Utilization of Fly Ash to Enhance Ground Waste Concrete-Based Geopolymer

Chen, Wu; Zhu, Zhiduo

doi:https://doi.org/10.1155/2018/4793917

Advances in Materials Science and Engineering

On this page

Abstract Introduction Materials and Methods Results and Discussion Conclusions Data Availability Conflicts of Interest Acknowledgments References Copyright Related Articles

Research Article | Open Access

Volume 2018 | Article ID 4793917 | https://doi.org/10.1155/2018/4793917

Utilization of Fly Ash to Enhance Ground Waste Concrete-Based Geopolymer

Wu Chen^1,2and Zhiduo Zhu^1,2

Academic Editor: Santiago Garcia-Granda

Received03 Mar 2018

Revised03 Jun 2018

Accepted05 Jul 2018

Published08 Aug 2018

Abstract

Demolition of the deteriorating infrastructure produces a large amount of waste concrete. Storage of waste concrete involves costly transportation, consumption of limited landfill space, and serious environmental problems. Combining them, the recycling of waste concrete is mainly limited to the use of recycled aggregates in the nonstructural filler and base course. Considering the limited geopolymerization potential of waste concrete, this study investigates the feasibility of using fly ash to enhance ground waste concrete-based geopolymer to recycle and utilize waste concrete in high-specification applications. The unconfined compressive strength of the binders synthesized at different fly ash contents, NaOH concentrations, and curing time are evaluated. Scanning electron microscopy/energy dispersive spectroscopy imaging, X-ray diffraction analyses, Fourier Transform Infra Red analyses, and Magic Angle Spinning-Nuclear Magnetic Resonance Spectroscopy techniques are also conducted to investigate the microstructure and phase/elemental compositions of the synthesized geopolymeric binders. The results indicate that the addition of fly ash to ground waste concrete profoundly enhances the strength of ground waste concrete-based geopolymer up to 75% fly ash content. The simultaneous formation of geopolymeric gel and CSH gel is responsible for the strength increase. The geopolymeric binder with required strength can be produced by the appropriate addition of fly ash to ground waste concrete.

1. Introduction

Concrete, consisting of Portland cement, sand, and aggregates, is the most widely used construction material. However, the manufacturing process of Portland cement, sand, and aggregates is usually associated with high consumption of energy, emission of CO₂, consumption of nonrenewable natural resources [1, 2]. Due to the growing awareness of environmental protection and sustainable development, the alternative low-cost and eco-friendly materials have been sought by the construction industry [3].

There has been an enormous increase of waste concrete (WC) in China during last decades due to the demolition of the deteriorating infrastructure. How to appropriately dispose off WC has been a great concern [4]. Most of the generated WC is disposed in landfill, which involves costly transportation, consumption of limited landfill space, and serious environmental problems [5]. Therefore, recycling of WC is encouraged by different institutions, and extensive research has been conducted [6, 7]. However, recycling of WC in the current practice is limited to the use of recycled aggregates in nonstructural filler and base course [8, 9]. The recycled aggregate has high water absorption, high emission of dust, low specific gravity and bulk density, and inferior mechanical properties in comparison to the natural aggregate. The adhered mortar/paste on the recycled aggregate is the main reason for these inferior properties and thwart the wide use of recycled aggregate to largely replace natural aggregate in the production of new concrete as it affects the strength and durability of the new concrete. To address this issue, some aggregate refining methods such as “freeze-thaw,” “thermal expansion,” and “mechanical grinding” [10–12] have been proposed to refine the quality of recycled aggregates by eliminating the adhered mortar but keeping the integrity of natural coarse aggregate. However, these techniques involve complicated procedure, high energy consumption, and most importantly they produce additional fines which need to be disposed of. Very few researchers [13, 14] have investigated complete recycling of waste concrete, but these methods require the reclinkering process at high temperature and thus consume significant amount of energy and generate tremendous amount of greenhouse gas.

