Durability Improvement of Synthetic Dry Adhesives by Metal Coatings

Kim, Gyuhe; Ahn, Taechang; Hwang, Hui Yun

doi:https://doi.org/10.1155/2017/1696038

Advances in Materials Science and Engineering

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Abstract Introduction Materials and Methods Results and Discussion Conclusions Conflicts of Interest Acknowledgments References Copyright Related Articles

Research Article | Open Access

Volume 2017 | Article ID 1696038 | https://doi.org/10.1155/2017/1696038

Durability Improvement of Synthetic Dry Adhesives by Metal Coatings

Gyuhe Kim,¹Taechang Ahn,¹and Hui Yun Hwang¹

Academic Editor: Mikhael Bechelany

Received17 May 2017

Revised01 Aug 2017

Accepted16 Aug 2017

Published20 Sept 2017

Abstract

Gecko-like synthetic dry adhesives (SDAs) have adhesion comparable to that of a real Gecko’s foot, but with very low durability. To address this problem, self-cleaning or stiff core embedding methods have been proposed. However, the proposed methods require special locomotion or complicated manufacturing. In this study, we suggested a metal coating on synthetic dry adhesives to improve durability. SDAs were fabricated via PDMS. Then, metals such as indium, zinc, and gold were coated on the SDAs. The adhesion tests show that the indium- and zinc-coated microstructures have a higher shear adhesion strength than the noncoated ones. Also, the shear adhesion strength of noncoated SDAs was only 14.5% of the initial strength while that of the zinc-coated ones was 35.6% after 200 times of attachment and detachment. We could find PDMS debris and fractures on noncoated SDAs, which results in weakening of the adhesion strength. On the other hand, a relatively high hardness, strength, and stiffness of the zinc coating layers reduced the wear and fractures of the micropatterns, which led to an improved durability in the SDAs. From these tests, we can conclude that the metal coating method could improve the durability of the SDAs.

1. Introduction

Many researchers have engineered systems with a higher efficiency by adopting novel features that have been observed in nature. As such, synthetic dry adhesives (SDAs) inspired by Gecko’s feet are a typical example of systems inspired by nature [1, 2]. Gecko’s feet are widely known to have millions of microsized setae with over 1,000 nanosized spatulae in hierarchical structures, and the Van de Waals force between the spatulae and foreign surfaces gives the superb adhesion to Gecko’s feet. In addition, Gecko’s feet have other superior features, including directionally different and reversible adhesion, self-cleaning, and nonpollution characteristics. Therefore, there have been many attempts to mimic Gecko’s feet for industrial applications in, for example, medical patches and sticky robot hands [3–16].

In the initial phase (earlier stage), micro- or nanopatterned structures with a high aspect ratio were designed for SDAs, and their adhesion characteristics were evaluated using a pull-off test, friction test, and peeling test [17–19]. Tilted or hierarchical structures with 3D shaped-tips, such as with a mushroom shape, and self-cleaning properties were tested to improve the adhesion [20–27]. These researches were focused on how to fabricate SDAs with very small and complicated structure, and various microelectronic and micromechanical processes were applied. Dip transfer, multistep photolithography, UV-assisted CFL, and multistep template are typical examples of numerous trials. Micro- and nanopillars with a higher aspect ratio are essential to achieve reasonable adhesion, but the aforementioned fabrication methods cannot be used commercially since extremely precise equipment and a long time are required for fabrication [24, 28–41]. In contrast, polymers or elastomers such as polydimethylsiloxane (PDMS) have been widely used for SDAs due to their flexibility and ease of fabrication. However, these materials have a low stiffness and strength, which reduces the adhesion strength of the micro- and nanopillars due to fiber collapse, abrasion, and fracture [1, 22, 42–44]. This limits SDAs to only a single application, such as medical patches, whereas demand for applications for robot hands and transportation equipment for clean rooms requires a more durable adhesion. Therefore, maintaining the adhesion strength of the SDAs can increase their applicability to a wider range. One method that was proposed to maintain the adhesion strength was to coat it with an adhesive structure. Suh’s group reported on the adhesion strength of nanohairy dry adhesives coated with a 4 nm thick platinum layer [22], and Kim’s group also presented dry adhesives with micropatterns coated with a 6 nm thick gold layer [45]. However, these studies have only given the changes in the adhesion strength with and without metal coatings.

