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Bioinorganic Chemistry and Applications
Volume 2008 (2008), Article ID 479897, 10 pages
http://dx.doi.org/10.1155/2008/479897
Research Article

Synthesis, Characterization, and Biological Activity of -Methyl-2-(-1,2,3-Benzotriazol-1-y1)-3-Oxobutan- ethioamide Complexes with Some Divalent Metal (II) Ions

1Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait
2Microbiology Program, Department of Biological Sciences, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait

Received 26 June 2007; Accepted 13 November 2007

Academic Editor: Patrick J. Bednarski

Copyright © 2008 Nouria A. Al-Awadi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. Liu, L. Li, H. Dai, Z. Liu, and J. Fang, “Synthesis and biological activities of new 1H-1,2,4-triazole derivatives containing ferrocenyl moiety,” Journal of Organometallic Chemistry, vol. 691, no. 12, pp. 2686–2690, 2006. View at Publisher · View at Google Scholar
  2. L. Tian, Y. Sun, H. Li et al., “Synthesis, characterization and biological activity of triorganotin 2-phenyl-1,2,3-triazole-4-carboxylates,” Journal of Inorganic Biochemistry, vol. 99, no. 8, pp. 1646–1652, 2005. View at Publisher · View at Google Scholar
  3. B. Modzelewska-Banachiewicz, J. Banachiewicz, A. Chodkowska, E. Jagiełło-Wójtowicz, and L. Mazur, “Synthesis and biological activity of new derivatives of 3-(3,4-diaryl-1,2,4-triazole-5-yl) propenoic acid,” European Journal of Medicinal Chemistry, vol. 39, no. 10, pp. 873–877, 2004. View at Publisher · View at Google Scholar
  4. D.-K. Kim, J. Kim, and H.-J. Park, “Synthesis and biological evaluation of novel 2-pyridinyl-[1,2,3]triazoles as inhibitors of transforming growth factor β1 type 1 receptor,” Bioorganic & Medicinal Chemistry Letters, vol. 14, no. 10, pp. 2401–2405, 2004. View at Publisher · View at Google Scholar
  5. T. Asami, Y. K. Min, N. Nagata et al., “Characterization of brassinazole, a triazole-type brassinosteroid biosynthesis inhibitor,” Plant Physiology, vol. 123, no. 1, pp. 93–99, 2000. View at Publisher · View at Google Scholar
  6. J. G. Haasnoot, “Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands,” Coordination Chemistry Reviews, vol. 200–202, pp. 131–185, 2000. View at Publisher · View at Google Scholar
  7. S. J. Lippard, “Iron sulfur coordination compounds and proteins,” Accounts of Chemical Research, vol. 6, no. 8, pp. 282–288, 1973. View at Publisher · View at Google Scholar
  8. A. Z. El-Sonbati, A. A. El-Bindary, A. El-Dissouky, T. M. El-Gogary, and A. S. Hilali, “Substituents effect on the spectral studies on rutheninum(III) complexes of 5(-4-derivatives phenyldiazo)-3-phenyl-2-thioxo-4-thiazolidinone,” Spectrochimica Acta A, vol. 58, no. 8, pp. 1623–1629, 2002. View at Publisher · View at Google Scholar
  9. A. El-Dissouky, S. S. Kandil, and G. Y. Ali, “Cobalt(II) and copper(II) complexes of (2-acetylpyridine)-(5,6-diphenyl-[1,2,4]triazin-3-yl) hydrazone,” Journal of Coordination Chemistry, vol. 57, no. 2, pp. 105–113, 2004. View at Publisher · View at Google Scholar
  10. A. El-Dissouky, O. Al-Fulij, and S. S. Kandil, “Cobalt(II) and copper(II) complexes of (2-thiophene)-(5,6-diphenyl-[1,2,4]- triazin-3-yl)hydrazone,” Journal of Coordination Chemistry, vol. 57, no. 7, pp. 605–614, 2004. View at Publisher · View at Google Scholar
  11. N. M. Shuaib, N. A. Al-Awadi, A. El-Dissouky, and A.-G. Shoair, “Synthesis and spectroscopic studies of copper(II) complexes with 1-benzotriazol-1-yl-1-[(p-X-phenyl)hydrazono] propan-2-one,” Journal of Coordination Chemistry, vol. 59, no. 7, pp. 743–757, 2006. View at Publisher · View at Google Scholar
  12. B. Al-Saleh, M. A. El-Apasery, and M. H. Elnagdi, “Synthesis of new azolyl azoles and azinyl azoles,” Journal of Heterocyclic Chemistry, vol. 42, no. 4, pp. 483–486, 2005. View at Google Scholar
  13. G. O. Ezeifeka, M. U. Orji, T. I. Mbata, and A. O. Patrick, “Antimicrobial activities of Cajanus cajan, Garcinia kola and Xylopia aethiopica on pathogenic microorganisms,” Biotechnology, vol. 3, no. 1, pp. 41–43, 2004. View at Google Scholar
  14. E. S. Al-Saleh and C. Obuekwe, “Inhibition of hydrocarbon bioremediation by lead in a crude oil-contaminated soil,” International Biodeterioration & Biodegradation, vol. 56, no. 1, pp. 1–7, 2005. View at Publisher · View at Google Scholar
  15. C. N. R. Rao, Chemical Applications of Infrared Spectroscopy, Academic Press, New York, NY, USA, 1963.
  16. S. S. Kandil, N. El-Brollosy, and A. El-Dissouky, “Synthesis and characterization of Mn2+, Ni2+ and Cu2+ complexes of 4-arylideneamino-3-mercapto-6-methyl-1,2,4-triazin-5-one,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 30, no. 6, pp. 979–987, 2000. View at Google Scholar
