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A Study on the Fundamental Quality of Magnesia-Phosphate-Formed Mortar Composites Using Superabsorbent Polymer for Development of Concrete for Biological Panel
The purpose of this study was to investigate the base material of the biological panel as one of the researches for developing the biological panel using (micro)organisms. In order to select the base material for the biological panel, the applicability of the magnesia-potassium-phosphate-foamed mortar composites material using the superabsorbent polymer was evaluated through the evaluation of basic quality and characteristics. Experiments were conducted to evaluate the fluidity, compressive strength, pH, roughness (porosity distribution), and moisture retention (absorbency) of the magnesia-phosphate-foamed mortar composites according to the additional amount of the superabsorbent polymer. Experimental results showed that the addition of a suitable superabsorbent polymer can provide good results in terms of compressive strength, workability, and moisturizing properties (absorbency). As a result, it can be used as a basic quality study data of the biological panel design.
Due to the rapid industrial revolutions around the world and indiscriminate urban development, there is a series of serious environmental problem such as increase of CO2 emissions, fine dust generation, and increase of cooling energy use due to reduction of the green area [1, 2]. In order to solve this problem, various researches and efforts have been carried out both domestically and externally in order to develop ecofriendly construction materials. However, most of them have been focused on waste resource utilization, carbon abatement type, and environmentally friendly concrete technology [3–10]. These technologies can solve the problem of CO2 reduction, but it is difficult to take alternative measures to heat island phenomenon and increase of cooling energy use due to increase of city’s atmospheric temperature.
In order to compensate for this, there is a way to solve the problem by installing a vertical garden inside and outside the building, but it is difficult to integrate with the exterior wall of the structure. In addition, complex support structures and expensive maintenance and installation costs increase about three times as compared to the common garden of the same area, making it difficult to commercialize them economically . Although there are sponge, mat type, block type, and lightweight soil, similar to the vertical garden, there are many durability problems [12–17].
To solve this problem, biological panels can be developed and integrated with the structure. Biological panels should be easy to put on (biology), etc., and environment should be created so that it can survive after it is rooted. However, when cement is used as a material for panel fabrication, it forms a high pH, which makes it unsuitable for survival and maintenance of living (micro)organisms . In addition, smooth or dense surface makes it difficult to attach (micro)organisms, and similarly problems arise with nutrients and water supply for (micro)organisms .
As one of the basic studies for the development of biological panels, it was investigated whether the magnesia-phosphate-foamed mortar composites used the superabsorbent polymer. Unlike conventional cement, magnesium-phosphate composites can form neutral pH . In addition, air bubbles can form pores on the surface and inside the matrix, and adsorption of nutrients in the air through the pores can be beneficial for the growth of living (micro)organisms .
In addition to these, porous surfaces are important, and their supply to moisture also plays a very important role in the growth of living (micro)organisms. In order to achieve such a purpose, the superabsorbent polymer can be applied. The superabsorbent polymer can absorb more than several times its own mass of moisture, and the absorbed moisture gradually dries. When the superabsorbent polymer is applied to the biological panel, the moisture retention of the panel can be improved.
Accordingly, even in a dry environment, the absorbed moisture of the superabsorbent polymer can be utilized for the purpose of moisture supply of (micro)organisms .
Therefore, in this study, a magnesium-phosphate-potassium-formed mortar composites using a superabsorbent polymer was prepared as a parent material of the biological panel, and basic quality characteristics and biological characteristics were examined. The results of this study are used to reflect the quality of the biological panel design.
2. Experiment Outline
2.1. Experimental Materials
2.1.1. Magnesia-Potassium-Phosphate Cement Mortar Composites
The magnesia cement used in this experiment was dead magnesia (MgO, hereinafter referred to as “M”) with a density of 3.6 g/m3 fired at a high temperature of 1,500°C or more. As a curing agent which reacts with dead magnesia, potassium monophosphate (KH2PO4, hereinafter referred to as “P”) having a purity of 99% or more and a density of 2.34 g/m3 was used. In addition, boric acid (H3BO3, hereinafter referred to as “R”) was used as a retarding agent in consideration of its workability, and silicate no. 8 (hereinafter referred to as “S”) of 95% or more of SiO2 was used as an fine aggregate. Magnesia cement requires a retarder for workability due to fast curing time. And since it is made of a dense ceramic structure, it exhibits high strength of about 40 MPa in a short time.
Table 1 shows the chemical composition and physical properties of materials used in the experiment.
2.1.2. Foaming Agent
The foaming agent used in this experiment was sodium bicarbonate (NaHCO3, hereinafter referred to as “F”) which reacted with potassium ions and reacted with acid ions to generate bubbles. F is a suitable foaming agent that combines with ions generated by an acid-base neutralization reaction to generate a gas, and the chemical reaction formula can be expressed as follows:
The bubbles created through this bond create a rough surface through the voids inside and outside the mortar, which facilitates the absorption and storage of water and the adsorption of nutrients in the atmosphere .