The purpose of this study is to investigate the changes not only of the adhesion strength, but also of the structural integrity by considering the mechanical and physical properties of the coating materials and their thickness. We fabricated SDAs with micropatterns using PDMS and coated three different metals on the micropatterns with different thicknesses via plasma sputtering. We then measured the adhesion strength of the fabricated dry adhesives during repeated shear tests on glass surfaces and observed the structural changes with an optical microscope as well as a scanning electron microscope (SEM). For further analysis, we compared the changes in the adhesion strength and structural integrity based on the material properties and thickness of the coating metals.

2. Materials and Methods

2.1. Materials and Specimen

Many studies have used polydimethylsiloxane (PDMS), polyurethane (PU), and polyurethane acrylate (PUA) to develop SDAs. We selected PDMS (SYLGARD 184, Dow Corning Co. Ltd., USA) due to its easy micro- and nanofabrication, relatively high durability, and flexibility. The specifications of the PDMS are shown in Table 1.

Gold, indium, and zinc were selected as coating materials because they have different stiffness, strength, and hardness, as shown in Table 2. These properties were expected to have an effect changes in the adhesion strength, durability, and structural integrity.

2.2. Sample Preparation

SDAs with micropatterns were fabricated using the process shown in Figure 1. The base material (SYLGARD 184 Base, Dow Corning Co. Ltd., USA) and curing agent (SYLGARD 184 Curing, Dow Corning Co. Ltd., USA) were mixed at a ratio of 10 : 0.8 using a planetary centrifugal mixer (ARM-310, Thinky Co., Japan) under a rotating speed of 2,000 rpm for 1 min. Then, the mixture was poured in a micropatterning mold with microholes with a diameter of 30 μm, height of 60 μm, and interval of 30 μm. The mixtures were poured in the mold and cured at 80°C for 3 hours under vacuum in a vacuum oven (VO-64, Hanyang Scientific Equipment Co. Ltd., Korea). Finally, we could obtain SDAs with micropatterns once they were separated from the mold. Subsequently, micropatterns were coated with metal materials (gold, zinc, and indium) using a compact plasma sputtering coater (GSL-1100X-SPC12-LD, MTI Co., USA). DC argon plasma sputtering was conducted under gas purity of 99.995%, gas pressure of 8 Pa, discharge power of 2.4 W, and the sputtering time ranging from 4 s to 20 s to control the coating thickness from 2 nm to 10 nm.

2.3. Test Method

The macroscopic shear adhesion strength of the SDAs was measured using a frictional adhesion test, as shown in Figure 2 since the fabricated SDAs only had simple micropatterns [29, 46]. Specimens with sizes of 10 mm × 10 mm were attached to a slide glass with a preload of 2 N. A moving stage with a load cell at 30 N (DBCM, Bongshin Load Cell Co., Ltd., Korea) pulled off the specimens at the speed of 0.03 mm/s, and the frictional forces were recorded during the tests. Upon completing these tests, the thickness of each coating material with a maximum shear adhesion strength was selected. Frictional adhesion tests were then repeated 200 times with metal-coated SDAs with selected thickness, and the changes were analyzed regarding the shear adhesion strength to evaluate their durability.

In addition, we observed changes in the surfaces and structural integrity of micropatterns for every tenth frictional adhesion test using a digital microscope (KH-7700, Hirox Co., Ltd., Japan) and a field emission scanning electron microscope (JSM-6700F, Jeol Ltd., Japan).

