Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime

Table 2

Selected dond lengths (Å) and angles (${}^{°}$) for 1 $·$(py)C(Me)$\mathrm{\hspace{0.17em}\hspace{0.17em}}{NOH.}^a$

Mn–O31	2.089($2$)	Mn–N2	2.287(3)
Mn–$\text{O}{32}^{\prime }$	2.102(3)	Mn–N11	2.300(3)
Mn–N1	2.287(3)	Mn–N12	2.283(3)
O31–Mn–$\text{O}{32}^{\prime }$	101.06(11)	$\text{O}{32}^{\prime }$–Mn–N12	94.84(11)
O31–Mn–N1	164.21(11)	N1–Mn–N2	70.11(10)
O31–Mn–N2	95.50(11)	N1–Mn–N11	88.37(10)
O31– Mn–N11	87.21(10)	N1–Mn–N12	94.52(10)
O31–Mn–N12	98.23(10)	N2–Mn–N11	97.89(10)
$\text{O}{32}^{\prime }$–Mn–N1	87.06(11)	N2–Mn–N12	161.24(10)
$\text{O}{32}^{\prime }$–Mn–N2	95.00(11)	N11–Mn–N12	70.19(10)
$\text{O}{32}^{\prime }$–Mn–N11	163.96(11)

${}^{\text{a}}$Primes denote symmetry-related atoms.