Recently, an inorganic binder, named geopolymer, has attracted the attention of researchers from different engineering disciplines. Geopolymer has an amorphous to poor order polymeric structure synthesized from the reaction of a solid aluminosilicate with a high pH alkaline solution. Geopolymer possesses many merits over Portland cement such as rapid mechanical strength development, excellent adherence to aggregates, and lower CO₂ emissions and energy consumption. Researchers have applied this technology to produce geopolymer products from different raw materials, including fly ash, slag, and mine tailing [15–17].

Komnitsas et al. [18] have investigated using WC powder to produce geopolymeric binder. However, the WC showed limited geopolymerization potential and had a compressive strength of only 13 MPa. The high content of CaO in waste concrete impedes the geopolymerization of WC as it depletes alkaline hydroxide and forms brittle and soluble pirssonite (Na₂CO₃·CaCO₃·2H₂O).

The previous research [19] showed that metakaolin profoundly enhanced the strength of ground WC-based geopolymer; however, metakaolin is from kaolinite clay from the ground and is known for its high cost. So, this paper investigates the feasibility of using fly ash (FA) to enhance WC-based geopolymer so that WC can be recycled and utilized in high-specification applications. Sodium hydroxide (NaOH) solution mixed with sodium silicate solution is used as an alkaline reaction agent. The unconfined compressive strengths (UCS) of the geopolymeric binders synthesized at different NaOH solution concentrations, FA contents, and curing time are measured. Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) imaging, X-ray diffraction (XRD), Fourier Transform Infra Red (FTIR) analyses, and Magic Angle Spinning-Nuclear Magnetic Resonance Spectroscopy (MAS-NMR) analyses are also conducted to study the microstructure and phase/elemental compositions of the synthesized binder.

2. Materials and Methods

2.1. Materials

Ground WC, FA, reagent grade 98% NaOH, sodium silicate solution, and deionized water were used in this study. Ground WC was produced from the tested Portland cement concrete specimens in the structural lab of Southeast University. The tested concrete specimens were firstly crushed into two parts based on the particle size by a jaw crusher, and then the fine part passing mesh 32 (0.5 mm) was grinded by a ball mill to make most particles pass mesh 200. FA was received from Yangzhou Power Plant, China. The chemical components of ground WC and FA determined by X-ray fluorescence are presented in Table 1. The NaOH pellets and the sodium silicate solution (Na₂O = 8.52 wt.%, SiO₂= 27.28 wt.%, H₂O = 64.2 wt.%, modulus (SiO₂/Na₂O) = 3.1) were purchased from a ZD chemical company (in China).

Figure 1 presents the particle size distribution curves of the ground WC and FA determined by a Hydro 2000 Mu Melvin Laser Diffraction Particle Size Analyzer (the particles were suspended in deionized water). The D50 of ground WC is 8.3 μm with about 90% particles finer than 75 μm while the D50 of FA is 9.5 μm with about 96% particles finer than 75 μm. Figure 2 shows the microstructure of ground WC and FA photographed by SEM. The shape of WC particles is angular while the FA particles have a sphere shape.

(a)

(b)

(a)

(b)

(c)

(d)

2.2. Methods

Dry ground WC and FA at a given FA content were completely mixed. Simultaneously, the NaOH pellets were dissolving in deionized water at a selected concentration to prepare NaOH solution. The cooled down NaOH solution was added into the sodium silicate solution at a sodium silicate solution/NaOH solution (SS/N) mass ratio of 1.5 and stirred in a cement/mortar mixer at the rate of 60 r/min for 2 min. The well-stirred activator was mixed with the WC/FA mixture at a liquid to solid (L/S) weight ratio of 0.4. The resulting mixture was stirred for 5 min to facilitate dissolution of more Si, Al, and Ca in the liquid phase. The resulting paste was poured in cubic iron molds (length = 20 mm) and then shaken for 2 min to remove air bubbles. Then, the molds were capped and cured at 50°C for 24 h for setting. The specimens were demolded and placed in plastic bags and cured at ambient temperature before being tested. The specimen preparation method for all specimens was consistent. The size of the specimen was much smaller than the one required in the Chinese Standard for test method of mechanical properties on ordinary concrete (GB/T 50018-2002). Therefore, the UCS results should not be interpreted in absolute but rather in relative terms. As presented in Figures 3–5, the standard deviation in UCS is small.