  17. A. C. Fabretti, G. C. Franchini, and G. Peyronel, “Tin (IV) tetrahalide complexes of 2,5-disubstituted 1,3,4-thiadiazoles,” Spectrochimica Acta, vol. 36A, pp. 517–520, 1980. View at Google Scholar
  18. C. N. R. Rao, R. Venkataraghavan, and T. Kastyri, “Contribution to the infrared spectra of organosulphur compounds,” Canadian Journal of Chemistry, vol. 42, no. 1, pp. 36–42, 1964. View at Publisher · View at Google Scholar
  19. B. Singh, M. M. P. Rukhaiyar, and R. J. Sinha, “Thioamide bands and nature of bonding—IV: chelating behaviour of 2-mercaptoquinazole-4-one,” Journal of Inorganic and Nuclear Chemistry, vol. 39, no. 1, pp. 29–32, 1977. View at Publisher · View at Google Scholar
  20. K. Singh, M. S. Barwa, and P. Tyagi, “Synthesis and characterization of cobalt(II), nickel(II), copper(II) and zinc(II) complexes with Schiff base derived from 4-amino-3-mercapto-6-methyl-5-oxo-1,2,4-triazine,” European Journal of Medicinal Chemistry, vol. 42, no. 3, pp. 394–402, 2007. View at Publisher · View at Google Scholar
  21. J. Morales-Juárez, J. Pastor-Medrano, R. Cea-Olivares, V. García-Montalvo, and R. A. Toscano, “Nickel(II) and cobalt(II) complexes of methyl(2-aminocyclopentene-1-dithiocarboxy)-S-acetate (ACDASAMe),” Polyhedron, vol. 26, no. 4, pp. 918–922, 2007. View at Publisher · View at Google Scholar
  22. A. W. Coats and J. P. Redfern, “Kinetic parameters from thermogravimetric data,” Nature, vol. 201, no. 4914, pp. 68–69, 1964. View at Publisher · View at Google Scholar
  23. D. W. Johnson and P. K. Gallagher, “Comparison of dynamic with isothermal techniques for the study of solid state decomposition kinetics,” Journal of Physical Chemistry, vol. 76, no. 10, pp. 1474–1479, 1972. View at Publisher · View at Google Scholar
  24. S. Glasstone, Textbook of Physical Chemistry, Macmillan, Bomby, India, 2nd edition, 1974.
  25. N. K. Tunali and S. Özkar, Inorganic Chemistry, Hazi University Publication, Ankara, Turkey, 1993, Pub. No. 185.
  26. H. Arslan, U. Flörke, N. Külcü, and M. F. Emen, “Crystal structure and thermal behaviour of copper(II) and zinc(II) complexes with N-pyrrolidine-N-(2-chloro-benzoyl)thiourea,” Journal of Coordination Chemistry, vol. 59, no. 2, pp. 223–228, 2006. View at Publisher · View at Google Scholar
  27. G. S. Sodhi, “Correlation of thermal stability with structures for some metal complexes,” Thermochimica Acta, vol. 120, pp. 107–114, 1987. View at Publisher · View at Google Scholar
  28. H. Arslan, “Cobalt, nickel and copper complexes of benzylamino-p-chlorophenylglyoxime. Thermal and thermodynamic data,” Journal of Thermal Analysis and Calorimetry, vol. 66, no. 2, pp. 399–407, 2001. View at Publisher · View at Google Scholar
  29. H. S. Sangari and G. S. Sodhi, “Thermal studies on platinum metal complexes of N-methylcyclohexyl dithiocarbamate,” Thermochimica Acta, vol. 171, pp. 49–55, 1990. View at Publisher · View at Google Scholar
  30. A. A. Frost and R. G. Pearson, Kinetics and Mechanism, Wiley, New York, NY, USA, 1961.
  31. M. Lalia-Kantouri, G. A. Katsoulos, C. C. Hadjikostas, and P. Kokorotsikos, “Kinetic analysis of thermogravimetric data on some nickel(II) N-alkyldithiocarbamates,” Journal of Thermal Analysis and Calorimetry, vol. 35, no. 7, pp. 2411–2422, 1989. View at Publisher · View at Google Scholar
  32. B. J. A. Jeragh and A. El-Dissouky, “Synthesis, spectroscopic and the biological activity studies of thiosemicarbazones containing ferrocene and their copper(II) complexes,” Journal of Coordination Chemistry, vol. 58, no. 12, pp. 1029–1038, 2005. View at Publisher · View at Google Scholar
  33. E. K. Efthimiadou, G. Psomas, Y. Sanakis, N. Katsaros, and A. Karaliota, “Metal complexes with the quinolone antibacterial agent N-propyl-norfloxacin: synthesis, structure and bioactivity,” Journal of Inorganic Biochemistry, vol. 101, no. 3, pp. 525–535, 2007. View at Publisher · View at Google Scholar
  34. K. Z. Ismail, A. El-Dissouky, and A. K. Shehata, “Spectroscopic and magnetic studies on some copper (II) complexes of antipyrine Schiff base derivatives,” Polyhedron, vol. 16, no. 17, pp. 2909–2916, 1997. View at Publisher · View at Google Scholar
  35. A. D. Russell, Densification, Sterilization and Preservation, Lee and Febinger, Philadelphia, Pa, USA, 4th edition, 1991.
  36. Z. H. Chohan, “Antibacterial and antifungal ferrocene incorporated dithiothione and dithioketone compounds,” Applied Organometallic Chemistry, vol. 20, no. 2, pp. 112–116, 2005. View at Publisher · View at Google Scholar