Synthesis and Characterization of Novel Organo-Inorganic Hybrid Material of Poly(3,4-Ethylene Dioxythiophene) and Phosphomolybdate
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Murugan, A. Vadivel; Kwon, C.-W.; Campet, G.; Kale, B. B.

doi:https://doi.org/10.1080/0882751031000073896

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Volume 26 | Article ID 456152 | https://doi.org/10.1080/0882751031000073896

Synthesis and Characterization of Novel Organo-Inorganic Hybrid Material of Poly(3,4-Ethylene Dioxythiophene) and Phosphomolybdate Anion

A. Vadivel Murugan,¹C.-W. Kwon,²G. Campet,²and B. B. Kale¹

Received31 Aug 2002

Revised17 Nov 2002

Abstract

The organo-inorganic hybrid material, consisting of Poly(3,4-Ethylene Dioxythiophene) (PEDOT) doped with phosphomolybdate cluster anions [PMo12O40]3− , has been synthesized by direct in situ oxidative polymerization of 3,4-Ethylene Dioxythiophene (EDOT) with phosphomolybdic acid (H3PMo12O40) . Its characterization is investigated by Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM). The hybrid material presents predominantly high electronic conductivities of around 2.0 and 7.0 S cm-1 at 300 and 400K respectively.

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Copyright © 2003 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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