Bioinorganic Chemistry and Applications

Volume 2006 (2006), Article ID 58937, 12 pages

http://dx.doi.org/10.1155/BCA/2006/58937

## Reactions Between Chalcogen Donors and Dihalogens/Interalogens: Typology of Products and Their Characterization by FT-Raman Spectroscopy

Dipartimento di Chimica Inorganica ed Analitica, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, Monserrato (CA) 09042, Italy

Received 22 June 2006; Revised 4 October 2006; Accepted 5 October 2006

Copyright © 2006 Massimiliano Arca et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Linked References

- C Raby, J F Lagorce, A C Jambut-Absil, J Buxeraud, and G Catanzano, “The mechanism of action of synthetic antithyroid drugs: iodine complexation
during oxidation of iodide,”
*Endocrinology*, vol. 126, pp. 1683–1691, 1990. View at Google Scholar - W-W du Mont, G Mugesh, C Wismach, and P G Jones, “Reactions of organoselenenyl iodides with thiouracil drugs: an enzyme mimetic study on the inhibition of iodothyronine deiodinase,”
*Angewandte Chemie—International Edition*, vol. 40, no. 13, pp. 2486–2489, 2001. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “Anti-thyroid drug methimazole: X-ray characterization of two novel ionic disulfides obtained from its chemical oxidation by ${\text{I}}_{\text{2}}$,”
*Journal of the American Chemical Society*, vol. 124, no. 17, pp. 4538–4539, 2002. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, M L Mercuri et al., “$N,{N}^{\prime}$-dimethylpiperazinium-2,3-dithione triiodide, $[{\text{Me}}_{2}\text{pipdt}]{\text{I}}_{3}$, as a powerful new oxidation agent toward metallic platinum. Synthesis and x-ray structures of the reagent and the product $[\text{Pt}{({\text{Me}}_{2}\text{pipdt})}_{2}]{({\text{I}}_{3})}_{2}$,”
*Journal of the American Chemical Society*, vol. 123, no. 8, pp. 1788–1789, 2001. View at Publisher · View at Google Scholar - A Serpe, F Bigoli, M C Cabras et al., “Pd-dissolution through a mild and effective one-step reaction and its application for Pd-recovery from spent catalytic converters,”
*Chemical Communications*, no. 8, pp. 1040–1042, 2005. View at Publisher · View at Google Scholar · View at PubMed - L Cau, P Deplano, L Marchiò et al., “New powerful reagents based on dihalogen/N,${N}^{\prime}$- dimethylperhydrodiazepine-2,3-dithione adducts for gold dissolution: the IBr case,”
*Dalton Transactions*, no. 10, pp. 1969–1974, 2003. View at Publisher · View at Google Scholar - G L Abbati, M C Aragoni, M Arca et al., “Oxidation of palladium powder by the adduct ${\text{Ph}}_{2}\text{P}(\text{S})\text{NHP}(\text{S}){\text{Ph}}_{2}$·${\text{I}}_{2}$. Crystal structure of ${\text{PdL}}_{2}$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 7, pp. 1105–1110, 2001. View at Publisher · View at Google Scholar - G L Abbati, M C Aragoni, M Arca et al., “Gold(0) and Gold(III) reactivity towards the tetraphenyldithioimidodiphosphinic
acid, $[{\text{Ph}}_{2}\text{P}(\text{S})\text{NHP}(\text{S}){\text{Ph}}_{2}]$,”
*European Journal of Inorganic Chemistry*, no. 3, pp. 589–596, 2005. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, M B Carrea et al., “Copper(I) complexes with a ${\text{Cu}}_{4}{\text{S}}_{6}$- and ${\text{CuS}}_{4}$-type core obtained from the reaction of copper(0) with HN${\left({\text{SPPh}}_{2}\right)}_{2}\cdot {\text{I}}_{2}$,”
*European Journal of Inorganic Chemistry*, no. 1, pp. 200–206, 2006. View at Publisher · View at Google Scholar - J R Ferraro and J M Williams,
*Introduction to Synthetic Electrical Conductors*, Academic Press, New York, NY, 1987. - C Näther and M Bolte, “Investigations on the interaction between ${\text{sp}}^{2}$-sulfur atoms and iodine molecules using the Cambridge structural database,”
*Phosphorus, Sulfur and Silicon and the Related Elements*, vol. 178, no. 3, pp. 453–464, 2003. View at Publisher · View at Google Scholar - C Ouvrard, J-Y Le Questel, M Berthelot, and C Laurence, “Halogen-bond geometry: a crystallographic database investigation of dihalogen complexes,”
*Acta Crystallographica Section B*, vol. 59, no. 4, pp. 512–526, 2003. View at Publisher · View at Google Scholar - G Y Chao and J D McCullough, “The refinement of the structure of the complex of iodine with 1,4 dithiane, ${\text{C}}_{4}{\text{H}}_{8}{\text{S}}_{2}.2{\text{I}}_{2}$,”
*Acta Crystallographica*, vol. 13, no. 9, pp. 727–732, 1960. View at Publisher · View at Google Scholar - M Arca, F Cristiani, F A Devillanova et al., “Reactivity of 1,3,5-trithiacyclohexane and 1,3,5-triselenacyclohexane towards molecular diiodine. Crystal structures of the diiodine adducts,”
*Polyhedron*, vol. 16, no. 12, pp. 1983–1991, 1997. View at Publisher · View at Google Scholar - C Rømming, “The crystal structure of the 1:1 addition compound formed by benzyl sulphide and iodine,”
*Acta Chemica Scandinavica*, vol. 14, pp. 2145–2151, 1960. View at Google Scholar - F H Herbstein, P Ashkenazi, M Kaftory, M Kapon, G M Reisner, and D Ginsburg, “Propellanes LXXIX. Comparison of the geometries
of dithia[n.3.3]propellanes $(n=1,\text{\hspace{0.17em}}2\text{\hspace{0.17em}},\text{\hspace{0.17em}}3)$ and dithia(and oxathia)[4.3.3]propellanes.