2.1.3. Superabsorbent Polymers (SAP)
The superabsorbent polymer used in this study was an acrylic acid polymer, sodium salt (sodium polyacrylate). The superabsorbent polymer is a white powder which is capable of absorbing water several hundred times its own weight. When the water is absorbed, the volume expands and reaches gel state. The swelling characteristics of such a superabsorbent polymer vary depending on the interparticle density, the chemical structure of the superabsorbent polymer, the pH of the absorbed liquid, the temperature, and the ion concentration.
2.1.4. Experimental Plan
In this study, first, data were collected for magnesium-phosphate-formed mortar composites (SMPFC) using the superabsorbent polymer. Through preliminary experiments, the data of more than 10 MPa of the target strength were obtained by using the water/binder ratio (W/B) 30%, MgO : KH2PO4 ratio (P : M) 1 : 0.5, fine aggregate volume/total mortar volume ratio (Vs/Vm) 10%, retardation 3%, and foaming agent 0.5%. Therefore, 4 levels (0.25, 0.5, 0.75, and 1.0%) were prepared for data acquisition according to SAP addition. In addition, the flow characteristics, compressive strength, pH, roughness, and moisture retentivity were measured. The bubbles were applied in the postfoaming mode. The compressive strength was set to 10 MPa or more in terms of landscaping design at 6 hours, 1 day, 3 days, and 7 days of age in accordance with the characteristics of magnesia cement. Table 2 shows the mixing ratio of SMPFC used in the experiment.
2.2. Experimental Method
2.2.1. Mixing of SMPFC
The SMPFC was subjected to dry mixing with M, P, R, and SAP for about 2 minutes. Then, the blend was then mixed with the compounding water for 2 minutes at the low speed and then for 3 minutes at the high speed. Thereafter, additional water containing F was added, and the mixture was further mixed at the high speed for one minute.
2.2.2. Extra Water (eW) Decision
SAP rapidly absorbs moisture when exposed to moisture. Also, the amount of absorbed water increases with time. For this reason, the unit water quantity sharply decreases, the fluidity decreases, and the workability decreases. In addition, magnesia cement requires a large amount of unit water, unlike ordinary cement. This problem can be solved by adding additional water .
Previous studies have shown that SAP exhibits maximum absorption after 10 minutes of contact with water and is shaped like a gel . Therefore, additional water should be added before reaching maximum absorption.
As a result of the preliminary test, it was found that, to achieve the target slump, extra water should add about 6% of the unit water when the SAP is increased by 0.25%.
The flow of SMPFC was measured in accordance with the “KS L 5105 Hydraulic Cement Mortar Compressive Strength Test Method”.
2.2.4. Compressive Strength
The compressive strength of SMPFC was cubic-type specimens of 50 mm × 50 mm × 50 mm prepared according to “KS L 5105 Compressive Strength Test Method of Hydraulic Cement Mortar,” followed by curing. Afterwards, the sample was demolded, and the compressive strength was measured by universal testing (UTM) at each age.
The pH of SMPFC was measured in accordance with KS M 0011 “Method for measuring pH of aqueous solution.” Also, the pH of SMPFC was measured according to age.
2.2.6. Surface Roughness
The roughness measurement of SMPFC was measured by relative comparison with the surface of the bubble-free reference specimen. Roughness is an important factor in the application of biological panels because it is one of the indicators to induce adsorption on the surface of rainwater or nutrients in the air.
2.2.7. Moisturizing Property
The moisture retention (moisture content) of SMPFC was measured by wetting curing of the specimen for one day according to KS F 2459 “Test method of apparent density, water content, water absorption, and compressive strength of foam concrete”. Thereafter, the mass of the dried sample in the drying furnace was measured.
3. Experimental Results and Discussion
Figure 1 shows the flow measurement result according to the addition amount of SAP of SMPFC. As a result of the experiment, the flow value decreased by about 10% every time the SAP addition amount was increased by 0.25% without determining the additional extra water (eW). The cause of this phenomenon is considered to be the property of absorbing moisture of SAP. However, if eW is added as shown in Figure 2, the target flow can be satisfied.
3.2. Compressive Strength
Figures 3–6 show the results of compressive strength measurement according to the additional amount of SAP of SMPFC, and the results of the compressive strength test at 6 hours, 1 day, 3 days, and 7 days of age are shown. The compressive strength at 6 hours did not achieve the target strength in all cases. Also, the compressive strength at 1 and 3 days was more than 10 MPa for plain. A mix with SAP that could achieve the target intensity was possible after 7 days. The compressive strength of SAP 0.25% at 7 days was above 12 MPa and decreased proportionally with increasing SAP. The compressive strength of SAP 0.5% was about 8 MPa, and the compressive strength of SAP 0.75 and 1.0% was less than 5 MPa lower than the target strength. Overall, as the amount of SAP increased, the compressive strength decreased, and the specimen with 1.0% SAP was easily destroyed. However, when the addition amount of SAP was 0.25%, similar results were obtained. Therefore, if the optimum amount of SAP is to be found, it will be possible to control the strength when applying the biological panel.