3. Results and Discussion

3.1. Thickness Selection of the Coated Metal Layers

Figure 3 shows the measured shear adhesion strength of the metal-coated SDAs for each material and the thickness of the metal films on the adhesives. As reference, the SDAs without metal coatings had a shear adhesion strength of 9.1 kPa. The shear adhesion strength of the SDAs coated with indium increased from 3.9 kPa to 10.9 kPa when the indium thickness increased from 2 nm to 4 nm, and the shear adhesion strength with an indium thickness ranging from 4 nm to 10 nm decreased from 10.9 kPa to 4.51 kPa. The maximum adhesion strength was 10.9 kPa for the 4 nm thick indium layer, and there was less than a 15% error when measuring the data. On the other hand, the zinc-coated synthetic dry adhesive displayed a different tendency. The shear adhesion strength increased monotonically from 5.5 kPa to 9.6 kPa and then decreased to 8.5 kPa. It reached maximum at 9.6 kPa when the zinc layer thickness was 8 nm, and the maximum error was 9.6%. SDAs coated with gold had a relatively low shear adhesion strength compared to the other two metals. The shear adhesion strength varied from 3.6 kPa to 6.3 kPa with a maximum error of 12.3% in the thickness range from 2 nm to 10 nm. The maximum strength was 6.3 kPa when the layer of gold was 6 nm.

The adhesion characteristics of the SDAs depend on the Van der Waals forces [5]. The Van der Waals force (Fvdw) between the two flat surfaces can be calculated as follows [47]:where and are the Hamaker constant (J) and cut-off distance (0.165 nm). can also be derived from the surface energy as follows [46]:where and represent the surface energy of the contact materials (dyne/cm), respectively. Therefore, the adhesion characteristics of the SDAs can improve if the SDAs are fabricated using a material with a high surface energy.

On the other hand, the Van der Waals forces are proportional to bending the SDAs due to an increase in the contact area [15], and bending is inversely proportional to the effective stiffness of the SDAs. This means that the increase in stiffness might lead to a reduction in the adhesion characteristics of the SDAs.

Table 3 shows the calculated bending stiffness of the SDAs with and without metal coatings as well as the surface energy of the coating metals. The surface energies of the coating metals are much higher than those of PDMS (about 20 to 70 times), but the bending stiffness of the SDAs increased by coating metals on the PDMS (about 10~100 times).

Two different results were reported regarding the effect of the stiffness of the SDAs [22]. Regarding the material properties, SDAs made with a hard polyurethane acrylate (PUA) with 320 MPa of modulus had a higher adhesion strength compared to those with a soft PUA of 19.8 MPa. However, from the point of view of the structural stiffness, SDAs made with a soft PUA with a high effective stiffness had a lower adhesion strength compared to those with a low effective stiffness.

The results calculated in Table 3 and the reported results [22] indicate that different materials have different adhesion characteristics, and only the modulus or structural stiffness is not unique factor in determining the adhesion characteristics of the SDAs. Whether the effects of the surface energy or stiffness of SDAs are more important to the adhesion characteristics has not been reported, so we could not estimate a change in the adhesion strength by the metal coatings. However, the adhesion strength of the SDAs with metal coatings might be higher or lower compared to those without metal coatings.

Based on the maximum shear adhesion strength, SDAs coated with indium and zinc had a higher strength compared to those without coatings, but the gold-coated ones had a relatively low adhesion strength. From the results of the shear adhesion test, we selected the optimal thickness of the layer for each metal: 4 nm, 8 nm, and 6 nm for indium, zinc, and gold, respectively.

3.2. Durability of the SDAs

The durability of the SDAs was evaluated with and without metal coating by repeating frictional adhesion tests. The changes in the shear adhesion strength for each metal are shown in Figure 4.

(a)

(b)

(c)

(d)

The reference durability data of the SDAs without a coating is shown in Figure 4(a). The shear adhesion strength decreased drastically from 9.1 kPa to 4.1 kPa during the first 50 repetitions. This displays reductions in the strength of 54.3% and a reduction rate of 0.099 kPa/repetition. Until 90 repetitions, a relatively gradual reduction in the shear adhesion strength was observed, and the reduction rate was 0.023 kPa/repetition. After 90 repetitions, the shear adhesion strength decreased monotonically with a reduction rate of 0.034 kPa/repetition and then gradually reduced to 1.3 kPa at 200 repetitions with a reduction rate of 0.011 kPa/repetition. After 200 repetitions, only 14% of initial shear adhesion strength was retained.