Study of the influence of complexation with ${\text{HgCl}}_{2},\text{\hspace{0.17em}}{\text{I}}_{2},\text{\hspace{0.17em}}{\text{CdCl}}_{2}$ and ${\text{PdCl}}_{2}$ and of formation of sulfoxides on some of these compounds. Demonstration of the ‘Klammer’ effect. Structures of eighteen crystals,”
*Acta Crystallographica Section B*, vol. 42, pp. 575–601, 1986. View at Google Scholar - A L Tipton, M C Lonergan, C L Stern, and D F Shriver, “Structure, conductivity and Raman spectrum of
4,7,13,16-tetraoxa-1,10-dithiacyclooctadecanebis(diiodine),”
*Inorganica Chimica Acta*, vol. 201, no. 1, pp. 23–27, 1992. View at Publisher · View at Google Scholar - F Cristiani, F A Devillanova, F Isaia, V Lippolis, G Verani, and F Demartin, “Spectroscopic studies and X-ray crystal structures of charge-transfer
complexes of 1,4,7-trithiacyclononane with diiodine,”
*Heteroatom Chemistry*, vol. 4, no. 6, pp. 571–578, 1993. View at Publisher · View at Google Scholar - A J Blake, F Cristiani, F A Devillanova et al., “Structural and solution studies of diiodine charge-transfer complexes of thioether crowns,”
*Journal of the Chemical Society, Dalton Transactions*, no. 8, pp. 1337–1346, 1997. View at Publisher · View at Google Scholar - P K Baker, S D Harris, M C Durrant, D L Hughes, and R L Richards, “Preparation and structural characterization of the charge-transfer complex ${\left(\left[12\right]{\text{aneS}}_{4}\cdot {\text{I}}_{2}\right)}_{\infty}$ ($12[\text{ane}]{\text{S}}_{4}=1,4,7,10$-Tetrathiacyclododecane),”
*Acta Crystallographica Section C*, vol. 51, no. 4, pp. 697–700, 1995. View at Publisher · View at Google Scholar - A J Blake, W-S Li, V Lippolis, and M Schröder, “1,4,8,11-Tetrakis(diiodine)-1,4,8,11-tetrathiacyclotetradecane,”
*Acta Crystallographica Section C*, vol. 53, no. 7, pp. 886–888, 1997. View at Publisher · View at Google Scholar - A J Blake, F A Devillanova, A Garau et al., “Thioether-iodine charge-transfer complexes. Synthesis and low-temperature single-crystal structures of complexes of penta-, hexa-and octa-dentate homoleptic thioether macrocycles,”
*Journal of the Chemical Society, Dalton Transactions*, no. 12, pp. 2037–2046, 1998. View at Publisher · View at Google Scholar - H Bock, N Nagel, and A Seibel, “Interactions in molecular crystals, 123: crystallization and structure of donor—acceptor complexes between rigid or conformationally flexible thio-crowns and iodine,”
*Liebigs Annales*, no. 10, pp. 2151–2159, 1997. View at Google Scholar - F H Herbstein and W Schwotzer, “Crystal structures of polyiodide salts and molecular complexes. 7. Interaction of thiones with molecular diiodine. The crystal structures of dithizone-diiodine, ethylenethiourea-bis(diiodine), bis(ethylenethiourea)-tris(diiodine), bis(dithizone)-heptakis(diiodine), and 1-(1-imidazolin-2-yl)-2-thioxoimidazolidinium triiodide-(ethylenethiourea-diiodine),”
*Journal of the American Chemical Society*, vol. 106, no. 8, pp. 2367–2373, 1984. View at Publisher · View at Google Scholar - F Cristiani, F Demartin, F A Devillanova, F Isaia, G Saba, and G Verani, “An X-ray, spectroscopic and semiempirical quantum-mechanical study on complexes of thiones and selones with molecular diiodine,”
*Journal of the Chemical Society, Dalton Transactions*, no. 24, pp. 3553–3560, 1992. View at Publisher · View at Google Scholar - E L Ahlsen and K O Strømme, “The crystal structure of the addition compound $N$-methylthiocaprolactam-iodine (1:1),”
*Acta Chemica Scandinavica - Series A*, vol. 28, pp. 175–184, 1974. View at Google Scholar - F Freeman, J W Ziller, H N Po, and M C Keindl, “Reactions of imidazole-2-thiones with molecular iodine and the structures of two crystalline modifications of the 1:1 1,3-dimethylimidazole-2-thione-diiodine charge-transfer complex (${\text{C}}_{5}{\text{H}}_{8}{\text{I}}_{2}{\text{N}}_{2}\text{S}$),”
*Journal of the American Chemical Society*, vol. 110, no. 8, pp. 2586–2591, 1988. View at Publisher · View at Google Scholar - D Atzei, P Deplano, E F Trogu, F Bigoli, M A Pellinghelli, and A Vacca, “Interaction of diiodine with some tetra-substituted dithiooxamides. Crystal and molecular structure of bis(morpholinothiocarbonyl)bis(diiodine),”
*Canadian Journal of Chemistry*, vol. 66, no. 6, pp. 1483–1489, 1988. View at Google Scholar - F L Lu, K M Keshavarz, G Srdanov, R H Jacobson, and F Wudl, “A new preparation of 5-(alkylthio)-1,2-dithiole-3-thiones and a highly functionalized
1,3-dithiole-2-thione,”
*The Journal of Organic Chemistry*, vol. 54, no. 9, pp. 2165–2169, 1989. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, M L Mercuri et al., “Evaluation of thermodynamic parameters on higly correlated chemical systems: a spectrophotometric study of the 1:1 and 1:2 equilibria between ${\text{I}}_{2}$ and ${\text{R}}_{4}$ todit = 4,5,6,7
tetrathiocino$[1,2-b:3,4-{b}^{\prime}]$diimidazolyl-1,3,8,10-tetraalkyl-2,9-dithione; (R = Bu, Me (new data); Et, Ph (reinvestigation)). Crystal and molecular structure of the charge-transfer complex ${\text{Bu}}_{4}\text{todit}\cdot 2{\text{I}}_{2}$,”
*Canadian Journal of Chemistry*, vol. 73, no. 3, pp. 380–388, 1995. View at Publisher · View at Google Scholar - D Atzei, P Deplano, E F Trogu et al., “Interaction of diiodine with ${\text{Et}}_{4}$todit = 4,5,6,7-tetrathiocino $[1,2-b:3,4-{b}^{\prime}]$diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione. Crystal and molecular structure of ${\text{Et}}_{4}\text{todit}\cdot {\text{2I}}_{\text{2}}$,”
