Synthesis, Characterization, Theoretical Crystal Structure, and Antibacterial Activities of Some Transition Metal Complexes of the Thiosemicarbazone (Z)-2-(pyrrolidin-2-ylidene)hydrazinecarbothioamide

Table 3

Bond lengths of the ligand.

Bond	Actual	Optimal	Bond	Actual	Optimal	Bond	Actual	Optimal
N(2)–H(11)	1.0117	1.0120	C(8)–H(15)	1.1188	1.1130	N(5)–H(13)	0.9906	1.0120
H(20)–C(10)	1.1242	1.1130	C(9)–C(8)	1.5256	1.5230	H(12)–N(5)	0.9929	1.0120
C(10)–H(19)	1.1246	1.1130	C(7)–N(1)	1.3204	1.2600	C(3)–N(5)	1.3652	1.3690
H(18)–C(9)	1.1167	1.1130	C(7)–C(8)	1.5251	1.4970	C(3)–S(4)	1.6285	1.5760
C(9)–H(17)	1.1169	1.1130	H(14)–N(6)	0.9976	1.0500	N(2)–C(3)	1.4145	1.3690
C(10)–C(9)	1.5399	1.5230	C(10)–N(6)	1.4571	1.4700	N(1)–N(2)	1.3414
C(8)–H(16)	1.1188	1.1130	C(7)–N(6)	1.4224	1.4620