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Advances in Materials Science and Engineering
Volume 2018, Article ID 3016304, 11 pages
https://doi.org/10.1155/2018/3016304
Research Article

Effect of Molybdenum on the Corrosion Behavior of High-Entropy Alloys CoCrFeNi2 and CoCrFeNi2Mo0.25 under Sodium Chloride Aqueous Conditions

1National Energy Technology Laboratory, 1450 Queen Ave. SW, Albany, OR 97321, USA
2ORISE, Oak Ridge, TN, USA
3U.S. Department of Energy, Washington, DC, USA
4AECOM, Los Angeles, CA, USA

Correspondence should be addressed to Joseph H. Tylczak; vog.eod.lten@kazclyt.hpesoj

Received 30 September 2017; Revised 14 December 2017; Accepted 21 January 2018; Published 20 March 2018

Academic Editor: Alicia E. Ares

Copyright © 2018 Alvaro A. Rodriguez et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. M. C. Gao, C. Zhang, P. Gao et al., “Thermodynamics of concentrated solid solution alloys,” Current Opinion in Solid State and Materials Science, vol. 21, no. 5, pp. 238–251, 2017, in press. View at Publisher · View at Google Scholar · View at Scopus
  2. G. R. Holcomb, J. Tylczak, and C. Carney, “Oxidation of CoCrFeMnNi high entropy alloys,” Journal of the Minerals, Metals & Materials Society (JOM), vol. 67, no. 10, pp. 2326–2339, 2015. View at Publisher · View at Google Scholar · View at Scopus
  3. P. D. Jablonski, J. J. Licavoli, M. C. Gao, and J. A. Hawk, “Manufacturing of high entropy alloys,” Journal of The Minerals, Metals & Materials Society (JOM), vol. 67, no. 10, pp. 2278–2287, 2015. View at Publisher · View at Google Scholar · View at Scopus
  4. M. C. Gao, J.-W. Yeh, P. K. Liaw, and Y. Zhang, High-Entropy Alloys: Fundamentals and Applications, Springer, Cham, Switzerland, 2016.
  5. D. Miracle, J. Miller, O. Senkov, C. Woodward, M. Uchic, and J. Tiley, “Exploration and development of high entropy alloys for structural applications,” Entropy, vol. 16, no. 1, pp. 494–525, 2014. View at Publisher · View at Google Scholar · View at Scopus
  6. M.-H. Tsai and J.-W. Yeh, “High-entropy alloys: a critical review,” Materials Research Letters, vol. 2, no. 3, pp. 107–123, 2014. View at Publisher · View at Google Scholar · View at Scopus
  7. Y. Y. Chen, U. T. Hong, H. C. Shih, J. W. Yeh, and T. Duval, “Electrochemical kinetics of the high entropy alloys in aqueous environments—a comparison with type 304 stainless steel,” Corrosion Science, vol. 47, no. 11, pp. 2679–2699, 2005. View at Publisher · View at Google Scholar · View at Scopus
  8. Y. Y. Chen, T. Duval, U. D. Hung, J. W. Yeh, and H. C. Shih, “Microstructure and electrochemical properties of high entropy alloys—a comparison with type-304 stainless steel,” Corrosion Science, vol. 47, no. 9, pp. 2257–2279, 2005. View at Publisher · View at Google Scholar · View at Scopus
  9. Y.-J. Hsu, W.-C. Chiang, and J.-K. Wu, “Corrosion behavior of FeCoNiCrCux high-entropy alloys in 3.5% sodium chloride solution,” Materials Chemistry and Physics, vol. 92, no. 1, pp. 112–117, 2005. View at Publisher · View at Google Scholar · View at Scopus
  10. H. C. Shih, C. P. Lee, Y. Y. Chen, C. H. Wu, C. Y. Hsu, and J. W. Yeh, “Effect of boron on the corrosion properties of Al0.5CoCrCuFeNiBx high entropy alloys in 1N sulfuric acid,” ECS Transactions, vol. 2, no. 26, pp. 15–33, 2007. View at Google Scholar
  11. C.-Y. Hsu, J.-W. Yeh, S.-K. Chen, and T.-T. Shun, “Wear resistance and high-temperature compression strength of Fcc CuCoNiCrAl0.5Fe alloy with boron addition,” Metallurgical and Materials Transactions A, vol. 35, no. 5, pp. 1465–1469, 2004. View at Publisher · View at Google Scholar
  12. C. P. Lee, C. C. Chang, Y. Y. Chen, J. W. Yeh, and H. C. Shih, “Effect of the aluminium content of AlxCrFe1.5MnNi0.5 high-entropy alloys on the corrosion behaviour in aqueous environments,” Corrosion Science, vol. 50, no. 7, pp. 2053–2060, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. C. P. Lee, Y. Y. Chen, C. Y. Hsu, J. W. Yeh, and H. C. Shih, “Enhancing pitting corrosion resistance of AlxCrFe1.5MnNi0.5 high-entropy alloys by anodic treatment in sulfuric acid,” Thin Solid Films, vol. 517, no. 3, pp. 1301–1305, 2008. View at Publisher · View at Google Scholar · View at Scopus