*Canadian Journal of Chemistry*, vol. 67, no. 9, pp. 1416–1420, 1989. View at Publisher · View at Google Scholar - F Cristiani, F A Devillanova, F Isaia, V Lippolis, G Verani, and F Demartin, “Charge transfer complexes of benzoxazole-2($3H$)-thione and benzoxazole-2($3H$)-selone with diiodine: X-ray crystal structure of benzoxazole-2($3H$)-thione bis(diiodine),”
*Polyhedron*, vol. 14, no. 20-21, pp. 2937–2943, 1995. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, A Ienco et al., “Structure and bonding of diiodine adducts of the sulfur-rich donors 1,3-dithiacyclohexane-2-thione (ptc) and 4,5-ethylenedithio-1,3-dithiole-2-thione (ttb),”
*Inorganic Chemistry*, vol. 38, no. 21, pp. 4626–4636, 1999. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, M L Mercuri et al., “Evaluation of thermodynamic parameters for highly correlated chemical
systems: a spectrophotometric study of the 1:1 and 2:1 equilibria between ${\text{I}}_{\text{2}}$ and $1,{1}^{\prime}$-methylenebis(3-methyl-4-imidazoline-2-thione) (mbit) and $1,{1}^{\prime}$-ethylenebis(3-methyl-4-imidazoline-2-thione) (ebit). Crystal and molecular
structures of $\text{mbit}\cdot 2{\text{I}}_{2}$ and $\text{ebit}\cdot 2{\text{I}}_{2}$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 17, pp. 3583–3589, 1996. View at Publisher · View at Google Scholar - M Yamamoto, L P Wu, T Kuroda-Sowa, M Maekawa, Y Suenaga, and M Munakata, “Preparation, characterization and X-ray crystal structures of ${\text{I}}_{\text{2}}$ and copper(II) complexes of 2,11-dithia[3.3]paracyclophane,”
*Inorganica Chimica Acta*, vol. 258, no. 1, pp. 87–91, 1997. View at Publisher · View at Google Scholar - J Allshouse, R C Haltiwanger, V Allured, and M Rakowski DuBois, “Molecular and polymeric compounds resulting from Lewis
acid interactions with ${\left[\text{CpMo}\left(\mu -\text{S}\right)\text{N}-t-\text{Bu}\right]}_{2}$,”
*Inorganic Chemistry*, vol. 33, no. 12, pp. 2505–2506, 1994. View at Publisher · View at Google Scholar - M Bois D'Enghien-Peteau, J Meunier-Piret, and M Van Meerssche, “Structure du complexe mérecyanine-iodide $2\left[{\text{C}}_{9}{\text{H}}_{11}{\text{S}}_{4}{\text{N}}_{3}\text{O}\right]\cdot {\text{I}}_{2}$,”
*Journal de Chimie Physique et de Physico-Chimie Biologique*, vol. 65, pp. 1221–1225, 1968. View at Google Scholar - J M Bransford and E A Meyers, “Bis(triphenylphosphinesulfide-S-iodine, ${\text{C}}_{36}{\text{H}}_{30}{\text{I}}_{6}{\text{P}}_{2}{\text{S}}_{2}$,”
*Crystal Structure Communications*, vol. 7, pp. 697–702, 1978. View at Google Scholar - D C Apperley, N Bricklebank, M B Hursthouse, M E Light, and S J Coles, “Vibrational, 31P NMR and crystallographic studies of diiodine adducts of some bidentate tertiary phosphine sulfides,”
*Polyhedron*, vol. 20, no. 15-16, pp. 1907–1913, 2001. View at Publisher · View at Google Scholar - D W Allen, R Berridge, N Bricklebank et al., “Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex,”
*Inorganic Chemistry*, vol. 42, no. 13, pp. 3975–3977, 2003. View at Publisher · View at Google Scholar · View at PubMed - H Bock, A Rauschenbach, C Näther, M Kleine, and Z Havlas, “Interactions in crystals, 111—crystallization and structure determination of donor/acceptor complexes between 1,2,4,5-tetrakis(alkylthio)benzene derivatives and bromine or iodine,”
*Liebigs Annales*, no. 12, pp. 2185–2194, 1996. View at Google Scholar - P D Boyle, J Christie, T Dyer et al., “Further structural motifs from the reactions of thioamides with diiodine and the interhalogens iodine monobromide and iodine monochloride: an FT-Raman and crystallographic study,”
*Journal of the Chemical Society, Dalton Transactions*, no. 18, pp. 3106–3112, 2000. View at Publisher · View at Google Scholar - G J Corban, S K Hadjikakou, N Hadjiliadis et al., “Synthesis, structural characterization, and computational studies of novel diiodine adducts with the heterocyclic thioamides $N$-methylbenzothiazole-2-thione and benzimidazole-2-thione: implications with the mechanism of action of antithyroid drugs,”
*Inorganic Chemistry*, vol. 44, no. 23, pp. 8617–8627, 2005. View at Publisher · View at Google Scholar · View at PubMed - C D Antoniadis, G J Corban, S K Hadjikakou et al., “Synthesis and characterization of (PTU)${\text{I}}_{\text{2}}$ (PTU = 6-$n$-propyl-2-thiouracil) and (CMBZT)${\text{I}}_{\text{2}}$ (CMBZT = 5-chloro-2-mercaptobenzothiazole) and possible implications for the mechanism of action of anti-thyroid drugs,”
*European Journal of Inorganic Chemistry*, no. 8, pp. 1635–1640, 2003. View at Publisher · View at Google Scholar - V Daga, S K Hadjikakou, N Hadjiliadis, M Kubicki, J HZ dos Santos, and I S Butler, “Synthesis, spectroscopic and structural characterization of novel diiodine adducts with the heterocyclic thioamides, thiazolidine-2-thione (tzdtH), benzothiazole-2-thione (bztzdtH) and benzimidazole-2-thione (bzimtH),”
*European Journal of Inorganic Chemistry*, no. 7, pp. 1718–1728, 2002. View at Publisher · View at Google Scholar - M Arca, F Demartin, F A Devillanova et al., “Synthesis, X-ray crystal structure and spectroscopic characterization of the new dithiolene $[\text{Pd}{({\text{Et}}_{2}\text{timdt})}_{2}]$