Unconfined compression tests were conducted on the cured specimens with a CBR-2 press machine at a constant strain rate of 1.27 mm/min. For each recipe, three specimens were tested, and the average values were reported. The end faces of the specimens were polished to ensure parallelism and smoothness. SEM/EDS, XRD, and FTIR were used to inspect the microstructure and phase composition of geopolymers. SEM/EDS analysis was performed using a HITACHI SU3500 scanning electron microscope. The XRD analysis was conducted in a PANALYTICAL X’Pert PRO MRD/XL diffractometer, FTIR analysis was using Thermo Nicolet 370 FTIR/EZ Omnic, and MAS-NMR analysis was using a JEOL NM-ESH40MU Nuclear Magnetic Resonance Spectroscopy.

The variables proportion mixture and conducted test are presented in Table 2.

3. Results and Discussion

3.1. UCS

This study investigated the effects of NaOH concentration, FA content, and curing time on the UCS of the geopolymer binder.

3.1.1. Effect of NaOH Concentration

Two mechanisms may explain the roles of NaOH in the geopolymeric reaction: dissolution of Si and Al species and charge-balancing of Al species [20], which can be presented chemically as follows [21]:

As shown in Figure 3, the UCS values increase as NaOH concentration increases from 10 M to 14 M, which is also reported by Ahmari et al. [21]. This trend may be explainable knowing the fact that more Si and Al are dissolved at higher NaOH concentration and thus incorporation of lager amount of Si and Al in geopolymerization. However, some researchers have found a parabolic relationship between NaOH concentration and UCS [22]. The UCS firstly increases as NaOH concentration increases and then decreases after NaOH exceeds a certain value. That parabolic relationship may be attributed to the excess Na⁺ presented in the geopolymer framework and adversely affect the properties of geopolymers [23].

Another possibility for the UCS increase with alkalinity up to at least 14 M may be attributed to CSH gels formation as a result of the pozzolanic reactions. Different researchers [24–26] have reported high alkalinity, and present sufficient calcium leads to CSH formation. Since the WC contains substantial quantities of calcium, CSH might have formed filling the voids in the matrix and thus leading to higher UCS. However, the CSH formation is different at low and high alkalinity [24, 25]. Calcium can be easily dissolved for forming CSH at low alkalinity. At high alkalinity, OH⁻ ions will hinder the dissolution of calcium but the geopolymeric reaction and incorporation of OH⁻ in the geopolymerization decrease the alkalinity and thus lead to calcium leaching and CSH forming [24, 25].

The second mechanism is to provide Na⁺ to charge-balance the Al species and thus the Na/Al ratio is important display the availability of Na⁺ for Al atom. In the current investigation, the Na/Al ratios ranges from 0.39 to 1.31 listed in Table 2. Researchers have investigated different materials with Na/Al ratios varying from 0.38 to 2.06, and a Na/Al ratio around 1 is recommended [21–23, 27]. Excess Na⁺ presented in the polymeric framework leads to adverse effect on the UCS of geopolymers [27]. This may explain the current observation that the UCS keeps almost constant as NaOH concentration increases from 14 M to 18 M.

3.1.2. Effect of FA Content

The relationship between UCS and FA contents can be explained based on the Si/Al ratio of the WC/FA mixture. The amount of Si and Al in the source material plays a vital role to the synthesis of the geopolymer product as presented in the above scheme [27]. Researchers have investigated the influence of Si/Al ratios on geopolymerization [16, 20–23, 28, 29], and the optimal value may change depending on raw materials used in geopolymerization. The WC and FA have an initial Si/Al ratio of 3.30 and 1.90, respectively, which is not necessarily the same as the reactive ratio in the precursors. By adding FA into WC and utilizing appropriate amount of alkaline reaction agent, the Si/Al ratio varies from 2.13 to 3.86 (Figure 4). The Si/Al ratio of 2.34 (at 75% FA used in this study) reaches the highest UCS.