Figure 7 shows the pH measurement results of SMPFC at 6 hours, 1 day, 3 days, and 7 days. As a result of the experiment, the pH of the specimen tended to increase with age. Magnesia cement was measured at pH 7–9 depending on the type of the phosphate used in the formulation. The SAP used in the experiment was a material with a pH of 6.5 and showed no significant effect on the pH change of SMPFC. The pH at 7 days was measured as 9. Since the matrix for biological panels is important for the survival of (micro)organisms, it is necessary to examine the pH. From these results, SMPFC, which is a neutral region, would be a favorable condition for the survival environment of (micro)organisms.
3.4. Surface Roughness
Figure 8 shows the result of measuring the surface roughness of the SMPFC. It found that the pore depths of the 0.25% are in the range of 1.0–0.005 mm and the pore depths of the 0.5% SAP additions are in 0.1 mm. And pores visible by the naked eye were observed from the micropores.
In the case of 0.75% and 1.0% of SAP additions, SAP was observed on the surface because the amount of SAP added was too large. In addition, it was confirmed that the effect of the foaming agent was hardly observed. The reason for this is that a considerable amount of SAP absorbs moisture quickly and suppresses bubble generation. Figure 9 shows the distribution of voids on the surface of the bubbled test piece. These results suggest that SMPFC with a rough surface due to bubbles will be an advantageous growth condition of (micro)organisms and will be advantageous for the adsorption of nutrients in the air.
3.5. Moisturizing Property
Figures 10–14 show the measurement results of moisture content (moisture content) according to the addition amount of SAP of SMPFC. The test roughly evaluated the amount of moisture absorbed by the test piece and SAP through the pores generated on the inside and the surface of the test piece. A qualitative evaluation was performed on the assumption that the larger the pores, the more the SAP could contain in the pores and absorb a large amount of water. The weight of the dried specimen was measured first, and then, the weight of the specimen immersed in water for one day was measured. Then, the period of reaching the dry weight at room temperature was measured.
As shown in Figures 10–14, the moisture retention of SMPFC-P was about 10% larger than that of dry weight. And SMPFC-0.25 was 5% higher than SMPFC-P. As the SAP increased by 0.25%, it increased continuously by about 5%. These results show that the amount of SAP added affects the moisture retention, and the sample without SAP showed a drying time about 3 days faster than the sample with SAP added. As the amount of SAP increased, the drying time at room temperature tended to increase by 2 to 3 days compared to that of SMPFC-P. In the case of the sample with 1.0% SAP content, the complete drying time was about 9 to 10 days. These results suggest that when applied as a matrix for biological panels, the addition of SAP improves the moisture retention and absorbs moisture in the air, which may have a positive effect on the growth of the organism. However, when the amount of SAP increases, it will decrease in compressive strength and durability. Therefore, the optimal amount of SAP should be reviewed. Figure 15 shows the SAP that absorbed moisture inside the test.
These results suggest that SMPEC with improved moisture retention by SAP may contribute to the water supply of (micro)organisms to some extent. In addition, it is considered that the moisturizing effect in the atmospheric moisture or rainy weather will be further increased.
As one of the basic studies for the development of biological panels, it is investigated that the magnesia-phosphate-foamed mortar composites using the superabsorbent polymer. The following conclusions were obtained:(1)The magnesia-potassium-phosphate-foamed mortar composites using a superabsorbent polymer were able to satisfy the target flow when extra water was added according to the mixing ratio of the superabsorbent polymer.(2)The magnesia-potassium-phosphate-foamed mortar composites using a superabsorbent polymer showed a tendency to decrease in compressive strength depending on the mixing ratio of the superabsorbent polymer. The mixing ratio of the superabsorbent polymer satisfying the target strength was found to be within 0.25%.(3)The magnesia-potassium-phosphate-foamed mortar composites using a superabsorbent polymer showed a tendency to increase in water content according to the mixing ratio of the superabsorbent polymer. It also formed a roughened surface by bubbles.
From these results, it was confirmed that the optimum range of the superabsorbent polymer satisfying the target strength was 0.25%. In addition, the rough surface by the foaming agent and the moisture retention by a superabsorbent polymer will be beneficial to rooting and growth conditions of (micro)organisms. As a sequential study, studies on biological acceptability and the growth of (micro)organisms should be accompanied.
The data used to support the findings of this study are available from the corresponding author upon request.
Conflicts of Interest
The authors declare that there are no conflicts of interest regarding the publication of this paper.
This research was supported by a grant (17CTAP-C114646-02) from Construction Technology Research Program funded by Ministry of Land, Infrastructure and Transport of Korean government.
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