™/SunTherm 4. This film, obtained by using extrusion technique with a thickness of 200 μm, consists of five layers: two external polyethylene (PE) layers and a central poly(vinyl acetate) (PVAc) layer with two intermediate layers containing adhesives to ensure the cohesion between PE and PVAc. This intermediate layer containing adhesives consists of various additives such as anticondensation, anti-UV, antiparasite, antivirus, antidust, and antidrops.

In this study, the tests were conducted on the following films:(a)Five-layer virgin film(b)Five-layer film after artificial ageing for 1000 hours at 40°C(c)Five-layer film after artificial ageing for 1000 hours under UVA radiation at 40°C(d)Five-layer film after artificial sand wind simulation for 8 hours at 40°C

2.2. Methods

A laboratory equipment/set-up, specifically designed and constructed for the artificial ageing, was described in our earlier studies [34, 35]. This equipment was composed of a thermostatic tube, a sand wind chamber, and a control keyboard. From an air turbine, the flux was heated up to the targeted experimental temperature ( = 40°C), under a pressure of 100 kNm⁻², inside the thermostatic tube. This dry air was introduced in the sand wind chamber where natural sand particles were deposited. A Brownian movement of the sand particles resulted, striking randomly the polymer surface. A 30 Watts lamp was placed 20 cm away above the samples.

The surfaces of the films tested were examined before and after sand wind ageing by using a Leica DMLM microscope, Japan.

Fourier transform infrared (FTIR) spectroscopic analysis was recorded in total reflection on a Nicolet Avatar 360 instrument equipped with a germanium crystal. 128 scans were accumulated with a resolution of 4 cm⁻¹for each spectrum. IR spectra present absorbance from 3000 to 600 cm⁻¹. The calculations were made for the various samples after standardization, according to a reference peak. The peak at 2920 cm⁻¹ is chosen as reference because it remains identical for all the samples.

Tensile tests of films were carried out using a universal testing machine (Instron model 4301, France). The tests were performed using a 5 kN load cell at a cross head speed of 2 mm/min. The tensile modulus was obtained from the tangent at the origin of the stress-elongation curve according to the AFNOR NF T54-102 [36]. The results obtained represent an average value calculated from five samples.

3. Results and Discussion

3.1. Optical Microscopy

Figure 2 shows the images obtained by the optical microscope for the trilayer and five-layer films, virgin (i.e., case (a), as in Section 2.1) and after exposition to sand wind for 8 hours at a temperature of 40°C (i.e., case (d), as in Section 2.1). The microphotographs obtained by using the incident light technique at the same lighting conditions show clearly the produced damage on the surface of the two films due to the impact of the sand particles. The effect of sand wind on the five-layer film surface is negligible compared to the trilayer film. The influence of abrasions may be recognized by cavities or the dark areas in the images. These abrasion mark sizes were increased with exposure time. While in the case of the a trilayer sample [16], after 8 hours of exposure to sand wind, the sand particles have been observed to cover completely the surface and the cavities — to the extent that the percentage of visible light transmission was almost zero — the damage effect was much less for the five-layer film sample here tested. Because of the presence of air bubbles in the trilayer film, significant destruction occurs on the film surface. These results are in coherence with those reported in a similar research [30].

3.2. FTIR Analysis

In Figure 3 the FTIR spectra of the surface of the five-layer film are reported in correspondence of the different above-mentioned exposure conditions (a–d).

Figure 3(a) presents the initial film spectrum in which the characteristic bands of polyethylene are highlighted: CH₂ stretching vibrations (2920 and 2850 cm⁻¹), CH₂ deformation vibrations (1470 cm⁻¹), and CH₂ skeleton vibrations (720 cm⁻¹) [37, 38]. All these bands are present in the FTIR spectra of the aged samples (Figures 3(b), 3(c), and 3d) and grow with exposure time and become sharper.

Figure 3(b) presents the peaks of a film sample kept artificially aged at 40°C for 1000 hrs exposure time. As ageing continued, new peaks appeared between 650 and 1750 cm⁻¹specifically at 1650 cm⁻¹, 1390 cm⁻¹, and 1029 cm⁻¹ that correspond to oxygenated groups and those at 1540 cm⁻¹and 1450 cm⁻¹which correspond to the absorption band of vibrations of CH₂-O group [32] or C=C double bonds. The spectra indicate that the intensity of the peaks increases as a function of time. A peak at 1740 cm⁻¹, which corresponds to the formation of ester groups [39], is observed in Figure 3(b) (40°C + 1000 hrs) and Figure 3(d) (40°C + 8 hrs sand wind).

Figure 3(c) shows the FTIR spectra for the samples artificially exposed to UVA and 40°C temperature for 1000 hrs. It is observed that all peaks of Figure 3(a) are present while, in addition, new peaks appear between 650 cm⁻¹ and 1750 cm⁻¹, similar as in Figures 3(b) and 3(d). The intensity of the peaks increased significantly compared to the samples kept at 40°C. It is noticed that the peak observed in Figures 3(b) and 3(d) at 1740 cm⁻¹ for the samples kept at 40°C for 8 hrs and 1000 hrs were not seen here.