Komnitsas et al. [18] indicated that the high content of Ca in waste concrete impedes the geopolymerization of waste concrete. In the current study, the high content of Ca in WC (Ca/Si = 0.60) is decreased by adding the FA into the WC. The negative impact of too high Ca/Si ratio is primarily attributed to the precipitation of Ca(OH)₂ [30]. The highly unstable Ca(OH)₂, as a result of atmospheric carbonation, is favored to form calcium carbonate [31]. Simultaneously, Ca species may be hindered to be incorporated in the formation of CSH as the precipitation of Ca(OH)₂ [32]. And thus causes a decrease in UCS. However, researchers [33–35] have reported that Ca can improve the strength of geopolymeric binders since Ca²⁺ serves as a charge-balancing agent in the geopolymeric network and facilitates the formation of calcium silicate hydrate (CSH) gel leading to fill the voids between the phases, which may explain the UCS at 75% FA (Ca/Si = 0.19) higher than that of the specimen in the absence of the WC (Ca/Si = 0.11). At the highest UCS, the optimal Ca/Si in the WC/FA geopolymeric system is 0.19.

Ahmari et al. [21] investigated the geopolymeric binder from blended waste concrete powder and fly ash. Their results showed that the geopolymers synthesized with 50% FA and 50% waste concrete have the highest compressive strength. This may be attributed to that the alkalinity concentration (5 to 10 M) they used is lower than the one used in the current study as higher alkalinity concentration leads to the lager dissolution of Si and Al and the formation of CSH as discussion above.

3.1.3. Effect of Curing Time

Figure 5 shows the UCS of the specimens cured for different curing times. Significant increase in strength was found on these specimens in the first 3 days, and they reached their maximum strength which can be observed by almost constant strength at 7 days and beyond. Due to the specimens cured at 50°C for 24 hours, the geopolymeric reaction was already completed at 7 days. The amorphous phase is the only reason for the increase in strength as the crystalline phase makes no change with time [36].

3.2. Micro/Nano-Scale Investigation

3.2.1. XRD Analysis

The results of XRD analysis for the FA, ground WC, and the three geopolymeric specimens synthesized with 0%, 75%, and 100% FA are presented in Figure 6. FA contains semicrystalline and amorphous phase with a broad hump centered at approximately 22° along with a low-intensity peak corresponding to quartz and mullite. The ground WC mainly consists of crystalline phases including anorthite, quartz, portlandite, and CSH. In the ground WC, quartz and anorthite are derived from the crushed aggregates. The portlandite and CSH are the products of the cement hydration. In addition, a weak amorphous phase from 25° to 40° is observed in the XRD pattern of the ground WC. The XRD patterns of the specimens synthesized with 75% and 100% FA show that the crystalline peaks decrease and the broad humps shift to larger angles. The amorphous hump which extends from 20° to 40° is a feature of the geopolymeric gel. The decrease in crystalline peaks is probably because the wt % of crystalline elements is lower than it is in the powdered product. There is no new crystalline phase being synthesized by geopolymerization of the 75% FA specimen under the conditions used in this study. That may be attributed to that the crystalline CSH is not a main synthesized product of the reaction. The same observation has been made by van Jaarsveld et al. [37]. In the XRD pattern of the 0% FA specimen, the portlandite disappears indicating complete dissolution of the corresponding phase in the ground WC after geopolymerization. However, the CSH gel shows lower reactivity to the alkaline solution as only a portion of it dissolves. Pirssonite, which is responsible for low compressive strength of the ground WC-based geopolymer [18], is not formed. It may be attributed to the ground WC used in this study that has much lower CaO content (21.29%). In addition, the sodium silicate/NaOH equals 1.5 in this study while the sodium silicate/NaOH equals approximately 1 in Komnitsas et al.’s study. That also explains no pirssonite formed in this study because soluble silicate thwarts the dissolution of Ca-silicate.

