Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime

Table 1

Crystal data and structure refinement for 1 $·$ (py)C(Me)NOH and 2.

Empirical formula	${\text{C}}_{35}{\text{H}}_{40}{\text{Mn}}_2{\text{N}}_{10}{\text{O}}_{13}{\text{S}}_2$	${\text{C}}_{16}{\text{H}}_{18}{\text{MnN}}_4{\text{O}}_6$
Formula weight	982.77	417.28
Crystal size	0.75 $\times$ 0.50 $\times$ 0.40	0.25 $\times$ 0.20 $\times$ 0.20
Crystal system	triclinic	monoclinic
Space group	P-1	$\text{P}{2}_1/\text{n}$
θ range for data collection.${}^{°}$	$5.5\le \mathrm{\hspace{0.17em}\hspace{0.17em}}\theta \le \mathrm{\hspace{0.17em}\hspace{0.17em}}11.0$	$3.4\le \theta \le 30.1$
$a$, Å	9.627(4)	10.6538(5)
$b$, Å	9.962(4)	14.3935(7)
$c$, Å	11.750(4)	11.8231(8)
$\alpha$ , ${}^{°}$	92.610(10)	90.00
$\beta \text{,}$${}^{°}$	96.560(10)	90.264(7)
$\gamma \text{,}$${}^{°}$	107.450(10)	90.00
V, ${{\AA }^3}^{}$	1064.2(7)	1813.00(17)
Z	1	4
${\rho }_{\text{calcd}}\text{,}$$\text{g}{\text{cm}}^{-3}\hspace{0.17em}$	1.534	1.529
$\mu \text{,}$${\text{mm}}^{-1}$	0.766	0.770
GOF	1.116	1.009
$R{1}^{\text{a}}$	0.0443	0.0344
$wR{2}^{\text{b}}$	0.1125	0.0948

${}^{\text{a}}$$I>2\sigma (I),R_1\mathrm{\hspace{0.17em}\hspace{0.17em}}=\mathrm{\hspace{0.17em}\hspace{0.17em}}\sum (|F_{\text{o}}|-|F_{\text{c}}|)/\sum (|F_{\text{o}}|)$
${}^{\text{b}}$$w{R}_2\mathrm{\hspace{0.17em}\hspace{0.17em}}=\mathrm{\hspace{0.17em}\hspace{0.17em}}{\{\sum [w{(F_{\text{o}}^2-F_{\text{c}}^2)}^2]/\sum [w{({F_{\text{o}}^{}}^2)}^2]\}}^{1/2}$