After exposing the film to sand wind for 8 hrs, the same bands of absorptions of ageing in temperature appear, in addition to more two bands at 875 cm⁻¹and 1110 cm⁻¹ (Figure 3(d)) which corresponds to the vibration of Si groups. More details are presented by Adam et al. [31] and Djakhdane et al. [30, 35]. A peak at 1740 cm⁻¹ has been also noticed (Figures 3(b) and 3(d)) which corresponds to the formation of ester groups for samples exposed to sand wind at 40°C for 8 hrs of sand wind and for 1000 hrs. Thus, the various bands of absorption observed after the different ageing conditions show that the surface of film suffered some chemical modifications such as cross-linking, unsaturation, and oxidation. Moreover, the chemical modifications observed for the samples exposed for 8 hours to sand wind and 1000 hrs at 40°C (i.e., case (b), as in Section 2.1) are almost similar. A comparison of the FTIR peaks of trilayer [16, 30] with that of five-layer shows that both of them have similar peaks, but the intensity of peak is more for the trilayer film. This is due to the structure of the five-layer film and its additives, which are effective in resisting the sand wind deteriorative impact.

The variation of peak at 1715 cm⁻¹, which represents the bands of vibration of the carbonyl groups, and the peak at 1550 cm⁻¹and 1415 cm⁻¹, which corresponds to the presence of CH₂-O and/or C=C functions, are due to the breaking and branching of double bonds of the polymeric material under different ageing conditions. Under the action of the radiation and/or heat, the formation of radicals occurs on the film surface, which leads to the reactions of reticulation of chains, reactions with oxygen in air, and reactions of scission of chains [40, 41].

The peak at 1740 cm⁻¹ found for the samples kept at 40°C for 8 hrs and 1000 hours (i.e., case (b), as in Section 2.1), which diminished for samples exposed to UVA (i.e., case (c), as in Section 2.1), indicates that the degradation mechanism is different for the UVA/temperature from that unexposed film to UVA.

3.3. Mechanical Behaviour Characterization

Figure 4 presents the mechanical stress-strain curves of the five-layer and trilayer films, virgin (i.e., case (a), as in Section 2.1) and after exposition to sand wind for 8 hrs at 40°C (i.e., case (d), as in Section 2.1).

The polyethylene is considered as a ductile polymer. We can see that the stress at failure of the aged film is lower if compared to virgin film. This phenomenon can be attributed to the cross-linking, a chemical reaction induced by temperature and effect of sand wind leading to the formation of covalent bridges between the nearby segments of a polymer chain. Considering the mechanical properties, this process usually leads to an increase of the Young modulus [42] in the elastic phase. From this, we can deduce that there was an effective cross-linking after exposure to sand wind at 40°C.

For comparison the values of the elastic modulus and percent elongation of the mono-, tri- [27, 29, 31], and five-layer films before and after the sand wind treatment are shown in Table 1. After the sand wind treatment a slight increase in the elastic modulus and a decrease in the elongation at break are observed. With regard to the monolayer film, the multilayer films have higher elastic modulus certainly due to the presence of PVAc as central layer. The elongation at break is higher for the five-layer than for the three-layer and monolayer films. The five-layer material is thus more flexible than the three-layer and monolayer films, even after exposure to a sand wind.

4. Conclusions

The effect of ageing under three different conditions on five-layer LDPE greenhouse covering film has been studied by using several physic-chemical characterization methods. Optical images show distinctly that the deterioration on the surface of the trilayers is more severe when compared to five-layer film and the deteriorative effects grow with time of exposure. The FTIR spectra and free surface energy calculated using contact angle method indicated that all the three test conditions modified the film surface due to cross-linking, oxidation, and chain scission reactions. In FTIR a band vibration of Si groups appeared after exposure to sand wind. The mechanical tests showed a slight increase in the elastic modulus and a decrease in the elongation at break after ageing. This is attributed to the chains cross-linking. Due to the deterioration of the superficial layers of the material, the gas permeability flow increased slightly through the aged films. It can be concluded that the surface properties of the films were more affected by the ageing conditions, and the properties of the five-layer film are much better when compared to mono- or trilayer films after exposure.

Since the formulation of a plastic film for greenhouse covering is currently based on chemical considerations about the composition of the polymer and its additives, whereas the technical aspects about the performance of this material during its working life are usually poorly or totally not considered during their design and engineering phase, further experimental analysis should be conducted. The limited life of agricultural plastic films, even if they are produced with considerable quantities of appropriate additives, would indeed be enhanced thanks to new more efficient customized formulations, performed also with the support of suitable equations able to predict their useful lifetime on the basis of the main meteorological characteristics of the area where this material will be exposed and the operative conditions (contact with pesticides/agrochemicals, external pollution, contact with structural frames, etc.).

Competing Interests

The authors declare that they have no competing interests.

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Copyright © 2017 A. Dehbi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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