Indium-coated SDAs had the highest initial shear adhesion strength, and their strength reduction was only 51.7% from 10.9 kPa to 5.3 kPa (reduction rate of 0.061 kPa/repetition) during the first 90 repeated tests (Figure 4(b)). In the range from 100 to 180 repetitions, the reduction rate decreased as 0.021 kPa/repetition, and then the shear adhesion strength was reduced at a reduction rate of 0.064 kPa/repetition. Finally, the shear adhesion strength became 1.8 kPa (16.3% of initial strength).

A tendency for the reduction in the shear adhesion strength for SDAs coated with zinc was similar to those with indium (Figure 4(c)). First, 90 repetitions decreased the shear adhesion strength from 9.6 kPa to 6.3 kPa, which corresponded to a reduction rate of 0.036 kPa/repetition. The shear adhesion strength decreased slowly to 5.15 kPa (reduction rate of 0.016 kPa/repetition) until 160 repetitions, and then the reduction rate increased at 0.032 kPa/repetition. In total, 36.5% of the initial shear adhesion strength (3.5 kPa) was maintained after 200 repetitions.

As shown in Figure 4(d), SDAs with a gold coating layer had a different trend in the shear adhesion strength compared to the other 3 cases. During the first 100 repetitions, the shear adhesion strength decreased from 6.4 kPa to 2.1 kPa at a reduction rate of 0.042 kPa/repetition. Even though the reduction rate seemed to be lower than or similar to that of the other cases, the cause may be due to a relatively low initial shear adhesion strength rather than good durability. At 100 repetitions, the shear adhesion strength was only 2.1 kPa, which is close to those of reference data after 200 repetitions. Until 200 repetitions, the reduction rate was quite low at 0.005 kPa/repetition, but the shear adhesion strength eventually became 1.5 kPa (23% of initial shear strength).

We calculated the retention rate, percentage ratio of the shear adhesion strength after repeated tests to the initial strength to compare the durability of the SDAs with and without metal coating layers based on Figure 4. As shown in Figure 5, the retention rate of the reference synthetic dry adhesive degraded the fastest, and those with metal coating layers had a relatively higher retention rate. In particular, the zinc-coated SDAs had the highest retention rate (63.9% at 100 repetitions and 36.6% at 200 repetitions) as well as the highest shear adhesion strength (3.5 kPa) at 200 repetitions although initial shear adhesion strength (9.6 kPa) was lower than those of indium-coated ones (10.8 kPa).

3.3. Surface and Structural Integrity of SDAs

The changes in the surface and structural integrity of the SDAs with and without metal coatings were investigated, as shown in Figure 6.

(a)

(b)

(c)

(d)

We could observe a large amount of wear on the top surfaces of the reference SDAs along the direction of the slide, as shown in Figure 6(a) (see the dark areas pointed by the arrows) after only the first 50 repetitions. The fracture on the root of the micropatterns appeared in some places at 50 repetitions because the top surface wear made a larger deformation, even though the wear was not severe until 100 repetitions. However, the fracture began to spread to the entire region after 100 repetitions and continued until 200 repetitions. At the end, 98% of the micropatterns were fractured.

Indium-coated SDAs kept the top surfaces of micropatterns relatively less worn than those of the reference until 50 repetitions due to the metal coating layer, as shown in Figure 6(b). From 50 to 100 repetitions, the wear on the top surfaces increased. At 100 repetitions, we could observe self-adhesion due to large bending deformation and some fractures at the middle of micropillars rather than the root in the reference. After 200 repetitions, fractures occurred on both the middle and root of the micropillars, and debris formed between the unfractured micropillars. At 200 repetitions, 47% of the micropatterns were in self-adhesion or large bending, and 15% were fractured.

Figure 6(c) presents the surfaces of SDAs coated with zinc. Unlike the above two cases, small abrasive particles of the zinc layer were attached on the micropillars at 50 repetitions. This means that the wear tendency of the zinc-coated SDAs is abrasion, but the above two cases represent plastic deformation, which led to the contact area becoming wider. However, the degree of wear was not severe compared to the other cases until 100 repetitions. After 100 repetitions, a large bending deformation was observed, and only 12% of the micropillars were fractured on the root at 200 repetitions. A tendency in the bending deformation and fractures was similar to that of the indium-coated ones.