3.2.2. FTIR Analysis

The IR spectra of the FA, ground WC, and the 75% FA specimen are presented in Figure 7. Both FA and ground WC show strong broad bands from 800 cm⁻¹ to 1200 cm⁻¹, which corresponds to the stretching vibrations of Si–O bonds [38]. In the IR spectrum of the 75% FA specimen, the Si–O vibration band has two main changes. First, the band shifts to a lower wave number, which is due to the depolymerization of silicates and replacement partial Si with Al [38], and thus leads to the transformation of Si–O band from symmetric to asymmetric form [34]. The Si–O stretching modes for the SiQⁿ units show absorption bands centered around 850, 900, 950, 1000, and 1100 cm⁻¹ for n = 0, 1, 2, 3, and 4, respectively [34]. These values shift toward lower wave numbers when the degree of substitution of Si with Al in the second coordination sphere increases [39]. The second change is the band becomes wider, which is attributed to the formation of randomly distributed Si–Al bonds [21]. Beyond that, a new weak band appears at 1400 cm⁻¹, which is due to the polymerization of the dissolved silicates [40]. The band centered at 798 cm⁻¹ in both FA and ground WC IR spectra, corresponding to the Al(VI)–O vibration band, vanishes (or weakens) in the 75% FA IR spectrum, and a new weak band centered at 619 cm⁻¹, corresponding to Al(IV)–O–Si vibration band, appears, which is attributed to the formation of new aluminosilicate phase related to geopolymerization [28]. The noticeable characteristic bands at 3640 cm⁻¹ corresponding to O–H vibration of Ca(OH)₂ [39] in the IR spectrum of ground WC disappears in the 75% FA spectrum, which indicates that Ca(OH)₂ undergoes full dissolution as confirmed with the XRD analysis.

3.2.3. MAS-NMR Analysis

The ²⁹Si MAS-NMR spectrum of the 75% FA specimen is presented in Figure 8. There is a broad resonance extends from −70 ppm to −110 ppm associated with three low-intensity peaks at −84.2 ppm, −91.6 ppm, and −103.4 ppm, respectively. The broad resonance is due to the disordered orientation of the Si and Al tetrahedrons. The three small peaks can be assigned to SiQ⁴(4Al), SiQ⁴(3Al), and SiQ⁴(4Si) units [41].

3.2.4. SEM/EDS Analysis

Figure 9 shows the SEM/EDS analysis of the 75% FA specimen, several distinct phases are observed: unreacted and partially reacted FA particles, partially reacted WC particles, two different forms of gel, and those particles embedded in the gel. The major elemental compositions of area A gel are Si, Al, and Na with a trace of Ca (1.73 wt.%) while in area B gel, Si, Ca, and Na are the major elements and Al is minor (2.54 wt.%). Area A gel has a Si/Al of 2.21 close to the chemical composition of the PSS type geopolymer. The Si/Al ratio of the geopolymeric gel is larger than the initial Si/Al ratio of the FA powder, which indicates that Al is likely to be dissolved and transported to the other phases after dissolution. In the area B, the phase could be some form of CSH. Yip et al. [33] found that the CSH formed in a NaOH-activated metakaolin/slag has a Ca/Si ratio of approximately 1, while Lecomte et al. [34] reported the Ca/Si is even smaller than 0.7. The Ca/Si ratio of area B is 0.90, which falls in the range of existing Ca/Si values. The highest UCS gained at the 75% FA can be attributed to the simultaneous formation of the two phases which fills the voids between these phases leading to a more dense binder.

(a)

(b)

(c)

4. Conclusions

This paper investigates the feasibility of using fly ash to enhance ground waste concrete-based geopolymer. The effects of NaOH concentrations, fly ash contents, and curing time on the UCS were studied. Microstructure and phase compositions are also presented based on the SEM/EDS, XRD, and FTIR analysis. The following conclusions can be drawn:(1)Increased NaOH concentration leads to higher UCS because of the larger dissolution of Si and Al and the formation of CSH; further increase of NaOH concentration results in no increase or decrease of UCS.(2)Addition of fly ash leads to the decrease of Si/Al ratio and Ca content reaching to the optimum ranges and thus improves the UCS of ground waste concrete-based geopolymer.(3)The geopolymers have a significant increase in strength in the first 3 days and gained their maximum strength at 7 days. Almost no change in strength takes place after 7 days.(4)The simultaneous formation of geopolymeric gel and CSH gel is responsible for the UCS increase.