  14. Y. L. Chou, Y. C. Wang, J. W. Yeh, and H. C. Shih, “Pitting corrosion of the high-entropy alloy Co1.5CrFeNi1.5Ti0.5Mo0.1 in chloride-containing sulphate solutions,” Corrosion Science, vol. 52, no. 10, pp. 3481–3491, 2010. View at Publisher · View at Google Scholar · View at Scopus
  15. Y. L. Chou, J. W. Yeh, and H. C. Shih, “Effect of inhibitors on the critical pitting temperature of the high-entropy alloy Co1.5CrFeNi1.5Ti0.5Mo0.1,” Journal of the Electrochemical Society, vol. 158, no. 8, pp. C246–C251, 2011. View at Publisher · View at Google Scholar · View at Scopus
  16. Y. L. Chou, J. W. Yeh, and H. C. Shih, “The effect of molybdenum on the corrosion behaviour of the high-entropy alloys Co1.5CrFeNi1.5Ti0.5Mox in aqueous environments,” Corrosion Science, vol. 52, no. 8, pp. 2571–2581, 2010. View at Publisher · View at Google Scholar · View at Scopus
  17. C.-M. Lin and H.-L. Tsai, “Evolution of microstructure, hardness, and corrosion properties of high-entropy Al0.5CoCrFeNi alloy,” Intermetallics, vol. 19, no. 3, pp. 288–294, 2011. View at Publisher · View at Google Scholar · View at Scopus
  18. Y.-F. Kao, T.-D. Lee, S.-K. Chen, and Y.-S. Chang, “Electrochemical passive properties of AlxCoCrFeNi (x = 0, 0.25, 0.50, 1.00) alloys in sulfuric acids,” Corrosion Science, vol. 52, no. 3, pp. 1026–1034, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. Ö. N. Doğan, B. C. Nielsen, and J. A. Hawk, “Elevated-temperature corrosion of CoCrCuFeNiAl0.5Bx high-entropy alloys in simulated syngas containing H2S,” Oxidation of Metals, vol. 80, no. 1, pp. 177–190, 2013. View at Publisher · View at Google Scholar · View at Scopus
  20. Z. Tang, L. Huang, W. He, and K. P. Liaw, “Alloying and processing effects on the aqueous corrosion behavior of high-entropy alloys,” Entropy, vol. 16, no. 12, pp. 895–911, 2014. View at Publisher · View at Google Scholar · View at Scopus
  21. J. Li, X. Yang, R. Zhu, and Y. Zhang, “Corrosion and serration behaviors of TiZr0.5NbCr0.5VxMoy high entropy alloys in aqueous environments,” Metals, vol. 4, no. 4, pp. 597–608, 2014. View at Publisher · View at Google Scholar
  22. E. J. Pickering and N. G. Jones, “High-entropy alloys: a critical assessment of their founding principles and future prospects,” International Materials Reviews, vol. 61, no. 3, pp. 183–202, 2016. View at Publisher · View at Google Scholar · View at Scopus
  23. Y. Shi, B. Yang, and K. P. Liaw, “Corrosion-resistant high-entropy alloys: a review,” Metals, vol. 7, no. 2, p. 43, 2017. View at Publisher · View at Google Scholar · View at Scopus
  24. Y. F. Ye, Q. Wang, J. Lu, C. T. Liu, and Y. Yang, “High-entropy alloy: challenges and prospects,” Materials Today, vol. 19, no. 6, pp. 349–362, 2016. View at Publisher · View at Google Scholar · View at Scopus
  25. J.-W. Yeh, “Alloy design strategies and future trends in high-entropy alloys,” Journal of The Minerals, Metals & Materials Society (Jom), vol. 65, no. 12, pp. 1759–1771, 2013. View at Publisher · View at Google Scholar · View at Scopus
  26. Y. Zhang, T. T. Zuo, Z. Tang et al., “Microstructures and properties of high-entropy alloys,” Progress in Materials Science, vol. 61, pp. 1–93, 2014. View at Publisher · View at Google Scholar · View at Scopus
  27. D. B. Miracle and O. N. Senkov, “A critical review of high entropy alloys and related concepts,” Acta Materialia, vol. 122, pp. 448–511, 2017. View at Publisher · View at Google Scholar · View at Scopus
  28. InfoMine, “Mining markets and investment,” 2017, , http://www.infomine.com/investment/. View at Google Scholar
  29. M. Gao and D. Alman, “Searching for next single-phase high-entropy alloy compositions,” Entropy, vol. 15, no. 10, pp. 4504–4519, 2013. View at Publisher · View at Google Scholar