Cracks were observed on a gold-coated back-up plate of the SDAs (see scratch-shaped lines in Figure 6(d)), and the top surfaces of the micropatterns were relatively bright due to the gold coating. After 50 repetitions, cracks appeared on the top surfaces, and the coated gold partially wore due to the repetitive contact. The gold-coated layer kept peeling until 100 repetitions, and it totally wore out on the top surfaces at 100 repetitions. From 100 to 200 repetitions, fractures in the micropatterns continued, similarly to the reference. Finally 89% of the SDAs were removed.

3.4. Discussion

An investigation of the surfaces and structural integrity of the SDAs could explain the tendency to reduce the shear adhesion strength through repeated use.

For the reference SDAs, wear on the top surfaces accelerated the degradation of the shear adhesion strength during the first 50 repetitions. A partial fracture was observed from 50 to 100 repetitions, and a total fracture observed by 200 repetitions resulted in a further reduction in the shear adhesion strength as a different trend. Fractured micropatterns occupied 98% of the entire area, which made the shear adhesion strength only 14% of the initial strength. The tendency for a reduction in strength implies that the most effective factors are the wear of the contact surfaces and the fracture of the micropatterns. Therefore, we can improve the durability of the SDAs if the contact surface is protected, wear is reduced, and strength of the micropillars increased. In this aspect, fabricating thin metal layers on the contact surfaces is an effective counterplan because the thin metal layers enhance the wear resistant contact surfaces and strengthen the micropillars by covering weak polymer materials.

The indium-coated layer could decrease the wear of the top surfaces until 100 repetitions compared to those of the reference, as shown in Figure 6(b). This leads to an increase in the retention rate of the share adhesion strength, as shown in Figure 5. However, a relatively low strength and stiffness for indium were not sufficient to decrease the bending deformation and reinforce the micropillars. After 180 repetitions, an abrupt reduction in the shear adhesion strength was observed, as shown in Figure 4(b).

For comparison, the zinc-coated SDAs had a higher durability though a reduction in the shear adhesion strength similar to those with indium, as shown in Figure 6(c). The wear of the top surfaces was not noticeable until 100 repetitions as hardness of zinc-coated layer is much higher than that of indium, and it retained 63.9% of the initial shear adhesion. In addition, a relatively higher strength and stiffness of zinc than indium resulted in less bending deformation and more strengthening of the micropillars. A retention rate of 36.5% compared to the initial shear adhesion strength was achieved by good mechanical properties of the zinc-coated layer.

Gold-coated SDAs showed a different tendency even though the strength and stiffness of gold are the highest among three coating metals where the hardness is comparable to zinc. As shown in Figure 6(d), the main reason for the reduction of shear adhesion strength was exfoliation of gold-coated layer on SDAs. In general, the adhesion between the gold and polymers is relatively weaker than that of the other metals [48]. Therefore, peeling the gold-coated layer resulted in a relatively large drop in the shear adhesion strength. After 100 repetitions, the gold-coated SDAs had a trend close to reference since no gold layer remained.

4. Conclusions

We fabricated four different SDAs with and without metal-coated layers to investigate the effects of the metal coating on the durability of the shear adhesion strength. Among the coating materials that were considered, zinc-coated SDAs had not only the highest shear strength (10.8 kPa), but also durability in repeated tests (retention rate of 63.9% at 100 repetitions and 36.5% at 200 repetitions). These results are more than double the strength of the SDAs without any coating. Surface observations with respect to the number of repetitions revealed important factors of their durability, including the mechanical properties (hardness, strength, and stiffness) of the coating metal and adhesion characteristics of the coating metals to the micropillars.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government (NRF-2012S1A2A1A01030569) and in part by the National Research Foundation of Korea Grant funded by the Korean Government (NRF-2016R1A2B4014603).

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Copyright © 2017 Gyuhe Kim et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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