and of its adduct with molecular diiodine $\left[\text{Pd}{\left({\text{Et}}_{\text{2}}\text{timdt}\right)}_{\text{2}}\right]\cdot {\text{I}}_{\text{2}}\cdot {\text{CHCl}}_{\text{3}}$(${\text{Et}}_{2}\text{timdt}$= monoanion of 1,3-diethylimidazolidine-2,4,5-trithione),”
*Journal of the Chemical Society, Dalton Transactions*, no. 22, pp. 3731–3736, 1998. View at Publisher · View at Google Scholar - H Hartl and S Steidl, “Crystal molecular structure of tetrapyridine-di-(diiodothiocyanato)-cobalt(II), $\left[\text{Co}{\left(\text{py}\right)}_{4}{\left(\text{NCS}\cdot {\text{I}}_{2}\right)}_{2}\right]$,”
*Zeitschrift für Naturforschung B*, vol. 32, pp. 6–10, 1976. View at Google Scholar - M Arca, F Demartin, F A Devillanova et al., “A new assembly of diiodine molecules at the triphenylphosphine sulfide template,”
*Journal of the Chemical Society, Dalton Transactions*, no. 17, pp. 3069–3073, 1999. View at Publisher · View at Google Scholar - D C Apperley, N Bricklebank, S L Burns, D E Hibbs, M B Hursthouse, and K MA Malik, “Crystal structure of triphenylphosphine sulfide diiodine; the first crystallographically characterised 1:1 molecular charge-transfer complex of a tertiary phosphine sulfide with diiodine,”
*Journal of the Chemical Society, Dalton Transactions*, no. 8, pp. 1289–1292, 1998. View at Publisher · View at Google Scholar - N Kuhn, H Bohnen, and G Henkel, “On the reaction of carbine adducts of carbon disulfide with bromine and iodine,”
*Zeitschrift für Naturforschung B*, vol. 49, pp. 1473–1480, 1994. View at Google Scholar - E J Lyon, G Musie, J H Reibenspies, and M Y Darensbourg, “Sulfur site iodine adduct of a nickel thiolate complex,”
*Inorganic Chemistry*, vol. 37, no. 26, pp. 6942–6946, 1998. View at Publisher · View at Google Scholar - S Ito, H Liang, and M Yoshifuji, “Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene,”
*Chemical Communications*, no. 3, pp. 398–399, 2003. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, M L Mercuri, M A Pellinghelli, and E F Trogu, “Spectrophotometric study, crystal and molecular structure of the 1:1
complex between 1,3-dithiolane-2-thione and diiodine,”
*Phosphorus, Sulfur and Silicon and the Related Elements*, vol. 70, no. 1-2, pp. 175–182, 1992. View at Google Scholar - F Bigoli, P Deplano, F A Devillanova et al., “Syntheses, X-ray crystal structures, and spectroscopic properties of new nickel dithiolenes and related compounds,”
*Inorganic Chemistry*, vol. 36, no. 6, pp. 1218–1226, 1997. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, M L Mercuri, M A Pellinghelli, and E F Trogu, “Synthetic, structural and spectroscopic studies of the donating properties of sulphur-rich molecules
towards ${\text{I}}_{2}$:X-ray structure of 1,3-dithiole-2-thione diiodine,”
*Phosphorus, Sulfur, Silicon and the Related Elements*, vol. 72, no. 1–4, pp. 65–72, 1992. View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “A theoretical investigation of the donor ability of [M(R, ${\text{R}}^{\prime}$timdt) 2] dithiolene complexes towards molecular diiodine (M = Ni, Pd, Pt; R,${\text{R}}^{\prime}$timdt = formally monoreduced disubstituted imidazolidine-2,4,5- trithione),”
*European Journal of Inorganic Chemistry*, no. 15, pp. 3099–3109, 2004. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “Charge-Transfer adducts of $N$-methylthiazolidine-2-thione with IBr and ${\text{I}}_{2}$: an example of polymorphism featuring interpenetrating 3D sub-component assemblies and halogen$\cdots \pi \cdots $halogen weak interactions,” submitted to
*Crystal Growth and Design*. - W I Cross, S M Godfrey, S L Jackson, C A McAuliffe, and R G Pritchard, “The reaction of the tertiary phosphine sulfides ${\text{R}}_{3}\text{PS}(\text{R}=\text{Ph},{\text{Me}}_{2}\text{N}\text{\hspace{0.17em}}\text{or}\text{\hspace{0.17em}}{\text{C}}_{6}{\text{H}}_{11})$ with ${\text{X}}_{2}({\text{X}}_{2}={\text{I}}_{2},{\text{Br}}_{2},\text{IBr}\text{\hspace{0.17em}}\text{or}\text{\hspace{0.17em}}\text{ICl})$; structural characterisation of the CT complexes ${({\text{Me}}_{2}\text{N})}_{3}{\text{PSI}}_{2}\text{\hspace{0.17em}}\text{and}\text{\hspace{0.17em}}{\text{Ph}}_{3}\text{PS}({\text{I}}_{0.89}{\text{Br}}_{0.11})\text{Br}$ and the ionic compound ${\left[{\left\{{\left({\text{Me}}_{\text{2}}\text{N}\right)}_{3}\text{PS}\right\}}_{2}S\right]}^{2+}2{\left[{\text{Br}}_{3}\right]}^{-}$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 13, pp. 2225–2230, 1999. View at Publisher · View at Google Scholar - N Bricklebank, P J Skabara, D E Hibbs, M B Hursthouse, and K MA Malik, “Reaction of thiones with dihalogens; comparison of the solid state structures of 4,5-bis(methylsulfanyl)-1,3-dithiole-2-thione-diiodine, -dibromine and -iodine monobromide,”
*Journal of the Chemical Society, Dalton Transactions*, no. 17, pp. 3007–3014, 1999. View at Publisher · View at Google Scholar - L Lee, D J Crouch, S P Wright et al., “Supramolecular polymers of 4,5-bis (bromomethyl)-1,3-dithiole-2- thionedihalogen adducts,”
*CrystEngComm*, vol. 6, pp. 612–617, 2004. View at Publisher · View at Google Scholar - P J Skabara, R Berridge, N Bricklebank, H Lath, S J Coles, and P N Horton, “Self-assembly of halogen adducts of ester and carboxylic acid
functionalised 1,3-dithiole-2-thiones,”
