Bioinorganic Chemistry and Applications

Bioinorganic Chemistry and Applications / 2006 / Article

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Volume 2006 |Article ID 013743 | https://doi.org/10.1155/BCA/2006/13743

Mukta Jain, R. V. Singh, "Synthesis, Characterization, and Biotoxicity of NN Donor Sulphonamide Imine Silicon(IV) Complexes", Bioinorganic Chemistry and Applications, vol. 2006, Article ID 013743, 10 pages, 2006. https://doi.org/10.1155/BCA/2006/13743

Synthesis, Characterization, and Biotoxicity of NN Donor Sulphonamide Imine Silicon(IV) Complexes

Received20 Apr 2004
Revised30 Jul 2004
Accepted08 Oct 2004
Published15 Feb 2006

Abstract

The organosilicon derivatives of 2-[1-(2-furayl)ethyledene]sulphathiazole with organosilicon chlorides have been synthesised and characterized on the basis of analytical, conductance, and spectroscopic techniques. Probable trigonal bipyramidal and octahedral structures for the resulting derivatives have been proposed on the basis of electronic, IR, 1H, 13C NMR, and 29Si NMR spectral studies. In the search for better fungicides, bactericides, nematicides, and insecticides studies were conducted to assess the growth-inhibiting potential of the synthesized complexes against various pathogenic fungal, bacterial strains, root-knot nematode Meloidogyne incognita, and insect Trogoderma granarium These studies demonstrate that the concentrations reached levels which are sufficient to inhibit and kill the pathogens, nematode, and insect.

