Bioinorganic Chemistry and Applications

Research Article

Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates

Table 4

Magnetic moment and electronic spectral data for the Mn(II) ditolyldithiophosphates.


S. no.		(nm)	Assignments

1.	—	347	⁶A_1g → (⁴D)
		431	⁶A_1g → (⁴G)
		510	⁶A_1g → (⁴G)

2.	—	339	⁶A_1g → (⁴D)
		435	⁶A_1g → (⁴G)
		512	⁶A_1g → (⁴G)

3.	—	344	⁶A_1g → (⁴D)
		433	⁶A_1g → (⁴G)
		517	⁶A_1g → (⁴G)

4.	5.90	341	⁶A_1g → (⁴D)
		432	⁶A_1g → (⁴G)
		514	⁶A_1g → (⁴G)

5.	—	370	⁶A_1g → (⁴D)
		449	⁶A_1g → (⁴G)
		536	⁶A_1g → (⁴G)
		269, 286	Charge transfer

6.	5.60	365	⁶A_1g → (⁴D)
		452	⁶A_1g → (⁴G)
		542	⁶A_1g → (⁴G)
		271, 285	Charge transfer

7.	—	373	⁶A_1g → (⁴D)
		456	⁶A_1g → (⁴G)
		538	⁶A_1g → (⁴G)
		264, 286	Charge transfer

8.	—	364	⁶A_1g → (⁴D)
		465	⁶A_1g → (⁴G)
		532	⁶A_1g → (⁴G)
		264, 284	Charge transfer

9.	5.68	363	⁶A_1g → (⁴D)
		450	⁶A_1g → (⁴G)
		540	⁶A_1g → (⁴G)
		271, 283	Charge transfer

10.	—	361	⁶A_1g → (⁴D)
		446	⁶A_1g → (⁴G)
		536	⁶A_1g → (⁴G)
		266, 285	Charge transfer

11.	—	359	⁶A_1g → (⁴D)
		445	⁶A_1g → (⁴G)
		533	⁶A_1g → (⁴G)
		270, 282	Charge transfer

12.	—	370	⁶A_1g → (⁴D)
		453	⁶A_1g → (⁴G)
		539	⁶A_1g → (⁴G)
		269, 280	Charge transfer

13.	—	396	⁶A_1g → (⁴D)
		479	⁶A_1g → (⁴G)
		542	⁶A_1g → (⁴G)
		273, 294	Charge transfer

14.	—	390	⁶A_1g → (⁴D)
		472	⁶A_1g → (⁴G)
		573	⁶A_1g → (⁴G)
		270, 296	Charge transfer

15.	—	393	⁶A_1g → (⁴D)
		478	⁶A_1g → (⁴G)
		549	⁶A_1g → (⁴G)
		273, 294	Charge transfer

16.	5.65	390	⁶A_1g → (⁴D)
		470	⁶A_1g → (⁴G)
		565	⁶A_1g → (⁴G)
		277, 295	Charge transfer

17.	—	352	⁶A_1g → (⁴D)
		435	⁶A_1g → (⁴G)
		524	⁶A_1g → (⁴G)
		253, 276	Charge transfer

18.	—	356	⁶A_1g → (⁴D)
		447	⁶A_1g → (⁴G)
		521	⁶A_1g → (⁴G)
		247, 274	Charge transfer

19.	5.76	353	⁶A_1g → (⁴D)
		432	⁶A_1g → (⁴G)
		525	⁶A_1g → (⁴G)
		251, 273	Charge transfer

20.	—	356	⁶A_1g → (⁴D)
		442	⁶A_1g → (⁴G)
		528	⁶A_1g → (⁴G)
		249, 275	Charge transfer