*Polyhedron*, vol. 25, no. 4, pp. 989–995, 2006. View at Publisher · View at Google Scholar - P J Skabara, N Bricklebank, R Berridge et al., “Crystal engineering towards highly ordered polymeric structures of 1,3-dithiole-2-thione-dihalogen
adducts,”
*Journal of the Chemical Society, Dalton Transactions*, no. 19, pp. 3235–3236, 2000. View at Publisher · View at Google Scholar - A J Blake, F A Devillanova, A Garau et al., “Structural and spectroscopic studies of charge-transfer adducts formed between IBr and thioether
crowns,”
*Journal of the Chemical Society, Dalton Transactions*, no. 4, pp. 525–532, 1999. View at Publisher · View at Google Scholar - J D McCullough, C Knobler, C Baker, and H Hope, “The crystal and molecular structure of the iodine monobromide complex of 1,4-dithiane, ${\text{C}}_{4}{\text{H}}_{8}{\text{S}}_{2}\cdot 2\text{IBr}$,”
*Inorganic Chemistry*, vol. 10, no. 4, pp. 697–700, 1971. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “C.T. complexes and related compounds between S and Se containing donors and ${\text{I}}_{2}$, ${\text{Br}}_{2}$, IBr, ICl,”
*Trends in Inorganic Chemistry*, vol. 6, pp. 1–18, 1999. View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “DFT calculations, structural and spectroscopic studies on the products formed between IBr and $N,{N}^{\prime}$-dimethylbenzoimidazole-2($3H$)-thione and -2($3H$)-selone,”
*Dalton Transactions*, no. 13, pp. 2252–2258, 2005. View at Publisher · View at Google Scholar · View at PubMed - M Arca, F A Devillanova, A Garau et al., “31P CP-MAS NMR, vibrational, and X-ray characterization of the adducts of triphenylphosphine
sulfide with ICl and IBr,”
*Zeitschrift für anorganische und allgemeine Chemie*, vol. 624, no. 4, pp. 745–749, 1998. View at Publisher · View at Google Scholar - F Demartin, F A Devillanova, A Garau, F Isaia, V Lippolis, and G Verani, “Reactions of $N$-methylbenzothiazole-2($3H$)-thione (1) and -selone (2) with ICl: synthesis and X-ray crystal structures of the charge-transfer
adducts $1\cdot \text{ICI}$ (I) and $2\cdot \text{ICI}$ (II),”
*Polyhedron*, vol. 18, no. 24, pp. 3107–3113, 1999. View at Publisher · View at Google Scholar - S M Godfrey, C A McAuliffe, R G Pritchard, and S Sarwar, “Crystallographic characterisation of dihalogenodimethylselenium compounds,
${\text{Me}}_{2}{\text{SeX}}_{2}$ ($\text{X}=\text{CI}$, Br or I) and the dependence of their structures on the nature of the halogen,”
*Journal of the Chemical Society, Dalton Transactions*, no. 6, pp. 1031–1035, 1997. View at Publisher · View at Google Scholar - S M Godfrey, S L Jackson, C A McAuliffe, and R G Pritchard, “Reaction of ${\text{R}}_{3}\text{PSe}$ with ${\text{I}}_{2}$; crystal structures of ${\text{Ph}}_{3}{\text{PSeI}}_{2}$, ${\left({\text{Me}}_{2}\text{N}\right)}_{3}{\text{PSeI}}_{2}$ and ${\left({\text{Et}}_{\text{2}}\text{N}\right)}_{3}{\text{PSeI}}_{\text{2}}$, the first crystallographically characterised charge-transfer complexes of tertiary phosphine selenides with diiodine,”
*Journal of the Chemical Society, Dalton Transactions*, no. 23, pp. 4499–4502, 1997. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, F A Devillanova et al., “Reaction of imidazole-2-selone derivatives with diiodine: synthesis, structural and spectroscopic characterization of the adduct 1,${1}^{\prime}$-bis(3-methyl-4-imidazolin-2-selone)methane bis(diiodine) and of the first examples of I-Se-I hypervalent selenium-compounds - 1,3-dimethyl-4-imidazolin-2-ylium diiodo selenanide and 1,2-bis(3-methyl-4-imidazolin-2-ylium diiodo selenanide)-ethane bis(dichloromethane),”
*Gazzetta Chimica Italiana*, vol. 124, no. 11, pp. 445–454, 1994. View at Google Scholar - F Demartin, F A Devillanova, F Isaia, V Lippolis, and G Verani, “Reaction of $N,{N}^{\prime}$-dimethylimidazolidine-2-selone (L) with ${\text{I}}_{2}\cdot $ crystal structure of the mixed-valence $\left(\text{L}\cdot {\text{I}}_{\text{2}}\right){\left({\text{L}}_{2}\right)}^{2+}\cdot 2{\text{I}}_{3}^{-}$- compound,”
*Inorganica Chimica Acta*, vol. 255, no. 1, pp. 203–205, 1997. View at Publisher · View at Google Scholar - H Hope and J D McCullough, “The crystal structure of the molecular complex of iodine with tetrahydroselenophene, ${\text{C}}_{4}{\text{H}}_{8}\text{Se}\cdot {\text{I}}_{2}$,”
*Acta Crystallographica*, vol. 17, no. 6, pp. 712–718, 1964. View at Publisher · View at Google Scholar - G Y Chao and J D McCullough, “The refinement of the structure of the complex of iodine with 1,4-diselenane, ${\text{C}}_{4}{\text{H}}_{8}{\text{Se}}_{2}.2{\text{I}}_{2}$,”
*Acta Crystallographica*, vol. 14, no. 9, pp. 940–945, 1961. View at Publisher · View at Google Scholar - H Maddox and J D McCullough, “The crystal and molecular structure of the iodine complex
of 1-Oxa-4-selenacyclohexane, ${\text{C}}_{4}{\text{H}}_{8}\text{OSe}\cdot {\text{I}}_{2}$,”
*Inorganic Chemistry*, vol. 5, no. 4, pp. 522–526, 1966. View at Publisher · View at Google Scholar - S Kubiniok, W-W du Mont, S Pohl, and W Saak, “The reagent diphenyldiselane/iodine: no phenylselenenyl iodide but a charge transfer complex
with cyclic moieties,”
*Angewandte Chemie International Edition in English*, vol. 27, no. 3, pp. 431–433, 1988. View at Publisher · View at Google Scholar - M D Rudd, S V Lindeman, and S Husebye, “Three-centre, four-electron bonding and structural characteristics of two-coordinate iodine(I)
