Transient Exciplex Formation Electron Transfer Mechanism
Figure 7
Dependences of (top) and (bottom) on for quenching of excited singlet states of various aromatic compounds in MeCN (according to the experimental data of Rehm and Weller [31]). Best plots are shown for simulation of the experimental dependence by (3)—1 and (6)—2, and by concatenated mechanism (16)—3. Dotted line shows thermodynamic limit for ET (, where ).