Data Availability

The authors agree to make freely available any materials and information described in their manuscript that may be reasonably requested by others. Readers can access the data through the following link. https://figshare.com/s/27a2206058fc260b19e1.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

The authors wish to acknowledge the financial support of Transportation Science and Technology Foundation of Jiangsu (no. 8821000039). Dr. Zhen Tang and Engineer Kewei Tan at the Province Key Laboratory of Urban Underground Engineering & Environmental Safety are gratefully acknowledged for carrying out SEM/EDS and XRD analyses.

References

L. Moretti and S. Caro, “Critical analysis of the life cycle assessment of the Italian cement industry,” Journal of Cleaner Production, vol. 152, pp. 198–210, 2017.
View at: Publisher Site | Google Scholar
F. N. Stafford, A. C. Dias, L. Arroja, J. A. Labrincha, and D. Hotza, “Life cycle assessment of the production of Portland cement: a Southern Europe case study,” Journal of Cleaner Production, vol. 126, pp. 159–165, 2016.
View at: Publisher Site | Google Scholar
M. Schneider, M. Romer, M. Tschudin, and H. Bilio, “Sustainable cement production-present and future,” Cement and Concrete Research, vol. 41, no. 7, pp. 642–650, 2011.
View at: Publisher Site | Google Scholar
C. T. Formoso, L. Soibelman, C. De Cesare, and E. L. Isatto, “Material waste in building industry: main causes and prevention,” Journal of Construction Engineering and Management, vol. 128, no. 4, pp. 316–325, 2002.
View at: Publisher Site | Google Scholar
H. K. Kanare and P. B. West, “Leachability of selected chemical elements from concrete,” in Proceedings of Symposium on Cement and Concrete in the Global Environment, Chicago, IL, USA, 2005.
View at: Google Scholar
F. Pacheco-Torgal, V. Tam, J. Labrincha, Y. Ding, and J. de Brito, Handbook of Recycled Concrete and Demolition Waste, Elsevier, Cambridge, UK, 2013.
J. De Brito and N. Saikia, Recycled Aggregate in Concrete: Use of Industrial, Construction and Demolition Waste, Springer Science and Business Media, Berlin, Germany, 2012.
D. R. Hack and D. P. Bryan, in Industrial Minerals and Rocks, Society for Mining, Englewood, CO, USA, 2006.
W. Lager, “Sustainability of aggregates in construction,” in Sustainability of Construction Materials, J. M. Khatib, Ed., pp. 1–30, CRC Press, Boca Raton, FL, USA, 2009.
View at: Google Scholar
A. Abbas, G. Fathifazl, O. B. Isgor, A. G. Razaqpur, and S. Foo, “Proposed method for determining the residual mortar content of recycled concrete aggregates,” Journal of ASTM International, vol. 5, no. 1, Article ID 101087, 2008.
View at: Publisher Site | Google Scholar
M. S. Juan and P. A. Gutierrez, “Study on the influence of attached mortar content on the properties of recycled concrete aggregate,” Construction and Building Materials, vol. 23, no. 2, pp. 872–877, 2009.
View at: Publisher Site | Google Scholar
K. Yanagibashi, K. Inoue, S. Seko, and D. Tsuji, “A study on cyclic use of aggregate for structural concrete,” in Proceedings of Action for Sustainability: The 2005 World Sustainable Building Conference, Tokyo, Japan, September 2005.
View at: Google Scholar
F. Tomosawa and T. Noguchi, “Towards completely recyclable concrete,” in Integrated Design and Environmental Issues in Concrete Technology, K. Sakai, Ed., pp. 263–272, Taylor & Francis, London, UK, 1996.
View at: Google Scholar
J. R. Costes, C. Majcherczyk, and I. P. Binkhorst, Total Recycling of Concrete, 2007, http://omogine.blogspot.com/.