complexes with halogen and chalcogen ligands. Synthesis, spectroscopic characterization
and X-ray structural studies of (Triiodo)[tris(dimethylamino)phosphaneselenide]iodine(I)
and Bis{(triiodo)[tri($N$-morpholyl)phosphaneselenide]-iodine(I)}/diiodine molecular complex,”
*Acta Chemica Scandinavica*, vol. 51, no. 6-7, pp. 689–708, 1997. View at Google Scholar - W-W du Mont, A Martens, S Pohl, and W Saak, “Reversible dismutation and coordination of bis(2,4,6-triisopropylphenyl) diselenide with iodine. A model study that relates to iodine intercalation between selenium chains,”
*Inorganic Chemistry*, vol. 29, no. 24, pp. 4847–4848, 1990. View at Publisher · View at Google Scholar - J Jeske, W-W du Mont, and P G Jones, “Iodophosphane selenides: building blocks for supramolecular soft-soft chain, helix, and base-pair
arrays,”
*Chemistry—A European Journal*, vol. 5, no. 1, pp. 385–389, 1999. View at Publisher · View at Google Scholar - C D Antoniadis, A J Blake, S K Hadjikakou et al., “Structural characterization of selenium and selenium-diiodine analogues of the antithyroid drug
6-$n$-propyl-2-thiouracil and its alkyl derivatives,”
*Acta Crystallographica Section B*, vol. 62, no. 4, pp. 580–591, 2006. View at Publisher · View at Google Scholar · View at PubMed - F Cristiani, F Demartin, F A Devillanova, F Isaia, V Lippolis, and G Verani, “Charge-transfer complexes of $N$-methylthiazolidine-2($3H$)-selone (1) and $N$-methylbenzothiazole-2($3H$)-selone (2) with ${\text{I}}_{2}$ and IBr: crystal structures of $1\cdot {\text{I}}_{2}$, $1\cdot {\text{I}}_{1.25}$${\text{Br}}_{0.75}$, $2\cdot 2{\text{I}}_{2}$ and $2\cdot 2\text{IBr}$,”
*Inorganic Chemistry*, vol. 33, no. 26, pp. 6315–6324, 1994. View at Publisher · View at Google Scholar - S M Godfrey, C A McAuliffe, R G Pritchard, and S Sarwar, “Structural characterisation of the diorganoselenium interhalogen compounds ${\text{R}}_{2}\text{SeIBr}$ ($\text{R}=\text{Ph}$ or Me) and the ionic compound $[{\text{Me}}_{3}\text{Se}]$$[{\text{IBr}}_{2}]$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 19, pp. 3501–3504, 1997. View at Publisher · View at Google Scholar - P D Boyle, W I Cross, S M Godfrey, C A McAuliffe, R G Pritchard, and S Teat, “The reaction of $N$-methylbenzothiazole-2-selone with the interhalogens iodine monobromide
and iodine monochloride,”
*Journal of the Chemical Society, Dalton Transactions*, no. 13, pp. 2219–2223, 1999. View at Publisher · View at Google Scholar - C Knobler and J D McCullough, “The crystal and molecular structure of the iodine monochloride complex
of 1-oxa-4-selenacyclohexane, ${\text{C}}_{4}{\text{H}}_{8}\text{OSe}\cdot \text{ICI}$,”
*Inorganic Chemistry*, vol. 7, no. 2, pp. 365–369, 1968. View at Publisher · View at Google Scholar - S M Godfrey, S L Jackson, C A McAuliffe, and R G Pritchard, “Reaction of tertiary phosphine selenides, ${\text{R}}_{3}\text{PSe}$ ($\text{R}={\text{Me}}_{2}\text{N},{\text{Et}}_{2}\text{N}$ or ${\text{C}}_{6}{\text{H}}_{11}$),
with dibromine. The first reported examples of 1:1 addition,”
*Journal of the Chemical Society, Dalton Transactions*, no. 24, pp. 4201–4204, 1998. View at Publisher · View at Google Scholar - P D Boyle, W I Cross, S M Godfrey, C A McAuliffe, R G Pritchard, and S J Teat, “Reaction of dimethylselenourea and selenourea with dibromine to produce selenourea-dibromine,
the ‘T’-shaped 1:1 molecular adduct $N,N$-dimethyl-2-selenourea-dibromine, its solvent of crystallisation-containing analogue and the unusual ionic compound $5{\left[\left({\text{H}}_{2}\text{N}\right)\left({\text{Me}}_{2}\text{N}\right)\text{CBr}\right]}^{+}{\left[{\text{SeBr}}_{6}\right]}^{2-}{\left[{\text{Se}}_{2}{\text{Br}}_{9}\right]}^{-}2{\left[{\text{Br}}_{3}\right]}^{-}$. A low temperature crystallographic reinvestigation of $N$-methylbenzothiazole-2-selone—dibromine,”
*Journal of the Chemical Society, Dalton Transactions*, no. 16, pp. 2845–2852, 1999. View at Publisher · View at Google Scholar - P D Boyle, S M Godfrey, and R G Pritchard, “The reaction of $N$-methylbenzothiazole-2-selone and 1,1-dimethylselenourea with sulfuryl chloride and dichlorine,”
*Journal of the Chemical Society, Dalton Transactions*, no. 23, pp. 4245–4250, 1999. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “Mechanistic aspects of the reaction between ${\text{Br}}_{2}$ and chalcogenone donors (LE; $\text{E}=\text{S}$, Se): Competitive formation of 10-E-3, T-shaped 1:1 molecular adducts, charge-transfer adducts, and ${\left[{\left(\text{LE}\right)}_{2}\right]}^{2+}$ dications,”
*Chemistry—A European Journal*, vol. 7, no. 14, pp. 3122–3133, 2001. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, A J Blake et al., “1,2-Bis(3-methyl-imidazolin-2-ylium iodobromoselenanide)ethane: oxidative addition of IBr at the
Se atom of $\text{a}>\text{C}=\text{Se}$ group,”
*Angewandte Chemie—International Edition*, vol. 40, no. 22, pp. 4229–4232, 2001. View at Publisher · View at Google Scholar - F Demartin, P Deplano, F A Devillanova, F Isaia, V Lippolis, and G Verani, “Conductivity, FT-Raman spectra, and X-ray crystal structures of two
novel [${\text{D}}_{2}\text{I}$]${\text{I}}_{2}$ ($n=3$ and D = $N$-methylbenzothiazole-2($3H$)-
selone; $n=7$ and $\text{D}=N$-methylbenzothiazole-2($3H$)-thione) iodonium salts.