  30. B.-R. Chen, A.-C. Yeh, and J.-W. Yeh, “Effect of one-step recrystallization on the grain boundary evolution of CoCrFeMnNi high entropy alloy and its subsystems,” Scientific Reports, vol. 6, no. 1, p. 22306, 2016. View at Publisher · View at Google Scholar · View at Scopus
  31. Thermo-Calc Software.
  32. M. Detrois and P. D. Jablonski, “Trace element control in binary Ni-25cr and ternary Ni-30co-30cr master alloy castings,” 2017. View at Google Scholar
  33. P. D. Jablonski, M. Cretu, and J. Nauman, “Considerations for the operation of a small scale ESR furnace,” in Proceedings of the Liquid Metal Processing & Casting Conference, pp. 157–162, Philadelphia, PA, USA, 2017.
  34. P. D. Jablonski and J. A. Hawk, “Homogenizing advanced alloys: thermodynamic and kinetic simulations followed by experimental results,” Journal of Materials Engineering and Performance, vol. 26, no. 1, pp. 4–13, 2017. View at Publisher · View at Google Scholar · View at Scopus
  35. ASTM, Standard Practice for Microetching Metals and Alloys, ASTM International, West Conshohocken, PA, USA, 2015.
  36. K. D. Ralston and N. Birbilis, “Effect of grain size on corrosion: a review,” Corrosion, vol. 66, no. 7, pp. 075005–075005-13, 2010. View at Publisher · View at Google Scholar · View at Scopus
  37. P. Crook, in Corrosion of Nickel and Nickel-Base Alloys, vol. 13, ASM Handbook, Corrosion: Materials, ASM International, Materials Park, OH, USA, 2004.
  38. J. R. Davis, ASM Specialty Handbook: Stainless Steels, ASM International, Materials Park, OH, USA, 1994.
  39. J. Sedriks, Corrosion of Stainless Steels, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2nd edition, 1996.
  40. M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions, NACE International, Houston, TX, USA, 1974.
  41. A. K. Mishra and D. W. Shoesmith, “The activation/depassivation of nickel–chromium–molybdenum alloys: an oxyanion or a pH effect—Part II,” Electrochimica Acta, vol. 102, pp. 328–335, 2013. View at Publisher · View at Google Scholar · View at Scopus
  42. A. Bard and L. Faulkner, Electrochemical Methods-Fundamentals and Applications, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2nd edition, 2001.
  43. NIST, “CODATA Value: Faraday constant,” 2017, https://physics.nist.gov/cgi-bin/cuu/Value?f. View at Google Scholar
  44. P. Vanýsek, in Electrochemical Series, J. Rumble, Ed., CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, FL, USA, 2017.
  45. B. Beverskog and I. Puigdomenech, “Revised Pourbaix diagrams for nickel at 25–300°C,” Corrosion Science, vol. 39, no. 5, pp. 969–980, 1997. View at Publisher · View at Google Scholar · View at Scopus
  46. C. R. Clayton and Y. C. Lu, “A bipolar model of the passivity of stainless steels—III. The mechanism of MoO42− formation and incorporation,” Corrosion Science, vol. 29, no. 7, pp. 881–898, 1989. View at Publisher · View at Google Scholar · View at Scopus
  47. J. R. Hayes, J. J. Gray, A. W. Szmodis, and C. A. Orme, “Influence of chromium and molybdenum on the corrosion of nickel-based alloys,” Corrosion, vol. 62, no. 6, pp. 491–500, 2006. View at Publisher · View at Google Scholar
  48. П. Николайчук and A. Tyurin, The Revised Pourbaix Diagram for Molybdenum, 2014. View at Publisher · View at Google Scholar
  49. ASTM, Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements, ASTM International, West Conshohocken, PA, USA, 2015.
  50. Y. Hua, R. Barker, and A. Neville, “Comparison of corrosion behaviour for X-65 carbon steel in supercritical CO2-saturated water and water-saturated/unsaturated supercritical CO2,” Journal of Supercritical Fluids, vol. 97, pp. 224–237, 2015. View at Publisher · View at Google Scholar · View at Scopus
  51. S. A. McCoy, B. C. Puckett, and E. L. Hibner, “High Performance Age-Hardenable Nickel Alloys Solve Problems in Sour Oil and Gas Service,” Stainless Steel World, vol. 4, pp. 48–52, 2002. View at Google Scholar
  52. NACE International, Petroleum and Natural Gas Industries—Materials for Use in H2S-Containing Environments in Oil and Gas Production, NACE International, Houston, TX, USA, 2015.