J. Xie and O. Kayali, “Effect of initial water content and curing moisture conditions on the development of fly ash-based geopolymers in heat and ambient temperature,” Construction and Building Materials, vol. 67, pp. 20–28, 2014.
View at: Publisher Site | Google Scholar
C. J. Tsai, R. Huang, W. T. Lin, and H. N. Wang, “Mechanical and cementitious characteristics of ground granulated blast furnace slag and basic oxygen furnace slag blended mortar,” Materials and Design, vol. 60, pp. 267–273, 2014.
View at: Publisher Site | Google Scholar
F. Pacheco-Torgal, J. Castro-Gomes, and S. Jalali, “Properties of tungsten mine waste geopolymeric binder,” Construction and Building Materials, vol. 22, no. 6, pp. 1201–1211, 2008.
View at: Publisher Site | Google Scholar
K. Komnitsas, D. Zaharaki, A. Vlacho, and G. Bartzas, “Effect of synthesis parameters on the quality of construction and demolition wastes (CDW) geopolymers,” Advanced Powder Technology, vol. 26, no. 2, pp. 368–376, 2015.
View at: Publisher Site | Google Scholar
W. Chen and Z. Zhu, “Synthesis and characterization of metakaolin modified waste concrete-based geopolymer,” in Proceedings of the 2nd International Symposium on Asia Urban GeoEngineering, Changsha, China, November 2017.
View at: Google Scholar
H. Xu and J. S. T. Van Deventer, “The geopolymerisation of alumino-silicate minerals,” International Journal of Mineral Processing, vol. 59, no. 3, pp. 247–266, 2000.
View at: Publisher Site | Google Scholar
S. Ahmari, X. Ren, V. Toufigh, and L. Zhang, “Production of geopolymeric binder from blended waste concrete powder and fly ash,” Construction and Building Materials, vol. 35, pp. 718–729, 2012.
View at: Publisher Site | Google Scholar
M. R. Rowles and B. H. O’Connor, “Chemical optimization of the compressive strength of aluminosilicate geopolymers synthesized by sodium silicate activation of metakaolinite,” Journal of Materials Chemistry, vol. 13, no. 5, pp. 1161–1165, 2003.
View at: Publisher Site | Google Scholar
M. R. Rowles and B. H. O’Connor, “Chemical and structural microanalysis of aluminosilicate geopolymers synthesized by sodium silicate activation of metakaolinite,” Journal of the American Ceramic Society, vol. 92, no. 10, pp. 2354–2361, 2009.
View at: Publisher Site | Google Scholar
M. L. Granizo, S. Alonso, M. T. Blanco-Varela, and A. Palomo, “Alkaline activation of metakaolin: effect of calcium hydroxide in the products of reaction,” Journal of the American Ceramic Society, vol. 85, no. 1, pp. 225–231, 2002.
View at: Publisher Site | Google Scholar
S. Alonso and A. Palomo, “Calorimetric study of alkaline activation of calcium hydroxide-metakaolin solid mixtures,” Cement and Concrete Research, vol. 31, no. 1, pp. 25–30, 2001.
View at: Publisher Site | Google Scholar
J. Temuujin, A. Van Riessen, and R. Williams, “Influence of calcium compounds on the mechanical properties of fly ash geopolymer paste,” Journal of Hazardous Materials, vol. 167, no. 1–3, pp. 2212–2219, 2009.
View at: Publisher Site | Google Scholar
M. Steveson and K. Sagoe-Crentsil, “Relationships between composition, structure and strength of inorganic polymers, part I-metakaolin-derived inorganic polymers,” Journal of Materials Science, vol. 40, no. 8, pp. 2023–2036, 2005.
View at: Publisher Site | Google Scholar
Z. Yunsheng, S. Wei, and L. Zongjin, “Composition design and microstructural characterization of calcined kaolin-based geopolymer cement,” Applied Clay Science, vol. 47, no. 3-4, pp. 271–275, 2010.