First example of ${\text{I}}^{-}\cdot 3{\text{I}}_{2}$ heptaiodide,”
*Inorganic Chemistry*, vol. 32, no. 17, pp. 3694–3699, 1993. View at Publisher · View at Google Scholar - F Bigoli, F Demartin, P Deplano et al., “Synthesis, characterization, and crystal structures of new dications bearing the -Se-Se- bridge,”
*Inorganic Chemistry*, vol. 35, no. 11, pp. 3194–3201, 1996. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F A Devillanova et al., “Square-pyramidal bonding of ${\text{I}}_{2}$ molecules at the ${\text{I}}^{-}$ nodes of a polyiodide infinite
*pseudo*-cubic 3D-network,”*CrystEngComm*, vol. 6, pp. 540–542, 2004. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F A Devillanova et al., “Kinetic and thermodynamic aspects of the CT and T-shaped adduct formation between 1,3-dimethylimidazoline-2-thione (or -2-selone) and halogens,”
*European Journal of Inorganic Chemistry*, no. 11, pp. 2166–2174, 2006. View at Publisher · View at Google Scholar - G BM Vaughan, A J Mora, A N Fitch, P N Gates, and A S Muir, “A high resolution powder X-ray diffraction study of the products of reaction of dimethyl
sulfide with bromine; crystal and molecular structures of (${\text{CH}}_{3}$)${}_{2}\text{S}{\text{Br}}_{n}$ ($n=2$, 2.5 or 4),”
*Journal of the Chemical Society, Dalton Transactions*, no. 1, pp. 79–84, 1999. View at Publisher · View at Google Scholar - A F Wells,
*Structural Inorganic Chemistry*, Clarendon Press, Oxford, UK, 5th edition, 1984. - F van Bolhuis, P B Koster, and T Migchelsen, “Refinement of the crystal structure of iodine at ${110}^{\xb0}$ K,”
*Acta Crystallographica*, vol. 23, no. 1, pp. 90–91, 1967. View at Publisher · View at Google Scholar - P Deplano, F A Devillanova, J R Ferraro, F Isaia, V Lippolis, and M L Mercuri, “On the use of Raman spectroscopy in the characterization of iodine in charge-transfer complexes,”
*Applied Spectroscopy*, vol. 46, no. 11, pp. 1625–1629, 1992. View at Publisher · View at Google Scholar - L N Swink and G B Carpenter, “The crystal structure of iodine monobromide, IBr,”
*Acta Crystallographica Section B*, vol. 24, no. 3, pp. 429–433, 1968. View at Publisher · View at Google Scholar - G Bernardinelli and R Gerdil, “2-chloroquinoline iodomonochloride,”
*Acta Crystallographica Section B*, vol. 32, no. 6, pp. 1906–1907, 1976. View at Publisher · View at Google Scholar - N Bricklebank, S M Godfrey, H P Lane, C A McAuliffe, R G Pritchard, and J M Moreno, “Synthesis and structural characterisation of ${\text{R}}_{3}{\text{AsX}}_{2}$ compounds
($\text{R}=\text{Me}$, Ph, $p$-${\text{FC}}_{6}{\text{H}}_{4}$ or $p$-${\text{MeOC}}_{6}{\text{H}}_{4}$; ${\text{X}}_{2}$= ${\text{Br}}_{2}$, ${\text{I}}_{2}$ or IBr); dependency of structure on R, X
and the solvent of preparation,”
*Journal of the Chemical Society, Dalton Transactions*, no. 23, pp. 3873–3879, 1995. View at Publisher · View at Google Scholar - C G Hrib, F Ruthe, E Seppälä et al., “The bromination of bulky trialkylphosphane selenides ${\text{R}}_{2}$${\text{R}}^{\prime}$ PSe (R, ${\text{R}}^{\prime}$ = $i\text{Pr}$ or $t\text{Bu}$) studied by
physical and computational methods,”
*European Journal of Inorganic Chemistry*, no. 1, pp. 88–100, 2006. View at Publisher · View at Google Scholar - S Abbas, S M Godfrey, C A McAuliffe, and R G Pritchard, “A cubic modification of (triphenylarsine)diiodine,”
*Acta Crystallographica Section C*, vol. 50, no. 5, pp. 717–719, 1994. View at Publisher · View at Google Scholar - S M Godfrey, C A McAuliffe, I Mushtaq, R G Pritchard, and J M Sheffield, “The structure of ${\text{R}}_{3}{\text{PBr}}_{2}$ compounds in the solid state and in solution; geometrical dependence
on R, the crystal structures of tetrahedral ionic ${\text{Et}}_{3}{\text{PBr}}_{2}$ and molecular trigonal
bipyramidal ${\left({\text{C}}_{6}{\text{F}}_{5}\right)}_{3}{\text{PBr}}_{2}$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 22, pp. 3815–3818, 1998. View at Publisher · View at Google Scholar - S M Godfrey, C A McAuliffe, R G Pritchard, J M Sheffield, and G M Thompson, “Structure of ${\text{R}}_{3}{\text{PCI}}_{2}$ compounds in the solid state and in solution: dependency of
structure on R. Crystal structures of trigonal bipyramidal ${\left({\text{C}}_{6}{\text{F}}_{5}\right)}_{3}{\text{PCI}}_{2}$, ${\text{Ph}}_{2}$(${\text{C}}_{6}{\text{F}}_{5}$)${\text{PCI}}_{2}$ and of ionic ${\text{Pr}}_{3}^{\text{n}}{\text{PCI}}_{\text{2}}$,”