References

  1. H Singh, V K Srivastava, S N Shukla, M K Srivastava, and M K Upadhyay, Indian Journal of Chemistry, vol. 33A, pp. 350–353, 1994.
  2. K K Chaturvedi, R V Singh, and J P Tandon, “The reactions of Boron and Aluminium Isopropoxides with the imines derived from sulphonamides,” Journal für Praktische Chemie, vol. 327, no. 1, pp. 144–150, 1985. View at: Google Scholar
  3. H-Y Zhang, J Lei, Y-Y Chen, Q-A Wu, Y-S Zhang, and L-H Gao, “Synthesis of the N,N-bis(ferrocenylmethylene)-1,2-phenylenediamine Schiff base and six rare earth metal complexes,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 31, no. 6, pp. 973–981, 2001. View at: Google Scholar
  4. S Hong-Jian, L Xiao-Yan, C Xue-Gui, and L De-Xin, Hua Xue Xue Bao. Acta Chimica Sinica, vol. 13, pp. 1168–1170, 1992, Chem. Abstr., 1993. 118, 261640X.
  5. W Dong-Mei, Y Rui-Na, H Xiao-Yuan, H Yi-Min, X Bao-Yu, and J Dou-Man, Huaxue Tongbao. Chemistry, vol. 10, pp. 35–36, 1995, Chem. Abstr., 1996, 124, 276796a.
  6. W Ji-Tao, G Sheng-Hua, L Xiang-Min, and L Feng-Quan, Hua Xue Xue Bao. Acta Chimica Sinica, vol. 14, no. 5, pp. 645–650, 1993, Chem. Abstr., 1993, 119, 240289v.
  7. K Singh, Indian Journal of Chemistry, vol. 30A, pp. 283–285, 1991.
  8. S Belwal and R V Singh, “Bioactive versatile azomethine complexes of organotin(IV) and organosilicon(IV),” Applied Organometallic Chemistry, vol. 12, no. 1, pp. 39–46, 1998. View at: Google Scholar
  9. A Phor, A Chaudhary, M Jain, R Swaroop, and R V Singh, Main Group Metal Chemistry, vol. 24, pp. 439–444, 2001.
  10. R V Singh, M Jain, and P Nagpal, “Nitrogen-sulphur and nitrogen-oxygen donor ferrocene containing ligands and their diorganosilicon (IV) complexes,” Main Group Metal Chemistry, vol. 25, no. 10, pp. 615–619, 2002. View at: Google Scholar
  11. M Jain and R V Singh, International Journal for Chemical Science, vol. 1, no. 1, pp. 17–24, 2003.
  12. M Jain, D Kumar, and R V Singh, “Toxicological aspects of the bioactive versatile sulphonamide-imine complexes of organosilicon(IV),” Main Group Metal Chemistry, vol. 26, no. 2, pp. 99–109, 2003. View at: Google Scholar
  13. M Jain, S Gaur, S C Diwedi, S C Joshi, A Bansal, and R V Singh, Phosphorus, Sulfur, and Silicon, vol. 178, p. 923, 2003.
  14. M Jain and R V Singh, “Spectral and antimicrobial studies of organosilicon(IV) complexes of a bidentate Schiff base having nitrogen-nitrogen donor system,” Main Group Metal Chemistry, vol. 26, no. 4, p. 237, 2003. View at: Google Scholar
  15. M Jain, S Gaur, V P Singh, and R V Singh, “Organosilicon(IV) and organotin(IV) complexes as biocides and nematicides: synthetic, spectroscopic and biological studies of {N\!\raisebox{5pt}{$\frown$}\!N} donor sulfonamide imine and its chelates,” Applied Organometallic Chemistry, vol. 18, no. 2, pp. 73–82, 2004. View at: Google Scholar
  16. C Saxena and R V Singh, Phosphorus, Sulfur, and Silicon, vol. 97, pp. 17–26, 1994.
  17. S Belwal, H Tanjea, A Dandia, and R V Singh, Phosphorus, Sulfur, and Silicon, vol. 127, pp. 49–58, 1997.
  18. S Belwal, R K Saini, and R V Singh, Indian Journal of Chemistry, vol. 37A, pp. 245–248, 1998.
  19. M S Singh, V W Bhagwat, M D Raju, and S K Tiwari, Indian Journal of Chemistry, vol. 38A, pp. 716–719, 1999.
  20. C Saxena and R V Singh, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 22, no. 8, pp. 1061–1072, 1992.
  21. R V Singh, S C Joshi, A Gajraj, and P Nagpal, “Studies of biologically potent organotin(IV) and organosilicon(IV) complexes of a sulfur donor ligand derived from 1-acetylferrocene,” Applied Organometallic Chemistry, vol. 16, no. 12, pp. 713–720, 2002. View at: Google Scholar
  22. N Fahmi and R V Singh, Transition Metal Chemistry, vol. 19, pp. 453–456, 1994.
  23. N Fahmi and R V Singh, Indian Journal of Chemistry, vol. 37A, pp. 1126–1129, 1998.
  24. N Fahmi, S CS Jadon, and R V Singh, Phosphorus, Sulfur, and Silicon, vol. 81, p. 133, 1993.
  25. P C Trivedi, Ed., Nematode Diseases in Plants, CBS, New Delhi, India, 1st edition, 1998.
  26. M Jain, S Nehra, P C Trivedi, and R V Singh, “Biologically potent heterocyclic sulphonamide imines and their manganese (II) complexes,” Heterocyclic Communications, vol. 9, no. 1, pp. 95–98, 2003. View at: Google Scholar
  27. M Jain, S Nehra, P C Trivedi, and R V Singh, Metal-Based Drugs, vol. 9, pp. 53–59, 2002.
  28. S C Dwivedi and M Mathur, J. Exotoxicol. Environ. Monit., vol. 9, no. 3, pp. 163–166, 1999.
  29. S C Dwivedi and M Bajaj, Indian J. Exp., vol. 3, pp. 153–155, 2000.
  30. R P Srivastava and R C Saxena, A Textbook of Insect Toxicology, Himanshu, New Delhi, India, 1989.

Copyright © 2006 Mukta Jain and R. V. Singh. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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