View at: Publisher Site | Google Scholar
P. Duxson, J. L. Provis, G. C. Lukey, S. W. Mallicoat, W. M. Kriven, and J. S.J. van Deventer, “Understanding the relationship between geopolymer composition, microstructure and mechanical properties,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 269, no. 1–3, pp. 47–58, 2005.
View at: Publisher Site | Google Scholar
J. W. Phair, J. S. J. Van Deventer, and J. D. Smith, “Mechanism of polysialation in the incorporation of zirconia into fly ash-based geopolymers,” Industrial and Engineering Chemistry Research, vol. 39, no. 8, pp. 2925–2934, 2000.
View at: Publisher Site | Google Scholar
V. D. Glukhovsky, “Ancient, modern and future concretes,” in Alkaline Cements and Concrete, P. V. Krivenko, Ed., CRC Press, Ukraine, 1994.
View at: Google Scholar
M. Frias and J. Cabrera, “Influence of MK on the reaction kinetics in MK/lime and MK-blended cement systems at 20°C,” Cement and Concrete Research, vol. 31, no. 4, pp. 519–527, 2001.
View at: Publisher Site | Google Scholar
C. K. Yip, G. C. Lukey, and J. S. J. Van Deventer, “The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation,” Cement and Concrete Research, vol. 35, no. 9, pp. 1688–1697, 2005.
View at: Publisher Site | Google Scholar
I. Lecomte, C. Henrist, M. Liegeois, A. Rulmont, and R. Cloots, “Microstructural comparison between geopolymers, alkali-activated slag cement and Portland cement,” Journal of the European Ceramic Society, vol. 26, no. 16, pp. 3789–3797, 2006.
View at: Publisher Site | Google Scholar
A. Fernandez-Jimenez, F. Puertas, I. Sobrados, and J. Sanz, “Structure of calcium silicate hydrates formed in alkaline-activated slag: influence of the type of alkaline activator,” Journal of the American Ceramic Society, vol. 86, no. 8, pp. 1389–1394, 2003.
View at: Publisher Site | Google Scholar
J. G. S. Van Jaarsveld, J. S. J. Van Deventer, and G. C. Lukey, “The effect of composition and temperature on the properties of fly ash and kaolinite-based geopolymers,” Chemical Engineering Journal, vol. 89, no. 1–3, pp. 63–73, 2002.
View at: Publisher Site | Google Scholar
J. G. S. Van Jaarsveld and J. S. J. Van Deventer, “Effect of the alkali metal activator on the properties of fly ash-based geopolymers,” Industrial and Engineering Chemistry Research, vol. 38, no. 10, pp. 3932–3941, 1999.
View at: Publisher Site | Google Scholar
W. K. W. Lee and J. S. J. Van Deventer, “Use of infrared spectroscopy to study geopolymerization of heterogeneous amorphous aluminosilicates,” Langmuir, vol. 19, no. 21, pp. 8726–8734, 2003.
View at: Publisher Site | Google Scholar
A. Allahverdi and E. N. Kani, “Construction wastes as raw materials for geopolymer binders,” International Journal of Civil Engineering, vol. 7, no. 3, pp. 154–160, 2009.
View at: Google Scholar
X. Guo, H. Shi, and W. A. Dick, “Compressive strength and microstructural characteristics of class C fly ash geopolymer,” Cement and Concrete Composites, vol. 32, no. 2, pp. 142–147, 2010.
View at: Publisher Site | Google Scholar
J. Davidovits, “Geopolymer chemistry and properties,” in Proceedings of the First European Conference on Soft Mineralogy, J. Davidovits and J. Orlinsl, Eds., pp. 25–48, The Geopolymer Institute, Compiegne, France, 1988.
View at: Google Scholar

Copyright

Copyright © 2018 Wu Chen and Zhiduo Zhu. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

PDF Download Citation

Download other formats

Order printed copies

Views

1800

Downloads

1205

Citations