*Journal of the Chemical Society, Dalton Transactions*, no. 24, pp. 4823–4827, 1997. View at Publisher · View at Google Scholar - P H Svenson and L Kloo, “Synthesis, structure, and bonding in polyiodide and metal iodide-iodine systems,”
*Chemical Reviews*, vol. 103, no. 5, pp. 1649–1684, 2003. View at Publisher · View at Google Scholar · View at PubMed - A J Blake, W-S Li, V Lippolis et al., “Template self-assembly of polyiodide networks,”
*Chemical Society Reviews*, vol. 27, no. 3, pp. 195–206, 1998. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F A Devillanova et al., “First example of an infinite polybromide 2D-network,”
*Chemical Communications*, no. 17, pp. 2226–2227, 2003. View at Publisher · View at Google Scholar - C J Horn, A J Blake, N R Champness et al., “Helical templating of polyiodide networks at a binuclear metallo complex,”
*Chemical Communications*, no. 3, pp. 312–313, 2003. View at Publisher · View at Google Scholar - C J Horn, A J Blake, N R Champness, V Lippolis, and M Schröder, “Construction of the first cross-linked double helical polyiodide,”
*Chemical Communications*, no. 13, pp. 1488–1489, 2003. View at Publisher · View at Google Scholar - M C Aragoni, M Arca, F Demartin et al., “${\left[\text{Ni}\left(\text{L}\right)\left(\text{MeCN}\right)\right]}^{2+}$ complex cation as a template for the assembly
of extended ${\text{I}}_{3}^{-}\cdot {\text{I}}_{5}^{-}$ and ${\text{I}}_{5}^{-}\cdot {\text{I}}_{7}^{-}$ polyiodide networks {$\text{L}=2,5,8$-trithia[9](2,9)-1,10-phenanthrolinophane}. Synthesis and
structures of $\left[\text{Ni}\left(\text{L}\right)\left(\text{MeCN}\right)\right]{\text{I}}_{\text{8}}$ and $\left[\text{Ni}\left(\text{L}\right)\left(\text{MeCN}\right)\right]{\text{I}}_{\text{12}}$,”
*Inorganica Chimica Acta*, vol. 357, no. 12, pp. 3803–3809, 2004. View at Publisher · View at Google Scholar - P Deplano, F A Devillanova, J R Ferraro, M L Mercuri, V Lippolis, and E F Trogu, “FT-Raman study on charge-transfer polyiodide complexes and comparison with
resonance Raman results,”
*Applied Spectroscopy*, vol. 48, no. 10, pp. 1236–1241, 1994. View at Publisher · View at Google Scholar - P Deplano, J R Ferraro, M L Mercuri, and E F Trogu, “Structural and Raman spectroscopic studies as complementary tools in elucidating the
nature of the bonding in polyiodides and in donor-${\text{I}}_{2}$ adducts,”
*Coordination Chemistry Reviews*, vol. 188, no. 1, pp. 71–95, 1999. View at Publisher · View at Google Scholar - A J Blake, R O Gould, W-S Li et al., “Silver-thioether crown complexes as templates for the synthesis of extended polyiodide
networks: synthesis and X-ray crystal structures of
$\left[{\text{Ag}}_{\text{2}}{\left(\left[15\right]{\text{aneS}}_{5}\right)}_{2}\right]{\text{I}}_{12}$, $\left[\text{Ag}\left(\left[18\right]{\text{aneS}}_{6}\right)\right]{\text{I}}_{7}$, $\left[\text{Ag}\left(\left[18\right]{\text{aneS}}_{6}\right)\right]{\text{I}}_{3}$, and $\left[\text{Ag}{\left(\left[9\right]{\text{aneS}}_{3}\right)}_{2}\right]{\text{I}}_{5}$,”
*Inorganic Chemistry*, vol. 37, no. 20, pp. 5070–5077, 1998. View at Publisher · View at Google Scholar - C W Perkins, J C Martin, A J Arduengo, W Lau, A Alegria, and J K Kochi, “An electrically neutral $\sigma $-sulfuranyl radical from the homolysis of a perester with
neighboring sulfenyl sulfur: 9-S-3 species,”
*Journal of the American Chemical Society*, vol. 102, no. 26, pp. 7753–7759, 1980. View at Publisher · View at Google Scholar - N Khun, T Kratz, and G Henkel, “Derivate des Imidazols, IX. Stabilisierung von Selendiiodid durch Komplexbildung,”
*Chemische Berichte*, vol. 127, no. 5, pp. 849–851, 1994. View at Google Scholar - A J Arduengo and E M Burgess, “Tricoordinate hypervalent sulfur compounds,”
*Journal of the American Chemical Society*, vol. 99, no. 7, pp. 2376–2378, 1977. View at Publisher · View at Google Scholar - F Bigoli, P Deplano, F A Devillanova et al., “A spectro- and conductometric study of the reaction of imidazoline-2-selone derivatives with
bromine—crystal structure of 1,2-Bis(3-methyl-4-imidazolin-2-ylium dibromoselenanide)ethane,”
*European Journal of Inorganic Chemistry*, vol. 1998, no. 1, pp. 137–141, 1998. View at Publisher · View at Google Scholar - A Mancini, University of Cagliari, Cagliari, Italy, 2006.
- C G Hrib, P G Jones, W-W du Mont, V Lippolis, and F A Devillanova, “Complexes of bidentate phosphane selenide ligands with mesitylenetellurenyl iodide and with
tellurium diiodide,”
*European Journal of Inorganic Chemistry*, no. 6, pp. 1294–1302, 2006. View at Publisher · View at Google Scholar