Table of Contents
Advances in Physical Chemistry
Volume 2016, Article ID 8092860, 8 pages
http://dx.doi.org/10.1155/2016/8092860
Research Article

Electrochemical Investigation of Catechol at Poly(niacinamide) Modified Carbon Paste Electrode: A Voltammetric Study

1Department of Chemistry, BLDEA’s College of Engineering and Technology Affiliated to VTU Belagavi, Vijayapur, Karnataka, India
2Department of Chemistry, BLDEA’s SB Arts and KCP Science College, Vijayapur, Karnataka, India
3Department of PG Studies and Research in Industrial Chemistry, Kuvempu University, Jnana Sahyadri, Shankaraghatta, Shimoga, Karnataka 577451, India

Received 19 July 2016; Revised 20 September 2016; Accepted 4 October 2016

Academic Editor: Claudio Fontanesi

Copyright © 2016 A. B. Teradale et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A polymeric thin film modified electrode, that is, poly(niacinamide) modified carbon paste electrode (MCPE), was developed for the electrochemical determination of catechol (CC) by using cyclic voltammetric technique. Compared to bare carbon paste electrode (BCPE), the poly(niacinamide) MCPE shows good electrocatalytic activity towards the oxidation of catechol in phosphate buffer solution (PBS) of physiological pH 7.4. All experimental parameters were optimized. Poly(niacinamide) modified carbon paste electrode gave a linear response between concentration of CC and its anodic peak current in the range within 20.6–229.0 μM. The limit of detection (3S/M) and limit of quantification (10S/M) were 1.497 μM and 4.99 μM, respectively. From the study of scan rate variation, the electrode process was found to be adsorption-controlled. The involvement of protons and electrons in the oxidation of CC was found to be equal. The probable electropolymerisation mechanism of niacinamide was proposed. Finally, this method can be used in development of a sensor for sensitive determination of CC.